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Zou 4d-un
I
5*t
b
C-Ae"'{t
Zou e 4d-un -
AFiEi-)I:'. Ifr
,r.5c Cheroj.stry - Sub Theory
IJl.sl. i-r.F atr er r C:ener a I Cherr-,istry
Zxte::na1
5n ;'. arlts
fnterna I
1 n rua rks
( 2+1+2+2)
*2 for.attencrance
t:
2
2
-s
*e!
f.r
for 2 test papers
for one serninar
for tlvo assignnrent
irj.r- !- r,,:5
Faier II -r'ieeoritical anc
F
hysical Cherr,j_stry
'i'ota
* )
50 rnarks
10 marks
(
sarns
10n rnarks
1
as
aoove
2n
rnark-s
)
actencance 2 niarks: cet./een 75-90:i 1.5 mark-c,
60-75,,', 1 mar.ks 16o,t. - nil
i'wo test pa-ers - 2x2+4 rnar;r_s , far each te-.t F:ap-:r
> B0:, Score 2 marl<s, be+-ween 60:80i, 1 .5 rnarks, 3O-6n9.,
1 rnar]<s, below 309', - no rnark.
Serninar - 2 nrarks: for excel_lanr prer{crmance 2 mar<s,
for EicC ;erf ,rrmance 1.5 marii-c, averaee one [rar'li.
Assicn:irent - 2 mar:<s if i,re]1 Cone - 2 narl<s, averace
1.5 r,iarl<s, below averace 1 marlt.
9n',,1
A!FEr::Ii'.
z . Sc
Cheinistry Suo i-ractical
Seconc: .year
', uaI ita trv€
v uSot j-tatrve
.
Externa
2s)
30)s5
L
Viva
(
Ilv-
basr-C on l.raetical-s
)
6o nrarks
Intern
,20
(
a1
t iiarl<s f or suDrrtit.ting
recorcs having recorced
the reciuirec nu-.rr,cf of
ex5:erinrents.
atten( ance zi marl<s
perforrnanee 4 marl<s
Vi.va internal 4 marks
-20 rrrarks
(Note: -kecoro vaI
uation is 1_,art of inttrr.-raL evaLuat:iol;. I'he culy
certif ie( ani val_uecl . racorc's must i;e sui,mitte( -at the ti.me of
e:,:ternal examiription ) .
'i'he ex=cutior: of the int-rnaI evaLuation anc,' forwarcinc of marks
Lo tire Universj.ty rtrd1l D€ done as p-:'r the ncte gl.ven in appencir I of
the irtinutes of Eos ri of S tudies meetinc- ( UC ) helC on 29 .lO. 1999co.py .attachei )
(contc . . .2)
-t ts.
sc
STtv rJI,I c\LTcUT
Ctremistry (suU) .syl_f abus _ t" be ef f
,June 2ooo
Admissicn cn viras
PAPER
unit r lnvircnment.rl
;\'
i*
UNI-\,aR
T
ectirre
f rom
GE\IER.IL CHEI.ITSTRY
( ?n r';)
ctrernistry
rntr:'r''rctiln: Envircnment, and its
o-9
Biceycles cf c.N.p anC-s]-" seglents.Ec;systems
gec-chernLc.e1
E: Hydro chemistry -hydrologicrl
cycre-w,lter
r !rs-w':Let
res)urces
reS)UfCe"
aqU.atie eCC sygggrnr.
a.nd
..
I;".I]r;i:L::i"il''.o.menta1hazardscfpesticides(brier
E. . Radi:tlon polluticn
and nolse polluti:n .(brlef
descriptlcn only)
tlnlt ff Ch&nical Bonding
s)
d,
iJNrr rrr
orqranic chremistry and
reactlon .mechanisms.
(/ leArg
, mescmeric .:nd,%tec[crmerte
of b;n,Cs. reactio" i"i"11ne6iates
:1 end carbene.
lon of metha,ne.
lticn to d:uble b;nd _
iNucL:ahilic subst-; iutlon
effect of substitutents on
E]-iminrtirn rea.etirns Er
and n2 mechanisrns _ mechanisms
dehydrarlrrl of
of
"r""r,J:.1*.Iu*u"r,rd;h;i;;"i.irr., 5f
al_lqrl ha.r.Ides.
i sm or i .qr rar
riilil::i: r;x";;u'.*: +.n - mechan
fliriii.lfHi]'
vuclecphiil; I;"matli
crefrs
re..:cri-:n.
suu.tit,rfi,cl;ael
n
I
1
cn
_
'2-
\\
Huckegls (ri+Z) rule of arcm.rtieity.
t'lentirn :f structures trf s)me..,r.r-o".,r,in:ia arrrl.:tic ccmpouncls
cycl)psntadienyl ani>n ferracene
F.eter:cyclic c:mprund.s- struccures of pyrr,)J-e, furan, pyrcfn,
thirphener ...nC indal-e.
( t z rrrs)
Unit lY. Sterecchemistry cf carbon crmp:un:is
Grnf:rmaLj-:ns and c.nfign:raLion. c.>nfcrmLEi;)ns of glhene,
cyclrhexane and methyr cyclchexane - e>qpl-,lnrtion cf more stable
.and fum-:.ric acids as examples. Optical iscm=rism- opticat
activity - chir.-rr c - enanticmers - rabemic mixt,rre - resclutbn
(Iatic acid and tartaric acid to be taken rs ex:mples)
(enrs)
Unit rlf Pclymers.
F
- phencl fcrmaldehyde, urea fcrmaldehvde
\fnes.cf pclymerisati:n
prastics
- srTnthetic rubbers - synthetic rirri:s---irrermipl;suic;
& thermc setting plastics-siliccnes p:lluti:n .lue to plastics
blodegradable pla stics.
-1
snrs)
Unlt \rfT Natural Prcducts
A. Terpenes : Essential oils - is;Iatj.cn - Classificaticn of
terpencids - citral and greranlcl.
e- 'Elkalcics: occ*rrence - extracticn - physigrcgicar activity -s)urce structure and uses of rric:tine, c"nhii.ne. p.:peverine,
morphine - narcctic 6rugs and psychedelic rlrugs.
(
(
enrs)
IJnit \rlff Bi-ochemistry
A. cellular energetlcs - thermcdynamics :f biochemical proaesses
coupled rea.sj-on - ATp eremenGi ;;;r*;.,t-oe rrre-metalrti"m
carb>hydrates. prgteins and lipids.
"r
B. Enzymes - nature, oJ-asslficagicn, matabclic functi:>n, fact-,rs
inflr:e:rcing enzyme acti.rn, t"tlchagris.Mentcn iherry, active site
and specif icity _- ccenzlme, .activatfr, iohlbitcps'and isoenzlmes.
o- Nucleic acids - stmcture of .DNA & RNA + Oiiierences
functi'>ns - different types ,)f RNA - genetic dod.e - self -replicaticn
mutation.
( 12hrs)
vLtl
Unit I[ Bioinorganlo Chemistry
Metal icns in biolcgic.al sysLems - bi:chemtstr:r of iron - o)qaqen
transpcrt and stcrege - haernoglcbin and myoglcbin - erementary
ldea cf structure anc mechanism of action - scdium - potasslum
pump - bicchemistry.cf Zn+& Co (Urj-ef menti:n)
(
-2.9
'
ci?
srrrs)
\
-3unit i-x .\ii-.i1,gisal chemistry
,,\ccur.rcy anc precision - classific.eti)n cf errcrs e.-r.Iibr.-rtion of
weights 'rnC measuring vessels.
analysi-s.
iiiicipf"s in the sefaragi:n cf cati:ns in qualiEative
Lux
thelry,
Lewis
therry,
.rorf
l:.lses
Brcnsted
acid
tft-,rry'rf
indicat)rs,
base
Acid
fioca'thoryr Usncvich c.:ncept-Ph-buffers
indicat.:rs.
red:x
-h.r*.ltrgr'aphy - aCs:rptiln, partiticn and i:n exchrnqe chromltoqr,lphy. Pafler and thiB layer ghrcmatoqraphy - Rf value - aPPlic-r.tixs.
irn excnange methrds in the separati'>n of IanthamiCes ':nd
(tqArs)
Desalinatif,a 3f ''fatar.
References:
'Puti d' 'SlAr^y".'a
cirqmi-sLry 1. Physical
irew
cenCig+ trncigemic chemistry - J' D' I-ee
2. in
o
- - 3:
cDncepts'& l"I5dels in tn:rgamlc chernistry - Drr$las &
' DantkJ.
4. Drgemic chemistry - vol f &"I{ - f'L'Finat
5. ?i Buide brok t' mechanism ln crganic chemistrv - Peter
Avkes.
6. tfrrzlrcnmental chemistry - A.K.De
7 - UniversotvGeneral Oremj-stry - CNR Ral
I
weight'bge of Marks
Examination 3hrs
sectj-rn A
sectlrn B
seeti,:n c
lut cf t5 (fzxfk = te rnalks Ir
IIT
4or11' 'r1 5 (a;a= te)"
^"IY
v
2outof 4 (z>e=fa)
'vr
vrr
'
vTr=
r*
12
,
k.a
!2
L2
g
'4
4
l0
5
.L2'
i '------EO marbs.
o
o.
,;l:
lr
P.'r?ER
If THEORITIa!.L t\D pHy3f3;:L f{t:,IitfCV
Unit f Nuelear Chami.stry
h l-'^C*'11%['6'
"t^.a\ tL'1'"1'
--
Nucl-ear forces n/p ratioJerchang6 €o..." in n,rcLeu5i
Liqui.i drop model_. Isotopes, isobars and isotones with soectfic
examole.s. Detection o! isotooes by \stcns mass sr2eetrogreptl
separation of isotopes by diffusj_on methcds.
Nud]ear fiSi-on & nuclear fllsion.
Applicatioris of radio i.sotopes - C14 .lrt,619,''fock dat.ing, rarliodiagnosis' an'f raCj-otherapy. mechanism o.i bioloricbl rproiCss
I
(illustration takiac photosynthcsis 1
(
10hr3)
unit rr solid state
Bonding in sofi.is-crfstal olancs-li{iler i dices - seven crystal
svstems and fourteen Bravis ratties-DeriYaticn of Braqg equationcrysEal structurc of NaCf-Iic4rid cry.staf s-types-pro,:erties and
appl ic.etion.
(Shrs)
6
Unit Iff TLermodynamics
Zeroth :nC iirst law-Math'ernatical formulation-Bond enerqy and heat
of formation-,Jou6e Thomsoa efEect-appltcation to liguefaction of
g+ses'by Linde mef-hori. EntropY and free enerqy. ' Second }ar^r 35
apptied to ent.rooy-cllange in entsooy of systern and the univers=coneept of entropy in ecoloqy, 6nerg:v changes in bioLoqical
DTOCESSES.
( torrrs)
Unit IV Properties of Liquids
Vapour pressure - surfac-e lensirn-viscosity-e><planaticn of these
prolerties on the basis of intermolecul.lr attracticns. ReLraction
repractise ithdex-moIar refraction - molar colarj-zation.
(
'6nrs)
Unit v Sol-utions
osn,rt:sirl tr.nL
C,rlligative pro"erti-es of dilute scluticns-osmotic pressure expressicn for osmotic pressure-measqrement - determination of
molecular Emss of pnllans=. (eg. Protains) Tsotome solutionS - theory
of semi permeability-the sj-eve theory, the solu'cilj-t1z theory t
adsorption theory and capillary theory-cefI wall as semi permeable
mei$eance, reverse osrnqsis, application in desali-nation of '^Iater'
Electrokinetic properties -7,s93 pctential -electrophoresis
Electrcosmosis-Dorn ef'Eect-Donnan membrane equilibrirm.
k..\
(to trrs)
unit,rJ
-tliqrhr
_
tion. nP=ut Lamb':rt '" l:::atnsteins
e i s,,,;
;:..; :ni}: li"i;lji:
Ii. i:lli"j
s
:g, !:
I :":.
.1-: i
;ffiitrr".;";r..i,fi.I::::,.,.?,
_ rn*o.lucr irn
':of
--'
A brief rt:. ^^.ed ma
Til# .t:: g:
3i:.i"",I ::.
;:. H,+'"Tr=y^1
i n r o n o. *". jls.
I:...;::;", ;fi
1
1ei,,_ql.,urrtum
yielri
# ;. _
;'"";:J;:::.:"=""=
unit Vrr Molecular
iP-.ettro5c6py.
sororry.^^^^
a
(shrs)
t:J-euEroilagnetiC
elec r
.
"
%rc
:.:;.I;j"
unlt ',.rr Kinetics
ofr,oactions.
First and se
r ed )
(snrs)
depenCence
on reactlonc
.determinatio
Li"iJio|",.,.o.,
lf-Iife
il:i:;
-l-ex
and its
or
in
tamP
h
unlt rx Ereatrochemistry
(3 hrs)
i.nation
e wi.th of
i.i"',i"iilt.."
eguation
Unit x Electromotive
force
_
(ehrs)
L and
Eurement
:tornetrio
..
is
Ls
of - carro;i;n.
unit xr Phals Eguillibria
- ___+urJ_cr
e.Leclro(ehrs)
is ;t*1i""'$*.1
unit Er surf.:c
*.]
...,.
phocochemistry
L::ii"l$ftili."_tii*"
rcn
- apc1ic."1i66.
;tt.ffii:"t;i^tt?-., -surr.rce secriDn or s.rrrr
(6 hrs)
.ppri.ijr"ilS. ""iii'Jii;;; :T:,13:'3f":"*i.'li;":"fiii:, j"..;*;:,:rrucrure,
(strr ean)
o.
-'r'ouis
. (ehrs)
,f. D Lee
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