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Document 1732026
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+
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br
,,rid
ll
+: gfH'-lAiI]-i*:l-:f -
c,1
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--.---'
gElllii.c-9ry'!-rtsI
comi;:uil( :
,
an Crganac
clisplrcement
ancl Electrcn'ic
lllectloit
t. orb1t-al' c'rer:Iap
and pi bollcls'
otuit-r gverlaI
"it*o fe"t - t-:::ire j-c e'' fect -'
(5 llrs' ) '
rnduct'it'"
"f
steric effc:L
clisoiecerne"t t'it"t
HYperconjugation effect
Electrc'meric
^, -.-.i.
(1o hrs' ) classrmechanj-sms
organic reacLj'cn
2. InLrr':''r'iction to
Peactlon inter e(.i' -eI"
fj-caLi';n cf organic 'reactlons'r-hej'r st'Jbirity"
s 6;1r5'-:eati"'' ";;-;'rbaniun t'r alkvr hal'ices --:s
-t
rg ;ncl rrrr
substitut'"t';:";;:-o'''u
I'/rorkownj'koff
tdd"'on Eiectropirilic
react';"= - E' ant' ll^1"'tlti::;;*';"
,r.r.i..ti-on
ur,:,<ructs
substituticn re'lctio
Irr.ti(rit'/ - "'"""t"i-'h11ic or+-ht: para cf fecc'
t".:'"'-i"t' sL.Ds!'i-tuL:'on
- mollos':cq536irius
C'r '' ss j-f -rcirt-icn
)
s
('i
lir
'
l:es
3 . Car:ch' '7:'1
;ni c'i rxyt' ;=: - :o:t' -"i- ::t""":";i:":::*:::
..i i-.,irrcrs a, ribose
t:::;::;:,.':;
j'it ui'in':'
(u,crirron .,,rrl'l- - ! iu':rra:'ltl.'
:
";;."="
princi; re 'lf
,f oruc<.'s.'- anti'
fructo: e.
-r
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=
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r-ranu''rcr--urt'
tt"'t'ilt'"::;;...,"..
e:"-:""s.i'":;.;;;.,.,'*'l:.-:f
n'-'t
sucri')9:-'
-rn
:.r-r.i4:tr.:r(rf unir:---
I
c:r ;uios'' - lnclugtrlill
prr te i-ns
5.
or
- testsl t"t
i\iUcti-'- i-!v'-'
*'--
t
nuclt'.oticjes RIrlA anc DtiA'
'X-
( s ructure
t's"s '.;f c:'11g195e
I
hrs' )
Nl
Ieic acitl*" 1r'
tn
i-dea
alncl DNL - :j1€menlarY The
l-
ecs i(l
frh
ur€ t
reS
cac
i
tn=r,r.t.
6.
urs)'
:)i
:
(4
en z)rme s'
"og?'-l,il"
"r,J,1o*ones
1"'-:::":';:lll .;'"
s i r i c a tio
:. ?:: 3?"=?l^:" :: fi ":':
characterrsE'
grolrp"
pro"tilii"
con.. . -. -.2,
.
a
I
L
\l
12.
poll-ution ( 11 Hrs. ) Definj.t.ion of poJ-lutj-on and pollutant
,t
Air pollution - air pollutants (oxicles of carbo5t,
s.uIphur, i *1, q, 1 fIy ash, arbestos dust, hydrocarbons,
Iead tetqaethyl)i Creen house effect - acid rain-.- ozone
l-i
layer - ,flurocagbons ano their effec:t - control of
I
l;
air pollution.
r
- sources of v;ater pollution
treatment of indirstrial r'vaste - irater - Harc-l anc soft
boiJer
for boi.
, i of
nf water
w=tcr - l;ater r for
^. *--^nacc
hardness of
waters - Retsovali
use - purifiqation of water for t'own sup,oly'
Water pollutron
ttse
- ceuses atrci effects due to over
leachlnE, non - degradable rv':ste'
of fertilizers,
pesticides, mining - remedies'
SoiJ- poj-lution.
REFEREiJCE
1.
2.
pollution anafYs'is
S.M. KhoPkars wi1e1Y Eastern Ltd'
Environmental Chemistry - Anil-kumar
D.c . vi1elY Eastern t,td.
3
Organic Chemistry Finar vol ' I & II '
4
organic Chemistry K'S' Tivrari & Co'
_3_
a
l,
i
An elementary aecount and charactei;i:ties cf .o..r.#".
cf asslfication of v-it-tmi.:s . Elerner-itiry
_biocatarvst.
stuciy'and
slrustural formulas of vitarni.ne A, D and f , vllarnin
cjeficiency ciseases.
7. Alkalej_ds ( 3 Hrs).,Iso1ation,
general prcperLi_es ard tests
2hysiolc,gicel action of a-lkaln.ids-_ strucLurls of coni.lne,
rncr,,hine. ano nj-cotine.
and
(:l
)C:
-
n
l1
.Preparation and yrvtErLrEe
propertie- ur
of rnd_LeIC
mafaic ano
and fumariC
fumaric aCidS.
acidr
Joly,rrers ( 3 urs. ) polymers .- class
j
,1suur!ruqLa(rrt
fication (JJ
of toolymers
.ootymers
I\ietural p<;lymers (protein, polysaocle.er:ides,
starch and natura.L
natu
poJ.yvj-nyl choride, polystyren and
nyJ-on preparation).
l
l
/
I
I
l'
I
1990 U'.riiLS
'l'''
Totlll- te.rchin[ Hrs: 90
': (aHrs)
ilolecules
oflirjtecutes
(8llrs)
. Structure anb shape of
boncj.
of
Ii1'bridisation
Theory
- sp, spf 'spJ'
:
Z
a
7 rz
2-covirlent
'dsd, d'sp/ d'sp, -.examples irKe CZH4
BdF2
L + CZHZ,CH4T
Z Lt
+'
- -1
,
-
BF1, HZO, NHJI PClq',
'".'
^eF2,
i
\
,\EF'4, SF6 r .-IF7 VSEPR theory.
;
Explanation br bond length, b:rnd r:nilie, bonci energy and shapes
of molecul-es - Elemdn'tary ideu ol v;l-ence bonci and molecular,
,.
orbital- methods fof,bcnding.; ,
.i
,|.|
.,
!
' I'luclear
CLremistry
(6 Urs)
Natural and arti-fictr51 trr:nsmutltlon - Radioactive series.
Group displacernent law. , Seprr.aticn oI lsotopes by g:seor"\s ancl
theriral- Ciffusion inethods . Il:dio.rc*"ir,e isotopes and their
applications in structlril el-,rcidi,ti-on, in mlaicine and in agriculare
age of rneterial-s and fossils. Atomic fj.ssj.on und fusion.
Nucl-ear energy in India.
, _
(J hrs)
1. -Fertilizers
CI sslfieation as dir.e't, inciirect, cr nplete and incomplete
':
fertllizsrs.
Potassj.um salts. P.ock phosphate. Altificial
inorg:,nic fertilizer-q'- amnlcnium sulphate, arnmonium phosphatecal-cium cyn.rrnide, urea, superphosph.':te, NPK vi:l-ue.
4. Fuels
Carbonand hydrogen besed glseous, liquid and solip
. Cal-ori-fic velue of fuels. Prjnciple of production con
.1nd uses of water gas.. producer g:s, natural gris petrg
-'io: l- g-s and bioguses. :
t'
.l
It{ineral wealth of Irldia
'
Occurrence of technic.rll1r irng,crt;nt mineril_s
Uith";picici_ r'efer./ ce to miner;r1 r
'l
,
I
i
r
wi-th composition and. uses
I
e study
rti ticn,
rent
typr
paper
!f
t
(gtrrs )
Met:Ilurgy
and aciinides'
Elec*ronic congigurt'r'tion cf l':nthanides
Iantheinide
'
Inport-nt gene:'i:1 ptoptttits t''f the elements'lanthanides'
of
contractlon. Occurr€nqe ind. ripplicotiong'
( ) nrs 1
!'roduc';ic,rl , ri'rcl uses of r Cc tireides '
of aluminium' . '
.Occurrencel isolation :rnd appl-lc'rtlons
(6frrs)
rrickel, titaniun snd tlorium'
:
and quantitctive
Theoretj-ca1 priniiples of qu;J-if,i{tive
(znrs )
analys is
quantit'itive
Theoretica1. principl'es of *lul'1iti'tlve''nd
'{
analysis.Appllcation!ofso].ubilityprociuct-coln[loninneffect.
permanganometry'
Principles of acidimetry, alkrl'iirietry'
dichrometry, i-odimetry and iociometry'
(4rrrs )
---9,-Cases
re'-rf gJs's from gi's ltlws'
'
Ideal gus
t- equ:rtion' Devi-'tion of
:'ition' Critical qgnglonts
rt', der vir'3'I'= tn":lill:-r::':;';:,
''
- ,- '.^-' ,,V:tt
*"ason for'deviation'
g'jses '
and their experimental 'leterroin-rtion' Liqueftrction 'of
Linde ard Clauders Procbss'
( 12hts)
1'0. Phase Rul-e
t"i:l:ent svs tem
d"^ '^i1*)';"u;Iin t"
-rerms
. inJolJf
""t
.e.*-statenent.
,
:
fu
5
'-t
uta
iit<,
/ttt*l '
* ( trr'ion6ruent melting Polnt
tii,'- cofnpo[n,i";;:J;';ii
nsimple 6utlc
applic-ti.-'ntoblnary.;}iqui$.s'ysterrt..-coni;u1.te}ymiscib}e.vapour
pressure of idear isofltigls
pressure compositlon*curves' v3pour
.
mixture;' rl"lcti-qna,1
Deviation from ideal be.hirv,r,outr. Azeotropic
i
i
1
distilr*tion. Comp'1.q-ii91v immiscible svstems '
: cailutatton oi morebular weielli;
t:ifi;
1.
crv=t,ri?fi""i,,'i"'iln$leG:
St9a1
d+sti|:aF:n
: ":i ,
i
.
rf-n":l-^.
.Sizednd.shapdloicr}4st+ls.Crystillographicsystemslspqce
oi iattices' spaclnt
Lr 1'= \j'
Numrrer- ti:rd
ceit. l\Li'muei
unit cej-r'
'1'ru type
and un:-t
i ' lattice
of X-rays by
of l-attice P3'iines ' Mi]I er lndices ' Dlffraction
I
I
of clil:tance ratio '
crYs t - ls . Bragg Equat'ion:i C"ricul-''+'ion
- -.
i
:
i
c"r.ta11r- structure,e{,soclun chlori|e '
.,zl r.-- \
'1
.i
2.
Chem]-ca1
:
l1'J'rle uruD'
Various factr
-l-rr nf
r-i
of nrre
molecularitY
molecularityofreac-|-ron.Fi.ite^ei:u:;t.cnoffirstor(]eI.I'tsquUlvrr.
-^1-^,,-'l
o{ the inffuence of temperatur"e
HydrolYsis of este:" Qual-itAti" ' ito
t
i in ,reaction rates ,-{:'':'henius ei'u'itl l(l
I
I.tI
"
i
I
.t
)i
I
I
-\__,
/
I
a
't3
1
method.
I
f
Chl-orir
Law, t
(
(lorrrs)
-24I
a
RIiS
Toplc
1.
2.
Hgurs
of
rnol-ecLrles
6
6
3
3
3
I
a
4.
E
2
6.
5
n
o
of Anirl-vsis
6
i ?.
1
3
t.
10
.\..
1
'-\.
.i
6.
2
12
11.
,1
.9
4
'l o.
I
o
8
)'
8.
.t
90
I
ga
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