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Document 1732021
fLi
UNr'./ERSTTY
.,6F C\LrcuT
B.Sc Chemistry (suU).syllabus _ t: be effective
,Iune 2616
Admissicn cn-vlrris
from
i ceveq.rl cHEi.,lT STRY
Unit f. , :-nvlrctrment.:1 Chemi stry
( ?" r,s)
A' rntrcd'rc,tiln: Envircnment and its segrents.Ec;systems.Bio_
grec-chernical cycles cf C.N.p anrl S.
tt
B' Hydr'; chemistry -hydrol0gicr1 c.r,cre-water
vv'.e=r rtis',u'.,e"
res)urces end
'aqUatie
P.\PER
eCC gyg..grng.
a..,
ifater quelitv par,lmeters-Do,BoD..
')
and coD. Detecticn r:f f]trcride,
rhloride' sulph:rte, nitrate, pncspnat":Liuia./
rnci r.r<ar-inity of
water. pcrlirranrs of warer
ertr,-,".rt", soep
and dorerqenrs, Desricida;; :';;;;;;)*i"i""t.i:rr.
rir",
rerti1iz"r",
w-*r.iii]*=ili.otoq.i".r
magnificatlon and bi.oaccumurati"" i""l.c
cf plrr-utants.
'tlater pqrif ication -, se.limentatlcn -.,
"i,rect
ig.,i-t
irr,,
f 1 rtrat icn,
Cisj_'rfectirn, icn
a"".:llnation.
"xdfri"q",
C. Ai.r pollution_rn;
re' pollution by
c>cldes of N.s.c, fryarr
:*:ffHI. '::*";ll-i,
:;.;l:Tr:ij"i,il:cmcbire
i:n :'E ozcne *
rg - acid ;aln.
r. Tcxtcity and environmental
hazards cf pesticides (brief
generrl discussj_cn)
E. Radi:tion polluticn and noise polluti:n
(Urlef descripllcn
Lrhit rI Chemical- Bsn ing
( ,
c)nseqlrencas. Greenhc
onj=r7)
.
\/4 A 's)
Iar .shapes (v.sepm)
en-e)
.Sp(ethylene)
Sq) rtof-ecuiar
bD
bicmclecules.
le, dipole- induced
clipcle, induced dipcle
cns.
iArrr rrr organic ctremistry
and reaction mechanisms.
(,, L, o
electcrmerlc
lon inLermediates
e.
eroxLde ef f ecr.
:i"::::ii3i::*
-
i^ratden
invesricri
Nucrrohil lib*lf"ir""
- effecr
rof substi_rutenrs
on
Sliminati?n reacti::ns Er and E2 mechanisms
- mechanisms of.
dehycratlin cf atc."ncrs-urrJ-a"nvdroharogenaticn
cf a1)q11 Lrar-ides.
Electrcphiric ar':m'rtic substituticn rnechanism
of nistrat':n
br.,mi'nrticn, sulphonati;;_ile Frie<rer
crafts rercti)n,
l.Iuele,rphilic er:m.atic rrf.Cft"ti_r>6
f
.. r;. . .2
_
- 2*
Hr:ckeEls (lt+il rule .rf aromatieity.
l"lention :f structures cf
c-yc1:p"ntadieny)anj.,>n
i";;;;"rr"
I;i;fi:I:i':.8;TilXi3:-'i."I."."s
r3in'11i" compounrls
or pyrrcre, ruran, p),ran,
unit ,v. ,lE.erecchemlstry cf. carbon
c:m}::unds
7)
(r.z nrs)
C).nf,)::maticns and c-.nfj-gmration.
cr>nfcrmrti:)ns of ethnne,
merhyr-Ey;i;;"".ne
_ e>cpt.en,rtion cf more stable
:fii:H..{il;.:"u
Geometrio.el_ iscmerisrn _ e><planatiol
and fumarj_c acid" ."
.talinq.2 _ butene, maLeic_
optica-r,liscm=rism_
actlvity - chiral c - "*u*rj;;:
optlcal
- racemic mixt,rre - rescr-ut1on
(latic acid and t.it. I"-'.tr*i"to
""iitiil"."
be taken .as
pprove(
. otinc
tt'
,
riilOUt
i---..V.---t"
L.
,^
s)me n)n_benzan:id
O
riiost t
exemples)
whotis.
Counc:
Unlt \If
to
Iyl:-".
prasri-cs
.polymers.
cf
(shrs)
pclym-e5l,s31ion.
._ phenor fcrmaldehvdr
- svntheric mbbe;;
= synrhdrl;-r{tF6""r"in5ffiiis:i Yde
L:!:#:"ffi:Ti":i::!f":"iri.Jil:=';ii"ii5J, u". t,, pr.Iti"" ICs
t)e
reqarc
year.
finaI"
"
(shrsi
Unlt \IrI Natural prcduits
r\. Terpenes : Essentlal oils-_ lsclaticn _
Classification of
- citral and g"."rri.oI.
lerpgpclds
B' Elkarolds:
occurren"E-]-"o.acrion - physisJ_ogicar
s,)uree strucrure and uses of
activlty
papeverine,
morphine. - narectl-c 6rugs ina'p"y"fredelic
"i;r;i;;;' "r5o1{r.,",
rirugs.
one we
pepers
j-t-:m
')y
(ohrs)
:
Lrrlj.t :\ZffL eiochemi.stry
ot
'.d
1
InE-'
vit
.
Unit {X Bloi66pnan.i.o Chemistry
12hrs)
Metal icns in ul3lpgicar- svstems- biochemtstr.r-of iron - oxygen
transpcpr and stcrase - r,.*n"qi""::Jq.*,iir.oir,
ldea cf structure anC
- _erement"qa
of actic. j soairxn
pump - lricchemj.srry ot mechanism
potassium
z,nas s. (uri"i-riJiIir.rl
,
.
'(enrs)
-2't'
s
I,l
n
Ax
,:,
_
{
ry
-3-
^.r^\
Unlt
f--X
rii-t2iytical chemistrlr
Accurl:.y and preci-sion - CLasSificati)n cf errrrs cnlibration
.f
weights .rnd measuring .ressels.
Prineiples in the separall:n cf cati:ns in quariE.ative anarysis.
The:ry rf acld -fnrr bases - Brcnsted therry, Lewis the:ry, Lux
frccd !h?.y, usncvich concept-ph-buffers
,lcid - b:se inaicitcrs,
red,:x indicatcrs.
chrrmatcgraphy - acs:rpti:n, partitlcn and j_cn exchanqe chromltogra_
phy. Paper and thin |ayer ghromgtcgraphy
Rf valu. - uppiicatixs.
r:n exchange methcds in the separation'ri -ranth._rmices
.rnd
Desalinari.f,q of ',rater.
(lqArS)
References:
1. Physical .he*r"; 2. .1 lew cen$lfe
Pun d, SAaY-.a
Incigemlc chernistqf - J. D. lee
3.
& Mcdels in tncrgamlc ilr*r,ist* --orglas c
Scncepts
If - r. L. Finat
crganic chemj.stry - peter
K.De
C|trR
Ra'_.l
r,{eigh€iqe of Marks
'f:
Marx Marks
Section
sectlrn
Secti:n
50
B
12 out of
4:r1g -r1
C
2outf,f
A
15
Unlt r
(fZxf\ = 18 rnarks rrc:.
rc)
-
6
(4xa=
4
(z>re:rn)
.
lz
.lz
-l+
t2
- v
-4
t/rd
VIr
vrr:
10
3
Bo
k.A
*..i.".
o
4
,/
g7'
,a
o
-4 P.iPER
TI
-a'-.
\,
THEORf?ICI,L \ND PHYSfC;IL C'{1r4IS'TRv
unit I Nucleai
CtremisttY
-J-
.*tA ol''1r'''l: h L'i)--'/'*qfr
Nucleir forces n/p ratiolerchFjngb forces in n'releus Liqui.i rlrop morle1 . Isotopes, isobars and isotones with speci-fj-c
examDles. Detection o'E isotooes by \st'ons mass sDectroqraph
s
scparation of isotopes by diffusion methcds.
(.
Nudlear fi"si-on & nuclear fllsion
applieati,:ris of radio i.sotopes - CL4 d.rt€tgr, rock dating, rarliorliagnosis and radiotherapy. meihanism o:E l:iolo?fica1 .nrocess.(illrrstratlon talcinq photo-synthc.sis )
^
(
rorrrs'r
unit rr snlid state
Bonding in sollrts-crystal olanes-Miler i dices - seven crystal
systems and :Eourteen Bravis Latties-Deri.ration of Braqg egu'atloncrystal structurc of NaCf-licarrld crystals-types-pro,:ertj-es anC
(8hrs)
application.
'
Uhit IfI Thermddynamics
zeroth snc Eirst law-Math*r,Jti".t to#uration:Bond energry and heat
of formation-Joube Tttomson gfEect-application to liguefacti-on of
gases by Linde method. Entropy and free energy' ' second law 65
app,lied to entrooy-change in cntrOoy of systern and the universej-n bioloqical
.6enecpt of entropy in ecology, energY cha.nges
rfrocesses.
(lohrs)
unit rv Properties of Liquicls
.Vapour pre'ssure - surface lension-visiosity-e>cplanation of these
prrt:erties on the basis of intermolecular attracticns. Retractlon
repractise irirdex-molar refraction - molar oolarization.
( fnrs).'
.t
Unit V Solut j-ons
osmos Lrl axaCulli-qative proDerties of dilute sclutions-osmotic pressure e4:ressicn' for osmotlc pressure-measurement - determination of
molecular Bmss of pnflrmess (eg,. eroteins) Isotome soLutions - theOry
of semi permeabj-lity-the sier'" ;hscrlr the solur:ilj-tv theory,
a.dsorption theory and capillary theory-bell- wa11 a.s semi permeable
menbg.rnce, t:ev3rse osmisj-S/ aOplication in Cesa1j-nation Of ''fater'
Erectrokinetic r:roperties -zeta pctenti3r -electrophoresis
ElectrcoEmosis-Dorn eff ect-Donnan membrane eqr:il ibri'rm.
(10 hrs)
k. \
a\
T^
-----
-
_z/'\
-
,l
-J
bimcleculariisi:IilceN':i'Itmechanisnr'-Jliminlticnacc'iiti'':''l
:':rlei:tati'--n j'n nucleophil:-c
mechlr:j-sm - re..lctivity ;1p3
( IO Hrs ' )
ar")m;rtic su'bsti-tuti'n '
unit Iv
5'i':a ir-crl.riiI j'l:"Y
cli
cj=P^ioir col'lPOUl'.ID5
Intrluucticntcc;ilf:rmati-onalandlysis'c:'r:fcmati:irs
cyclohcxane-1-3
rf ettran-', n butan''- cyclohexane' methyl
i:n gerxnetica I I sorneri sm
int g'r acticn s :r rltl pref i;'rreci c'nf r)rmat
i)f 'nomenclature'
Cis anu trqns is:)m!"rs - B an' i' systems fr:rna.ric oc_ids
rllustiatloss using 2 butenc - mareic lQg
meth;cls t'1.'<-if ferentiate'
1r2 clqc;;ikir1 ethena '. stil'cc'ne etc ',
gc-ometrlcal- isornells'Ii
ahd nrola::
optical is,:m...rism-c;lticil activity-9pgclfio'
elqmlnts cf
rrtati:ns, en'atrtil:tr':':rphisn''ehiralityl.
1T::"'
andsinrplesymmcntry':-rL'rati(ins'Racemicmixtltreresolutitrn
R an'j S
a'osolut'=
m.'thoCls- D & Ir configure'ti''rn'
:::t'nuraticn
synthesis' opticlll
Diast::r.'':,mcrs, mi:soft''rm' aslrmmetric
of aslrmletric
'cerb:'n.':tom
Isr:m-'rj-sm with':iut thu' presence
j.. '
( 12 Hrs. )
allenes, spiran , bip}r.enylq.. .,
.r
UNit V
}IYDR.OCZiRtsC}I5
Gcneral rn:-'thccis '-:f prcp='raticn of alkanes' ''Ik':''i:s'
alkyn,-'s-C:njugat''"c'cumul':tecl'an(lisolati'dd:u!:Ieb':ncrs'
of 1,,3 buta'Jit-Re'7
Preparatien and inrp 'r'!i"nt pr:perties
;f naphthalenc"
isr-rpfe-oli, styretl''', stillbene' syn€hc'sis
tlipheny.I rn'-'thane incL
lncthracerro nn,.l"nthr':tte uiphenyl '
cf these compouncs'
trii;h.'nyl methane''Imp'trrtgnt reacti(''Hs'
Ar:d pr:perties
Cycloalkanes - .n'lng'nclature - r)reparatien
civet':ne ( 12 Urs')
1art7,: ring c':mP-Junus '- mu.sc'')ne ':nn
Unit VI FIriLoG'tl'I cot'ii'('U:Ds
ecmpcuntls
AIkyI and :rni aryl haliies-1'1 clih:rl cgFn
rnci prcperties of thes'-=
Genc-ral .m.':thc,cs '-f pr-:pltr':tictr
j-cies ' preporatlcn and
cciitpr:uncis. Vinyl ':lnci rIIyI hlI
(8 Hrs')
'
properties.
Unit vII ORG-{}iO}illl.ALLIC COI'TDCI]}IDS
Grignarcrs
Synth*-sis of ';rg'rnic compc'unis using
zinc ccmpt-lunds'
1'g:gc'nt .rnci ':rIky Ij.-thj-urn - Org;'-'n'-r
( I tfrs )
'
?.-.f rrrln.lt sky r:-';icti:n '
Ui-rj.t VIII SfDRO>O( COI'rI}C)t'lIi)S
L,2 r3, aIc'--'hr:Is ^' Distlnct-icu
Mc/3.5 -2000
-''
betw,sen !12 ana 3 :rIc-*:'
..--.=.
ascent 3nd d,rsceut in :Iclir:I s.;ri.a s plnacc
I-pi n :c,: Ic,ne
r:-,afr.:rng€rrtr:ot ,. I,iuuf :.rctur-: .,f ethvl nlcc;h-'.I f.:rm.:ntati
:i)
hydretlo ,:f .ethylen.._. ..
Pclyhldrlc' a lc.lltol s g lycerr:l-preparatlon :rnd prcp.,_\rt ieb .Us.
s.
Preparatlcn and pfcp;,.1'1i...,s .-:f phe,ncl +ffL.ct <_,f subst_ltu*-nts
on c.leldi-ty cf ph.'n:rl, nitrc: phu:ni:Is picrlc lclcj., C,:tech::,I
,
resorclnol qulnor;thrlr irnpof,tance- r'{aphthors, Napht.ha(iuirton.J r Anthrar.Iuj;1r_rn.r-sg;ucturLr ancl lmportant prtpilrties
. (tZ ilrs.
Unit fX
)
9THE,RS
s synthL-.sj_s-prgparatlon of :niscld, ph--nstcIe, Euginol-Rcacti::n i:f eF,oxlcles. .CIalsen rr-'errangtment
m-'chanlsm, Zcise].'s m:-.thod of u.stj_matlon of methcxy groups(O
Urs. )
Wi1ll,tmo,;:ns
r
Un.lt X .TLDEI-IYDIS irtr,) KITOIIES
structure and r'e:ctivity cf carbonyr group. *,etlucti.n
with IJIAI HA,HaBH4r .rlumi.iri-um fs,:1rropo4ide, Wclf_Ki.shner
rc'duc t 10n, c lemmL5n s. s reciuct i..::r'r, ca.ta lyt ic
hyclrcgo,i 5ti....,-r,
I'Iuclcphirlc aucilti;n t-: e:rbcny.r. orrrup. Acrcilti.:n ::if i-IcN,
ph"nyr hy.cir:azine, hydrcxyrcmlne, phenyr hytJrazi.nr
arid,
rgagent.
cannizzarr) r€3cti':n Reimsr Tigmann reactlon, perl<in reacti:n.
benzriin Cr:ndensatiln snd thu-ir m=chenisms.
Dj.stinctlon b..twu,en alde$ydes and kel.rnes.
ccmparatlve studics -:f furmardehycie .ancl ac-.tarcehyde-arphirtic
and'aromatic ard*hydes. &B unsaturated carbonyr compruncis
acrcreln erotcnartlehycle, mesltyl cxlde and cinnarnarcehyc,_,
"
van1r11n prurparatlru :nd use.s Ardcxime.s anii l(c.t,_rxl_mesBorgchr:s
,
i
Beclonann rearrang..ment .
(18 Hrs.)
, p.lprREttcc; (F,or paper rr ancl. rv)
OrE.:lri'c.chcmistry VcI I & ff f:L finai
Advanc-ecl organic- cfi,:.mistry I tr'j.o.sef ana Fi.c..se.
Guriie book tr rn-rchianism in ,rganic ch;isary]i..t.,
Sy)<es
A t...xt br:r'l< r:rf ,:rg,:ni"
v"t
r
&
rr:
Tewari,
"t.r..riitry
prj.nci-ple.s rf ..n1lil'3Ilfi;"IiI.:
Acvaced :rgfaniC Cirenri.stry _ Jlrry March
Org-rnic chemistry - 1..!Jrris,-;n ano aoy<1
p-c.tvanced .crganle ch,mistri,
BahI
BahI
oraganic chemistry - Fi.:it/.:iici.s::ncrnd
Cram .inA H,,mmcna.
Examination duratiln, : u.=.
ltr.:fghtrge of l.{lrrlcs
Uni-t s
lsrrks
Total Uarks 55
Section A
16 cut r:,f 20 ( 16x1+24)
1B
Sr_.Cti:rn B
..4 c;ut <if 6 (a;<+ = 16)
rr
10
S:-ction C
2cut:f
4 (2x7\ = 15)
III
8
il:;:';ir.
Mc/3.5.20O0
\
IV
v8
VI
vIr
10
Total
g4
6
6
vrrr 10
tx6
xL2
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