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Document 1731736
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tr::i:1c::lciltctior:
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in ci:o:ri*r
2. I nutcs cfrst"r'y (
991
.
tl:c ncctin.r
J. i,Iinutcs uf. tirc r:rcctiu] l'" :llt I''r-curty of scicr:cc t.,clc'i c,: .r,.
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I
_-..--.---:--,---...-
'--/
4. Pass minimun
:rnd
A canriidete shai..l_
Peper ar-!d.l 0% marks
.vtq-
11.
J.
! s It
S=r-'?T
J-Ce
F^r
rru
tiOn
:
L reSS
r'lu aeorr,-:+=
a'-
. J
:lran J!I,, marks ir, each
For Fa,ss in M.5s. I
and
ielte
The
ID^
1-^ re
u
n-I
ll
^t'i
q
set
s u cs
es per tthe foL ) orving
pet+tions carrrij.;rg .
_
cf 2Ll
15'x 2 =r30
ca-irying
5 marl e'lch' 6 out
o""ons
Pi;p,T c- o"tui-t
G x 5 = 30
Led ansuJer type ques
tions
carrying 20 marl.s each,
2 out of 4
2 x 20= 49
FARI
B-
Total
,*
4......
v
t
..i...
I
I
\
l-
3
n
(
lr
I
:
:
(6.rL)
' -1 r-hernistrV
thaoret;c'''
PaPer 'I 'l ur", ^r \
unitr-ri01 o'"-l:"'r:]*i.t;'
(211)
_L..racter
or
Trr':
iI
,,
a) Basic f:"'_=^.:t"t' or rac;:-i.o..$rave.n.'::t-"^'o1,.,,
:r_.";_^:".-rr;:""t;r"".
cherac -- ..:rri j . El
e :trcn ur ' 'particie
'r"raicjes.
i'ia*tt:
-:' -'
u,"'"rt.t",
o"l',^:,
ics ,sL|^-.lusrs .
;'. .r mechan
b) postur t"=-""":ri:,
Fostulate
,
rhr
ton''-oo.rators
::=:;"".::":",,1t"."0."r'="",;t"= Lj ,,
of
oFe
_:l_: val,utss
corre5pondi"n
opc--,,a..1
j-cns' t ^"1-.
;::-r,,. rre i:::i,..::";xpectut;-on
equat
Hamiltonian
.".
;:i,:::;:',.:""=
t
.r"n
co o r
cl
n
t
o
in a t
e
"'
s
".
",
cartic!3-gr-'3n
;;=".;..,ed
he-rmon i'cs
'
s
L:::
n
schr:
.-,ti.mensir,ra_'
^o-Cislensic'ra
B -rts
in
Ln
he particle
Po- -The narticlr
values
aI:u eigen
''x : DegeneracV'
''o
H"'".:::--.
The
'
The Herul---'e
-^i1rator.
;l:1 {"=::'""#}".1".:'.'#
:'"'"
,
valut'"'
';,:,;;,",.:;:,",:i::i".':;T;i"::::.;';:'," a .w : i
The sgn:oo:::-'_,'rn"
l
i, r,' t. t:= -:.::t'.t"'_:".';=='
ph e i e t
-:.,nnlTl
1
1 r,.,
-.
"
*o,,,,u.o,u
".-0"
;:'; :::,:?;
t i.,., =,
s ph e
ano tr-e:r
vaJues '
"^^0""'u"ton
Tk*#';*ipilt#:::;i:
t
soilution of
o.tr^nol
,:";;"
funcirr,,n=.
i ssoct.*.nn :;t;"ror
".r,
Dis cuss ion
i+ ica i'ce '
ign
s
-. o" tn" "
iL^,,,x;'":'":
l1i:; "ii=:"
hYdrcgen--'
tftttt'r
helium aton '
0rbitar
,,,,
I
l'
ffi:,
;. r yn o* t "r i --'-,
ccr
I**
"
;
diasrams
?;''"
;::::':::1' :'
-.'/ \
j'caticrns ' St'rrk
The veriatic'n methoc ' Simr 1e appl
s tate of th=
eff ect in hycl rcgen-l:i ku aic)rns ' Ground
helium atorn.
f) Electrc,'-t sPin (-'-t
of orbitel eniJ
Spin functions and oP--irato:rs ' Lcupling
princiPle ' SPectrcspin func'ii'ons' Pauljr:, exc'Lus ion
scopic terril sYmbols lor atcms'
(
S) ComPlex i'toms 3L )
The se-Lf-consis'c'
Slatert s tl'eatment of camplcx atoms .
(brief discussicn )
field method. liartree-.'Fock n' ethod
eferences:
McGraw-liil-r
.'E.Ieneniary Quantum I hemistryr F'L'PilarP
A
2. Introduction to Quantum Mechnics ' 'K 'Chandra '
Tata-EcGraw-H i11 '
3. Quantum Mechanics, Strauss' Prentice-HaI.I
M.\,'|l .H6oo6l
4z Quantum Mechanics in Cherr:iatry l
W.A.Benjamin ' Tnc '
( 15L)
Chemical Eonding
a) The hydrogen molecule ion (3L)
ground state '
The molecufar o=bital 'heory fcr tne
+
and
Excited s tates of l-i ' The molecular orbital
state cnly of
valence bc-'nd t're&tm''nts frr the ground
hydrogen moiecul'e '
R
'l
,;
t:
Unit
,l\
T-4Oz
diatomic
b) M0 and VB t-;eatma 'ts r--'f mol-e 66mpiex
(3L)
moleculee (qr'llitl-';r'i:)
be discussec es
Lrrt Be2t L2,'-2, NZ' 0', artd l--, are t'o
LiH ' 0o '
exampl;s r'-rf i'c*onuc iJar j.e tcrnic molecuf es '
heteronuclr'cr
N0 and HF to b-' d:scusned es exernples of
diatomrc
noleculas. 5P-ctroscr- 2ac 'terrn syrbols f or
molecules.
c) Comp.l-ex mclecul-es ( 3L)
Directed velence
Localised bonds ' H Ybrid o rbitels.
be treated
(Methane r '.''qte::, ethYlene Enul acet-Y1ene tc
bond lengtt
as examPJ-es) Bond PrcPert -.es: bond energy,
anrl hnnd anqle.
c1
l.
)
..
e) Forces :i :.';:r"=..:t'"""
LLzec
,its
The generr
em
is..rv ,
F
.L'*:'i'-'.
i" '
'n""
"t
, aLEa.
Phvsi-';ai
a-n'd
theo:em
::t;' , .= :'.";.
* 'c 'Da Y ano 'r "'
'
u'
-:- r-hb{ntstrVr
9c}r')' 'tlr'0r$ahac
'd
i;-
Y
( 1BL)
Unit
T-403
i
,.Theory
_+
a'i
u--,--^r
,-^.ic, r vibr
ectronic
lines.
itv or spectrar
or thc '::i1" 1;.;ns
s'-"::'.::=;.:=,li*,^..*:.'.
::;;."r"naI
Lj
i
,-n-= r.ro.
Transition
I
\
r
rules '
Depeno,":: ."_:
:.o =rt-".*'ion
i l. i'' i': s.
; r:;. r
t ;. t io n
..
r_::::r r
nc ro
1
. .,
- r.'.rJ::
j'bra:tienar
r.r:"r:rr;
"
u) v
t d'v brat-"-:u',}"r, spectrcsoop,' Rarnan szectr j
.
ibra"ti:no1 r".;.,
t;".;;.,
Rotationai
v
'it"-'_::.";
tntrl'_u, =i""rror".,o^rr;"""
ber
Relation
Hera"-"'
spectra'
rotationa'
,tr";;;".
lnE iheory ' --^
The
sPectra
lnfrared
determinat
Jt'"c) SPectroscoPic
=)
r.5g IiIiOO
. Ia r.5g
The deterrnination ^,,'.
F
u'i"urotio,.'
erce co.stant
., mcIecuIes'
'
anc
R ,man
__*,.s(6L)
att'
.tt-=:;":r:."',,
and applicatlon
theory
a;.."ciaticn
Generor
cPv: 5en'
-!rr
to^;'.;;rre
EsR
mol-ecu"='
Nt4R anci
o
*..
i;he lecrronic _^+
tc
to the study
Differeni
I+c :eretion
Electront' '_t".:r';;,'
arrangements ""'--.,electrc"-arOtt of
:;";"1, ".t '?l:::
L,-
-ira:rsitions"
i. =p""" c'
...6
\
zG
References:
1. Physicel chenittty , F.i. l--n.iefs and ti.A.A1bcrtyl liviie:y
2t Moiecular spectroscopt, Berrow, l'lcGraw-Hil-l1
Fundamentals nf F'l o.l-ecu-r, r spLctrc;scoplr Bernwcl-I ,
Tata - McGraw-Hi11
L Atomic structu:e and chemic,-r1 Bonding j-ne.l-r-, din.-r
MofecuLar spectroscopy^ Nianas Chanda, Tata-ElcGravl-Hil-1
5r Physicel Chem-istry, P.w.,",ti ins,
Unj
ELBS.
(sL)
t T-404 Nlolecular Symmetry
opeletions. The symmetry
point' groups and their systernetic identification.
Construction of multiplicati.on tablr:: of simple point
groups, C2 V , C3V and C.h.
Symmetry elements and symmetr'.J
References:
I
1. Gro up theory and s ymmetrl,' in chemis try , Lowe-I1 .M.HeLl
2. Chemical Applicetions of Group Theory r F.A .Cotton
'
Interscience
3. Symmetry in Chemistry
';.H.Jaffc and M.0rchin.
Wiley Eastern.
4. Fhysical Metheds in Chemistr3rI R.S.Drago, W.B,Seunders.
*+*t(t+*.r(**
I
t,,
kns
/ I azgz
S-.\
i'1
7
paE R
unit T-401
lr -
ri{Gl(-i''-I.] :)iEl'lIstrr.j
r)
(r r)
refini-r:gr
occure; -rc' er(ttre;tionr
J;l;'**r
(eo
i
sr:ecific
uscs
ancliri:ortanta]ioJ'soiplatirr:,.ici;ais,ccri.-li]ancltiroriu-,.
I,rincipl,:s oi lovclcr nctallut'y' I EI;otroclunicel ilnory of
'
L{eta}Iic corrtr;ion a:ril Passivitf
iretallic corrosionr Passivifv
anl protectior- agailst'
nctals'
Referen ces
c'f
:
C'l'
:lani>el'
Sookr
1. Rale L{etal iDacl
!"Ietals' 'i:'H' Darnis'
iion-ferro"rs
of
IIetallugY
2.
iorrosionl T' 11' 0iri-fton'
i'
}1:ta1f
of
]. PrinciPles 'flcL
. r \.,,ijfdu
of L{e-:,Is, F-'C'Eva::s'
^-.:.'rar-i
Corrosion
Rot}'nry'
{.
urd d}oys' H":ae-\tr'
l'{etals
l\ttrrs,
Electronsl
!.
(tz r)
jn c&ion Corl:o-unds '
Unit I-402 0 o-c'rd
cffectr
or conplexes' Cirelaie
Tltc !-Lri
IornotiQn ancl :uab--Iity
of ldeta}-IiSarrl bond'
llab:rrc
-r'igand Ficlc.' tl:corics'
' i.r.crocycllc ciicct'
:';ays'!al ' icltL ar'rt
Bond
yglsnqs
spccttroru1e,
Jaiu-tcilca gfi'3tr
siaui'Lizaticn'
Ligaacl f iclcrin int-ro<Iuction to tic
cl:enical ooc' ofrcrauxitic
thcorY'
L[clecuJar oro' tal
s'
I
i
ii
Ir
ii
/
rjr:s'
1l
dnr*nnGWilkirson.
frefercnccs!
LJv
sv\ r' Ci:cnisEYr i- "'l
llorgt*llc
1. Arlvancecl
andSeibi-n'
Ct:er:risbyr l{'C' Day
fiorpnic
2. Theoretical
J'E' Ii-ureey'
1. Inorga:ic Clpn-stry'
a Joilson'
Clrcoistly' F' lasolo
Co-or'-ination
4.
i
I
;i;"Illll':i":
:: **:,;;".ffi"Jil"1
rb,tlru''oTl"
7. Eospccts -fc:
i:ucrre
Periotlic i"Llcr G't '
I
(;r)
]I
ll
(r'r)
flEilJ;l:l"ill'l'-ltlo'
I
I
Contrf
vG-
I
Unit f_{O) L;rllisniclcs
a.rj Cct..ri.iics
fti;aration L.y ion_e_yc]lirrj,.c
lt:j(.I __"__ ,c:. cxrrac.,.ica
rrrcctronic conir.;rr:.tic:.
o:c:,iat._J.u st:.tcr
o bonic
::uilii,
abcctptio_:t c:;ggf1g. r !,r.,..^_.
ct:c^rsfuy .,vif.i, t,at
rt.
cl:elatcs. 4i:i;11os*,^
L-ullsi)J*' ' a''
";;,,,..;;:;il:
.
cet i'h arx'l .i
- clcnr:nts.
(t t)
nsiltcGs.
ar:cr ion-:,:
:;;H;:*
-'Yans-actrnicle
Rcfeien ces:
. Cl:orui,: try .Li, ia;;il:anic
_.1 , ,1. oeLfer.
Z. ?lre Tlals_urr,niur:
EL:r;o
uu, .,
ur ar o
--..v. +.
^]].r.uorg.
3, lfa.r:_r:iarre 11,e.r:s_Lu
Elencnt's' c]'ir' &aborg'
4' rrorga:ic tirrcr:r.";*ttot
5. dclvanceu,rnors.,."';,;;I_.I,Tr..,.,otton
1
.
o
uxit I-404 lrorganic
Rir:ars anii Cl:ains
Irorg ai.c
ll terocJrcles :
rinSs' Pclyprrosp;;;"
Icrazinesl
rs
o
r:oly
Referen
tI
J.,rr*""r.
l
I
,l
G t')
L-onl
rvii;d:
"qPot.ncLs
Polyne.r-i
Cor
"*,,,o r.o..Ill*'"
i
i ro' 11"= ",
s
s-Ii'
P-ltr cnri P-s
: suii:l:.ir
::ifu icle.
I
rJ : c on ec
,4
t^
.l
ii
'l
cs:
ii
1t
r.r i c
-_,..4r
-I',:
li
i-*- uJ,
l
l1
rl
)i 1.F. Irelis.
ll
l:
F.A. Co0ton & G. WjLkirco::.
eJ.'.
II.il.
l
I
ri-l_Lcoc
k.
I
l
. IIt: tr:l ens (ed )
ar:aher (lr ),
/: .t)p 11J-rZl.
.
l
I
t:
lr
I
4rr.titqo.
rcl: CiEnish.y,
I
i
i
I.rn
Conkl_.
ie'
'l
i
lr
I
I
3
t\
()
init
ic ien i;
r-405 EI ec b;cn-Ief
J
l',\
cn1:oundo
:rni i'cnillng of boron
!cl':tic:rs' str-'rctr-ic
Polylrdra-'
oqr-ra;'i'cn of balance'
siyntl:csis1
con"ucun0s'
Ilvilri-Jcs and ru$ateii
ca:boranes an& nct*lfl-obo;ancs'
a;rions' A bric i strtly'cf
A.
G.
Cl;c;'Lis';:-'yr
-tI'J'Enc}e'us
Sharl:e '
F'A'cottcn
2. .Ai-l.vcncec rr:orgm c CIx:ni*ty'
J'E' .-:1:cey'
Cirr:rist:'-''
Incrgmic
,.
Unit
I-1106
'ot
AoiG-base
ancl
r
r'
I
&
G' vlilkillscrl'
(e
r)
eta-l-]oclroaict fluorescent
cbni.luninescent inrlicitors'
I,:eference:3
1.Ate>:tbookofQr.:entrtati-ucTrrorg.?,'icnnd.7cis,A.l.Ya.e}.
Skoog & D'I{' lilcct'
D'4"
Cl'ienl:itry'
2' Anal;iticcl
(g r)
Solrc';rts
lTep;@1]c'ous
Unit I-4OJ ;leactlon il
'solutc-::lvent i-nterecticn'
solvents'
of
ol'
Classi-f icati
sclf-icnizationot""t.,oot"'Reactionsirlliquiclurnonia'
s::--i;iui iLicxidc' orx}
liquicr
fl-;ori0e'
''liquic1 lryd-rcgen
sulPltuic acjil'
ile-lcrenoe s :
'
2'
]'
1
rclrE i't:;' Ii'li: Sislcr'
Cl:cnistr-v of lion-r'cluecul t'iiiri'1-din!:;on'
- C'
licn-aquecus Sol"enir-)
Ia;' a Sclbin'
'rr'
t)'reorc
Unit I-4OS Inorganic
bic"i I:r':;genic 'tnnis
i,['C'
(t - )
Pi-;"rcnts
lc ' rtlir arrar ile
I j-taniufi clio::iJc ' rcil
baJetl on zinc s'-'lilluiLe '
,-,l..
c
rc
'
Lr-rr:i:re
scent
i:ignentc
lf
I
i
lheo Y cf InJ'ucatqs
ved'ox, aclscrption'
i
i
I
Rcferenccs'
1. L{o<iern Aspecls cf Ino::ganic
-,,
cierence s :
l.Encyclci;ei.'iaoiClrnicalTeclrro]-crylf'ir1.--Gblr:orserics,
vol' 15'
D r'
ra && J':i' r'oqt- (at)
- .\ii.R"
i'r.r:' 'lS
q lrarf T.
l<'
trractica_i f Inclgar:.i_c
Cii6;11strf- f
U:rit f
r Ar._
v: 1u'l-lr
,3 are lc:.; fan_-.
ia:
?rrr ,rir zr, ,{,
u arr .:l'i:i::_
",,j.u
r?
tt
VOrrrdric netc.i.li:leticns
a) EDI?I (zn?+,
'b) cerinetry
c
,
) i)otassi,;n icrlei:e
a)
ctr:.orami:re_I (so,
-f
..,,,,-
t wc ,
aDLi,l' ac'iil. r,:iitca1s
'-.- rr!
nc
-ter_r:c (.1.1 t
srr
usinp;
,z*, co2*,
(.r52+,
r-rf:-c.l
rt: .,, ,, *,';j, ;":;:
i;rcsc'nt). Ccnfj.:r.;at..'-'--''-'
-l by si;o i
il-a "' +
\ib r.j)
$:ij.:rs.t ion ani.l
iclc::tifica-.-;
kgcincss o,l -vyatcr)
nitrite)
( __ioclicLe,
s.&)
oihito)
(g rs)
Ilnii fff
clroniunr 11orr manganese,
il:rr Dubascct or plptooLecbic
.\,efeier
ce s I
1. :'i ?ext riook c
,r.r. v";;;.* "f Qttotitatirrc rnora.aaic anal;,,sis,
2. ,halytictl C.ani^+.._ r\
^ -
'' r2lr.:t;1Lit* ;'"'.t"; ;;:r', :,".:,: h-r;J;,
4. Q*aatit,ttiva .,rnaI;rois,
tr..ul.
)ay (,r=) I i.r,.
gntrs::lyoocl.
Iin
contd.
b
I
fA,
n
Paircr
Unit
o-401
IlI -
Qrga: . r
(oe
Cl:cmistrY I
r)
(u u)
Stereo Ci:enistrY
o) opti"o] iscr:cri-t (e;')
:rytica1 aciiviiy due to
Molec.-rlai clissl'cr.6etry a.::-l cirirality,'
ccntainilg nore thar: one
moilec,-rlar e'i;j:ucture an<I ccnllcr:rrls
absolurte confktraaqn'rnet=ic carbon atcn' ?'el'ative ancl
j'sonerisn
(R
S
tions. Sequencc ruto a rI nctation)' Q;tica1
atons of conporrncls rtot coniainiry' asy:u:reir:c carlron
Biplrenyls,alleneoancl.si:flans'as;7r''lletryc"uetofof(J-ilge
cyclooctaae'
helical- stn-ictur:e - IexaL-elicenes i'-d tcans
ancl sulpll:r c o4)ourxls a":rcL of
Q,tica-r- isonetisn of nitrogen
substituteci
cylic anct bicylic cocri;or:nrls' (Thr:xiLic acicls and
adananteaes ).
,o) Gecnetrical isoileri-qr witit partiqular refercnce to rjrrg
fron acyclic
conpor:ncls . E-z notation r';i-tir iuus,trations
systens.Lhtho<isofrfctc'riningccnfiSr:rationsofgeonetriorl
isocrers-cyc10tc}aI]C1icxaclr1qoc1c}olrexanes-conpouil.1s
(1 t )
containi-ng il=Ii arrl ltrIi :'cuble -:oncls'.'
c) Confarnational AnalYsis (e l)
of '1, 2 - '1il:o'Ioethone - ileternination by
of cyclo.
.
neasu-re[lcrrts :f dii:oIe r:'cncnts ccnfcrrr:rhtions
confornation of
bt-rtane ancl :yclopcntanc" Detailcil stucl'y of
cyclolicntare.tretrilc'lsh-Lyofccniornaticnofc;-cloirxancs witir cllerly consiclr iati-cns- Jfulc bli'Ir dilulo'
.lil5r.irc>ly c|rcIobxancs, all' 1 cyclol:cxanols' clclolcxane
systcns'
clicarboxyl-j.c acirLs' Confornrations c'f bicycalic
i,hclir:n ancl large rings fursec] ring s;'stef,Is -'decali:ne'
decalyl
nonosubstitutcd clec a}lns, 1 anci 2dec CoIs arrl
ani:res, Ccnfcli:lation arx] reactivi'L;r - rleactions at
ancl
exccyclic trcl' of ri:cg 1:csitio::s - sleric control
Cohforr:rations
stere oelectronic f crctors'
Contcl
VG
......
\
L'Z
F.cferc--loes:
1. E1ie1r stereoclrr:iistry of carbon conporx''lis ' 1962'
2. Eliel, et aI conl'rlrnc.ticna-1 analJrsis'
1. Storcoclrcnistry b..r K' l"lisicw'
4. Steri-c eff ccts in'-L'gerlc clcnistq,'EcL' - I'-' i' Ilcwnan'
5. Conforneticnal tieory b;'' i'i' ilarna1"
5. Finai Vols. I ani-L II'
(t+ t')
unit 0-402 -r...i,.o.lucticn tc i;lrysicai c:-,:l,rj-c ci:cr:istry
a) l,tcctrcrlisll rrritl: s;tc,:cocl-rr-..lstr1' of ,ecieo,hilic substitution
substin:ent e-ifeots ( lom)a:t'ti-;e sir-d"' of the inductivc'
nescneric, eiecircncric, iniirrctcnc::ic a::cl steric cffects
on
reactivity
basei]. niai:tl:r
c:l carboxylic acic.s ionization)
ltilil
b) 6,uantitaiivc cor=elcticns of substitucnt effcct
slecial reiercncc tc ller:'r:ett ana !'ft equ"tions' tlrir
.,
ai"plicaticns anrl r:ter ic sribstitue:rt
c)
'
cons
tants'
sclvent
Solvcnt effects ccnprisi,ni basic asl:ects of
of solvent
strustr:re, enp:irical neasiJe colJ' i)ara[Etcrs
poluity (iilc y-va1ue )r lSrlro,,er oondirS' Sa-1t effects'
(i t')
Carbocaticris of si:recial i-nterest '
Refer.--nces !
Carbon Aton'
1. C.lr. Bunton, liuccclllu-ric substitut:-on at sah:rated' (A
serics of
(Vof. l of r!-eaction L,iecluaisns in C=3anic Cir.iistr;riionograpllsciliteclb}IE'D'il4i:es)':'l:evierPublrsbiagCcnl:any'
l,onclcn/I{es York ?9el)'
(2nci EcLition)'
2. Ifue; Plry-sical Qrganic Cl:r:nistry
(1952'i'
Iric Graw IIiII Bcok Cor'n:arlr Lonclon
Cllnistry'
,. L-P. Ilenncttr Plry'sical Qrg anic
T'orr1oa ( r %o ) z'a ec ition
L[c Graw
]'iili
Conpany'
Ccntil.
'l
I
ls
i
CI:cristryr
Koso.,er, An Introluction to -Iysica1 Qrganic
(t9eg)'
Jotn iTile,y and Sons' Inc', Iier' York
. E.i(.
.
Cllnistry (Z'O
R.A.Y. Jones, Plrysical ancl I'{cclia'uist:-o Qrganic
(t994)'
Ed.iticn), corUUge Univ' Press' Camtbriclge'
2ncl
Je:=y Llarchr &Ivarcecl Orgaric Ci:cnisiry'
;.
lnit
0-405:
er}ition'
1977'
(r t)
ilcirlity/nasicitl' of Qrga:ic Conpouncls;
cbtcrninatiolt of
Evah:ption of aciclity ancl basicity arrl
aciclity constants fo: strong a'nt1 lvealc acids'
Ifurnett aciclitY fr:nction'
Rcferences:
tr
,
'i;:
( a'A pO" ' )
f . iliae. Plysical Organic Ch:nistry
In1 Grow
EiII
Bock Corrpanyl I-'on0cn UgeZ)
Ir
lJIc Graw
2. L.P. Ibnnettr ?l:ysical Organic Clrenistry'
if'evailable'
LonrLon: (1.40). US 2at cclitj'on
iIiII
ji
Oonpmy'
,'
I
il
(e l)
Unit 0-404 fV trbee RarLical Reactions
lil
il
lr
Sor:rces ancl futcrnination of
Stability of trYee raiicals'
freerailicals'cheirrreaction:'-retarclatiol:anclacclcration
and stcrecof, anl rniluction peri-oil of ' Structur:tl
clnnioalasirctsofrarlicali-rrtc::ncxliates,free.raclical
oxiclaticn arx'l sub-
substituticn reactions ( iirlogenaticnr
stltuticns involving aryl rarlic ats )' Rearrangenents
fragr:rentation' carbenes
Rcferences
I
flnc1
nittrenes'
t,
I
filr
:t
ll
li
rlll
l?
1'I
I'
li
iI
!
Clrenistry by J. Marcir 2rO erl' 1977'
Clrenistry ily S'u' Muklrrjd' a'nrt
Qrganic
in
Meclpnisrr
Reaction
2,
S;P. 'Singh 1975'
C]rcw]a
I'[ecilanis: by V'S' Parna: aJrl H'l'i'
neactiom
of
Prirciples
l.
1.
[,,
ArlvanoetL Qrganic
o-,'t $r'ln ^ 1978
.
li
l1
Ir
tf
I
\
J.*
dr*
,:7
| .,+
upif
0-{05
tsasic
Reac
ticn
\
L,b
clrarri.sns
hz r)
o) i,.b"l-,onisr.is of e,furi:lation
- effect oi, base, steric
effect, stcreoclrcniotl;.,
forolytic elininatior:s,
classification of eljni::ation on
il:e basis of relativc
i;ositions oI ilrc eliainatirr8 Liroui:sr conpetition
bef,$reen elinir:ation
and. sr:.bstitrrtion.
(e f,)
U) t{cchanisns
cf pclar aricliti-on to carbon-carbon
nultiple
bcncls - arklitioh of lr.,logens,
of si:._onE acicls, of
carbonir:n ions apc1 cf netal
ca;ions
(i
c) tlcctranisn cf Ester. l5x,1ro1y,sis:
Acyl _ oqfoer:,
ali'yloxygen fissions of csteri-ficaticn
anl of
lrydrolysis, reactivity alrl catalysis
ancl
G t')
References:
1,
E.S. Gor:Id, Iyleclraniscr arC structure
1e
Jack lline, pi5rsical ftganic ClnnisLry,
i:t Q"ganic cl:onisiry
5. C.K. I4go1c1, Sf,n:ctr:-re arrl l,{er:hanis.r j:t
2nc1
eclition
ftg.
t
Unlt 0-405 ,lronatic ity
ancl
ed.ition.
2nc1 ccln. 19G9.
4' D'V'SaItlrope, Elisi:laticn Reacticns, Elsevier publis,ing
Lonclor 19Gj.
Znd.
19G2.
Ct:enlstry
Co.,
+ronatrc substifution
(g r)
Tlnories of aronatic cl:aracrer an1
clelocal_iser] bcncling.
fuclclrs tlreory arrL iis al;i;iications _.xi:faini.nS
aonatic
stability' Encr3lr level-s of norccular
orbitars i, si'1:1e
rystens
'
Ircn -benzcnci',r. a:,'c1
i)seuclsaxona
ti-c
l,)
coni..or:acls.
Alternant and ncn-afternant i:;rcLr:ocarborrs.
Honca.rorratic arrri
antlarondic syslqn5''lnriufenes. Er-cctloprdric
ir,ionlatic
srbstitution. ?hccry o.f reactiv_ity
arra orientation.
Q,pical cxanplcs of clcctroi;ldlic @orratic
sr-rbstitution
nrc c h:lr isns
-llj.tr a t icr.:, Ih1 csen rtion, .qb j-e.Iel _craf
ts re ac tion,
sulp]ronation.
Ccnfil. .... !
t
'I
1<
sul:s';ition
I::t:-':IJ;:l:::*
uLlese-'-r:.ucleor:lr,lic oronatic
nccl-''risn - cl-ne
lenzlnc
ovj-clences'
anrl
(5
trct';co
)
carbcn - ltr: '-'-:c '^"'-riiPl: -boncls
-Lc carbon j-t o-40T Rcactions cf
a'r'ilitions
Ilecleci;llilic a"f "fe"troi;hil':-c
r:cniis' t'"-ct'anis": :::
cqtgen cloublc
il:;t+,.|::ttjl''u"''
cnirtes'
']*:'1"-'I
cf ilater' a-'l-cclrcls'
benzoin conclensat:":t-:
Dieck:an:::
claisor::
":
-:::j::::*-'
'o'*"'c:'tir I t<'"'*"so''
:larz
ticns'
r':#;j;:il**"'
-r
reac*i:'::
rj,,s
of
irlarmich anrl
^l:"Tt-"reoclrnistrv lnrrlro-
H:HL3"r#;Jffi;l
ion
a:ncl
:'::'"ioai
}ysis.Ifur}rc}ysis,alcl:clysisanclreclucticnofnitrilesconclesaticn'
Riti;cr reaction
mc1
fhorl;e
405' 406 anl
ireierences foc 404'
t. J. Mcrclir
4C73
rtkllancecl Qrganic Clenrsfyr '
tOrgamic Clcnist/)rt '
noyl
2. l'llorrison arrl
* *:;:
,Guide book tc *"""*'"'.
1.
*O iY-';:u:onc1r ' iganrc
ttT'
".sylccs
Pinc, ftntfriclr'sonr
Siinbcl-'
",.
Chenistrlr - Carey
Org'
5,.i\il-.
rl
'l
:::ttffi.
1\
Ii't
I
(i t)
il
to pclyrrer cr'u;ristry
Intrcrlr'rction
O-4OB
Jnit
- clasces of 1:clyncrs
l
?rinciplcs ci ?ohrnerizatr:n
crosslin}ctl
synthcticancl.bici;olylrers-cirairtreactionl;o}tr'rirerizaticn
-Ljsear'
ancr stel; ::eacticn'"';;iza'bion'
ionic and r
Fveo-:adicaf
rubber'
a'nc netflcrt p"fyt'"t"'
I'IatuaI ind' sy-ntlttic
,.\
l1
l
,
co1ol;nrerization'
i:';,:;;.",,'*,
Tl "'*::::.::il
::ffi" J[1.
l
ts
l
f-\
\
'qr
1i.
J.t3
Practical fI - ftganic Clcrrls,=;i f
;jn
it
lai:craiory
GG
ts)
?cch:rique s.
of seporation r-t- i)u.rii,..abj_in cii organic coni;oundr: fractional, stearl ancl 1ow-::.- .-:lure,.Iisttllaticil, fractional
crlistal-Iisation un{ sutr1ina,,ir:l: .
(1 rs)
i.{ethq.1s
Unit Ir-- Sel:araiion aucl j.:ri:ntrfication :f
ccrlt)onent..;
of orsanic
bin.r'y nixtlrrcs
Analycis ci iitc:-ri a d.ozen ni-r:t,:es, or. ,..,cr:re of rvirich
containing conpouncls ,r jtir r:rore illan ,l:2c functicnaf gr.ofir.
(tg ts)
E
.;J:
-,:
Unit fII
ft3.l,nic prcparatrcns
aation of
(at least s!.<
cLoubl-e
prei)aratrcns) il_tustrat:::1 inr:riant synfl:etic
"tryo
Prei;
nrcthocls alcl
about t-,,rcIvc o=3anic coni)ouftr.s
reacticns such as i=yiciiej_Crafts reacticn,
Gri3nalcl, Perki-::, Rei'er-licnanr, S.-a:hrc7er, ancl Canr:izzaro
reactions, C'laig at, a1ilcl, anl benzci:: ccncicns.:ticns.
ft lo ct rv e re cluc t i-on i.:r p ol3ai i.'; c ar oirat i-c c cn:; o-rncrs,
iliazccout;Ifog, plrti:a]ei:t iusior
114 LS)
"i6.
i,cicrelce
s:
'i' rL r' vcgel-, a text-'rcoi. of plactic c organic
ciciii-siry.
2. Slrirerr Euscn anrl Giillfp., Qystc::ltivc Id.entjjicaticn of
or3axic coniiourcls,
,
.
Exir r
Q. L{an:r
q
:.--c .n
ts 'iil
1,954,
org:n
aril" Saur:iicrs,
i
c
c l:e
nis
jry by F ie se :. .
practical ftgat-j-c Chnistry,
1g57,
Dcyr Sitaramanr ancl Govir:clacluri-, . Labore.tory lriannuai of
Cfganic C!=nisby, 1%T (ttrirr.t eclition).
5. P.R. Siirgh, D.C. Gui,ta ancl KS. lajirair Experinental &3anic
Chcmistryr Voh:ncs 1 ad 2, 19C0.
'trL
tr
'I
l7
. . J.
--4,O---.
Paper
IV - PhYsical ChesristrY I
ne Solid State
(66 L)
(
18
r_)
) Semiconductors:- Their preparation, Frcperties :rld iiecustrial
importance.
cf sol-ids: Imperfections
) Imperfections anc Physical- lropertie,s
and plane defects '
defects
line
Cefectr
,in sol-ids:- Point
properties
:physictrl
Nonstoichlometry
i. Electrical properties Electricai conductivity,
HaII effect, cieleatric properties, piezoelectricity,
ferroelectricity and inonic conducti-vi-'uy'
optica]_ propei^ties - pLrotoconductivity, luminescence'
li.
colour centres, lasers, refraction, birefringance.
li
111. Magnatic properties - ciamagnetism, paralnagnetism,
ferromagnetism, antiferyomagn3tism and ferrimagnetlsm'
iv. Thermal propertj-es th'-'r',nal- couductivity and specific heat'
eference.s : ''
1, Che mlstry
of solids, A.K. Galway, chai,man and t{all.
2. Introduction to solids" L,V. Azaroff , lilcL.:rarti-Hj-l] '
3, solid state ctrem.j-stry, l.l.B. Hannay, Prentice-Ha11.
4. solid state chernistry, ,)'. .,\rud Hedivell, Elcetlj-er.
53 Physical chemistry, G.Pi. |larl'owr Itlc.Graw-Hi1l.
6. physioal chemis lry, Id. i . I{oore, Pr:ntice-lla11.
I
t
I
I
ti
I
i
I
i,
I
t,
ri
I
i
)
nit P-402 Crystall-ine Solj-ds
(6L)
Crystal Symmetryr Point groups, 'space groups, crystal
systems. Factors affecting crystal struc$ur:e of simple
inorganic solids cf type AX, !J.2, AZXZ and ffi2X4. Crystal
imperfecti-ons.
fl7292
contd....Page
20
i
/1
\
Referenc€s
1.
*2C.'-
:_
Advanced iviethods
tallorgraPhy,
ace
G. p. Ramacrranci
e L:',.'
z. *"n'o "o'tcrystar.r.
';;;: i;|il^
:oD,
"":r
*:"t;, _- a ilrier
hi.H . F"u.ru"
^'' -'--r:t'r-I-Ll,i2
^ ,.-, ^ o-compendiLri
;;--rq jJ:ot,
eor
i'i
'F-' de JonS'
unit p-6nu -,
Thermodlaaamic's
a, ,nr",oo'
i la ' of thermodJeranics
,,
s
tater,ler
una
tuirrl,
(12 L)
termina
.. : : :i:'
1" en'Lrop :
:IJ
.iT .,:"-: ] ." Ii**:ffi#
;"li:I,T':J
1'.",""'1,
"t"'"
..oartions o,""0
generaf *"t|,'oo'na'rics o>nfrrec
,o.-aiuf,
.,.** .,,n"lnol
#i;h';*j1:
vessiur" p"romi.cs or
Re
ferenc es ;
-'f
""*qtcr,loQy4amic
:'ierrnod,rnamic
"
"['":":'#:
irr,
utt"'us
i
simlrr
The
e
o;'
rxaoples
; ;";;A
":":;r""""'
"" *:: :titnn
1, physical
chenistry,
a
Denie: o anci
2. ?he lrr thema*r^- ueniels
a-r.ber
1'
lr/i-r-e r.
Murph , uoitt:" of pr.vs cs :nc che.ristry, 'o?"
I. r, cr*;.';. "" =.0'-an'.1,,l'' ,." rr."*"man
:
s,,stems
..,t)
rh e
i'"::]iliJ":-'^'-.'.:
-;';;';'
-ir"."r'"""
T:"::"H.t"*rt,""'
"or*u.
;ml'", .x":
=.",T:"""t rela;#:'
""T'T::::
*n"*"i
Fr€ssurr
on'
o.r,leren c s''t
s
i'"J;
*i
T:-*:'ff"1'#'
(;
Parllql
to
Exces_q
e
-:i
of lrre-
]fu
and G.1i.
1ZZ9Z
ccntd...p ge
21
I
lr
it
ii
i'
i
!,,
ii
-
\
\t
1
2
1. An introdr-iction tc Chei1j-ca.l- firermr:dynanics, R.P.
and R.. R. Misra , Vil'. ^s .
R.astogi
io,
An Introcluctirn to the Qrer. rc,Cynainics of Irrevessible ProcGs;
)j
I. Pigcgine, Interscience.
Statrstical :''ec:tanics, Therinodynamics and Klnetlcs, 0.1(.'iic-,
eS
Vi.H. Freeman and Company.
6.
Cl-remical Thermodynamics
,
Yerami
; , rulir Publishers, Moscol.
I
;
I
(18 L)
t
f
I
llr
rlii
t P.' 404
'.,i
i:l
Electrochemis try
ll
Validity o.f th.: Debye-Huckel Onsager .equation (.ro derivat.ior:1
for aqueous and,non aqueous so.lutions, deviations from tirc
Onsager equation, significance of the degree of dissoci',-uiri
and its determlnation, ccnductance ratlo ar-rd Onsager equatj-r'.-:
disper.si-on of -con*uctance at high frequencies-Debye-Fal-keni:i'.. .
effect, conduc-Lance with high potential gradi.ents. 15s pg)--:,,,€
Hucke1 limiting law .:.nd its various forms (no derivatlon),
Qualitatlve and quantitativl, tests of the Debye-Hucl"el
'limiting equation, octivity and actlvity cc-efficlents j-r,
electrolytic solutlons.
vi.
il
ifi
rj
,i
F. Stanclard electrtde potentials. Factors affectii::g el-ectr:oci.
pctentials. Lbsolute single el-ec i i oie pctent:-als. Rates of
electrode processes. Appiicatic,ts of E.l'i. F. measureffents
irr the study :f comfrlex- irrs, f' S;a-tility ccnstant, dissociation constant of wear ; cidei ;.lr:.d i'ed-ox titraticns.
Over voitage. 'Iheories c 1' ,.r-rervolta.<e.
I
l
References
t.
)
i
-
D.A. McInnes, The l'r'inciyl':s o.f Electrocilemistry,
Dover publlcations.
S.Glasstone, Introductj-on t.: IJI-ectrochenristry, D.
Nos
)o
:
trand
I
lt
l
Va.n
.
Bockris and Reddy, Ivlodern Aspects of sl-ectrcchemistry Vo1.f
and fI, Academic Pre-q,.
lr
It
I,
I
i,t
li
ir
t(il
y"L
li
$
Surface
2+,
phenornena
(i2 L)
0ptical behavlours of collclda sol-ut.,ons.. Dsterminatj-on
o-f
i,loLecul_ar weight by lrght scatter.ir,g, Osnotic
l...,ressui.e, Ultr:,_
c'-'trtrifuge. Sols , Er,ulsicns and Ge_ls . inOus trial
Ctl-io j_ds .
Elec tro]<inetj-c phenornena. f,le ,-. ,;rol<irietic po
bei.i tial.
The
efectrlcal Coubl_e layel, " Zeta :tclitral.
Derivatio. of the
equatlon !:r zet:. i_roter;tial_-
Langmuirrs abs.orption 1soti. ,rm_lii n, t j c a;
d s tatls tical_ cierivation.
fhysical_ a bsorpticn and cl,=rniscrpt :ii. 'i'ri=
B.E.I. equation. De .t..,i._,
rni.nation of surf::cc at-ea of absorbi nts.
IJeat of absorpticii and its
Absorption frorn solutitn surfaces:- .Ihe Gibbs
ry equation.
IJxperinisntal_ inves tigaticn of rnonol-e]rer.s
. T,ite equation of statd of
nonol_ayers.
ribsorptiorr in.l:_cators
.
layer and i:igh pressure
Refei'en ces
1'
:
il
-
I
The physics and chernistry c,,
publlca tions
,ji;rfaces, N.K. edam, Dove.
.
2. Fhysicai chemistry of surface, A.iv. Adamson, lVi1ey_Intersc
3. Collcid science,
press.
A.
L. rilexaridej and ijr Johns:,n, oxforri univer.sity
4. fntroductI_cn to Colloid,science, K.J.
p18292
j ence.
i,
yse11s, l{iIey-fnterscj.ence
.
contd . . ..23
/
rtr
,l
lr
\,
il
\
\
2i
I
I
l
-. . i)?2 .. -
Unit
r
Unit rJ
I11 i,hysical Ci:erlis
try f
(l6fS;
-from solubility oDt.t
"rt:ffJ.'::r.
Oxalate , K2CNZ,
(Ammonium
Succin;_c acrd)(2
Heat
f.D,/
l,{olecul_ar iveight
u.slng soli<i sol_vent
rnethod.
2, Plolecu1ar weight _
coolj-ng curye
fr.,om
depressior: of transition
cooling curve method.
point
3, Ivlolecular vreight _
cryoscopic metiiod.
(: fs)
it III 1. Crloscopic
study cf KI + lzreactj_r.n
in water.
2. Equilibrium study
of
- rz
_
I
l,l
I'
I
f:'ri
and (ii;
;;"J:J
bel
il.,f]-^,
*_*r,
copper
surFnale
bY partj:tion
ano annoni.a
cornplex
fortration
r"*;;r;",1";,
it fV 'i . Refractlve
indices of pure
liquicls and binary
- +reu.us
z. viscosj.tv of h;-^__
uixutres.
binary liquld mj.xture
3. o"t..airfy
of molar ref::action .
of selected liquicjs.
f v conducti,rra'_]tton
y experiments (at
least 6 expts to be
done).
5 Ls)
1. Equivalent conductanc.
..^^
of
^r weak a
1aw _ car_cur_.,te
- verify ostwaids
or",r."
socj,atlon
Z. Equlvalent conductat
factior: of o,saga"
1
89?
i
I
i
in o .oo.Ivl znso4 using
e>rperiemts (any
five
t
ii
I
i\i
\
r1I
i
I
I
i
,iili
I,
,1,
electrolvtes verifi-
r"r.
4. Solubility product
of Agcl.
i. C6nduct
FIcl- x Irlaofi,
ousro -T";lttratjon
Hc1 + HoAe x
6. Rei_ative strengths
of acids. (1O
LS)
t Vf Potentiorretiic
I
ii
"or.""a.l
:;;ff.t""nt
3, riCtiVitvtY nr-ro+.coefft o-f' Zn ++
Huckel ts limiting
I
I
lrt
i
Irit ,
\
ii
Debye
li
t
I
\
1,
I]
l
ii.
NaoH
experj.ements).
I
g'
f
.!
Z-
.
:-. -
1. El-ectrode potb-ntiar-s
of Zn aircr Ag elsctrodes
o ' oo1 M s or-uti-oi'rs at
250 c .nd find s tan.ia
r-c
2.
ilt;l:il"..:"rr.
po ten
ry ancl
tials
.
of an ef ectrolyte a; diifer.ent inorstitres
3. Dissociation constant oI. acetrc
titr:tion method.
4. Determination
1, c.1
of strength of
Jy po=ent_i-ometric
acicl
-Llu
by
glven
FIcl sol_ution
by diffdrentiaL potentiome
tr_i c titration.
5. Dissociation constarrt
of ace tlc acicr in Dl,iso, Divr', .**cetone
dioxane by . titrating witli
IIaOH.
C
, Potentiometric titrations
.
and
L.,'
i) ttixture. of Chl_oride and iodide.
1i. Mixture of Ilcl and HOAc (
l OLS )
References
1
.
2.
3
'
4'
5.
:
-
onr.icat chemistry, A. Findlay,
::::"a.":oa.
Longman
,s,
physical Chemistry,
A.rvI. James, J.A. Churchill
;;;:a.""1
;ff;Tlii]
Phvs
icar
chemis
trv,
Experimental- physical
chernistry,
Uniersity pr.ess,
R. A
If
Experj-ments 1n tshyslcal
Cheinistry,
C. W. Garland
, IricGraw Hill.
. al berty ancr o thers ,
.G. Falner, cambridge
D.p. Shoemaker
and
19292
contd. . .page
25
t
C
B'
g
23
-+!5+-11
Paper V - Inorganic Chemlstli' II
(eo L)
I
it i -:.I
The
I
(15 L)
t4etal1ic State
I
I
I
i
of metal-l-jr rondinS: Flee electron theorlv,
rid ald zone the.li'1es-. Tirelm: - and r lectric:1 conductivrty oi
tals. Inters-,itiai and substrtr- iio:^alL iillcys ' Inter-metall-ic
r:ipor-urds. Hunre.-Rothary i'uIes
terstitial compouueCs: iioricies, c i'i,'icles ' nitricles and silicides '
i
Theories
:
ferences
:
-
. Jntroductlon to so1:'ls, L.V. Azarodff '
2. An Introciuction to solid state, G'i' Epfinor'
' 1 Electronic structure of metal-s r. N.d. Brandt and s..M'chinoir;cv'
4. Moderrr Aspects of Inorganic chernlstry, H.J. Emeleus anG
A.G. SharPe.
', Struftural friorganic chemistry, :;".i:r' !/e1Is'
1
'
rlt.I 5JZ Ccncept of Iiarrl and So-t't iiclcls and ilases,
(HSA3) (gi')
Chattts and Pearsonts classificatlon of Lelis acids and bases'
Stabili-za'bi-on of unusual oxiCat orlasis for the classi-iic?tion
states. l.letal- cornplexes oi :-rtia'y 1-hosphines and nitric
oxide. Compounds of metill-s in thei-r' zero oxida'tion state'
:ferences: - 1 . Theoret-lcal Inor,r-anlc Chemistrv , Ivl'C' Day and J'Selb1:r '
Z. Ad.*rancecl Inorgl-lnic Chernistry, F.A. Cotton a G.Wilkinson
nrt I TZ l4agnetic Properties of Transi-uion lvletal- Corrpdexes (9L)
Types of magnetic beh-r..ri-ours. P:tr3trragnetlsm: Tempe;-ature
dependence, spin and urbitarl- ,;ontribrrtions, spin-orbit coupl inq'
Ls and jj coupling schemes. ! 1e spin-on1y noment and its
application in coordi-nation chemistry of the
It
ti
il
tilr
l!L
',1
t
I
. 24
transition metar-s. MaEnetic prope:.ti
-_s of ianthanide complexes .
Deter-mination of rnagnetlc
susceptlci-Lrty by Gouy,s meti-lod.
Antr_
fe*oinagnetic interaction in
transitioi'l :netar complexes. Magnetlc
p.opLrrties of heavier
,!ransitio,, *eta1 corrplexes.
Rr'iet'enc€s : . 1 . Techniques of fn_oi.ganlc
chem1.-qtr-r Vof . IV, H.B. Jonassen
i."
irleissberger (OOs
).
2. Modern Co-ordination Chemistr.v,
.f . Lewj-s R.G. l{i1klns.
i.
irlagne
toihemis tr1., -..' Earnshaw.
Unit I 5O4 Visible spectra of Trar:sition
Gror-mr.: state te,rrn synbc,ls
fcr varic-rs dn
I'fetal_ Complexes (12L)
el-ectronlc ccnfiguratic.,:.
.
Electronic transit-lons responsible
for co-iour of transition rnet.r.complexesr d-q transition and its
selection ru-r_es. Orgel
diagrarn ror d1, d4, d6 and dt ;i;";;;"-.;";;;;.i;^
or rnetal
lons in complexes. Reasons vrh-y thls dirgr.am
differs from Tanabesugano diagram. (rne latter
d-r-agrarn .s irc._ sxpected; onJ_y
the
qua]l ta tive reasons for ths
dii.ference r.equi rsd ) .
Charge transfer translti_ons: _
trat151's. s.oectra ir: the vis:ibt
.{,n.,1_
s
.Lic:l applications of
_.=gion
charge
.
A brlef x qualitative introduction
to c i rcular- Clchroisrn (CO) ,
optical- rotatory rlispe:sion (Om), ,r' d
cottcn effect
qtically
active complexes.
References
:
Sf
-
1. Transi_tion Metal cheriiistry, L.E. Crgei.
I
"l
p19292
contci. ..27
bt
r
I
I
I
25
I
l
rhysical Methods in Inorgi:nic Cheniistry, R.S.
Drago.
lodern Co-ordlnation Chemist Ir Jr Lewis I..G. v/il-kinson.
dvanced rnorganrc chemis try, F.A. cotton
r
Mecahnism
G. vrilkinson.
ls of co-ordination
:
compounds.
-
:vanced rn organic che-mistry, F.A. cotton G. trVilklnson.
chanism of rn-organic Reactioiis in soluti-on, D. Benson.
rchanism of
)
of rnorganic Reactions 1n sol-uticn (12L)
nd subs titutlon in oc tahe clral complexes : SN1 and SnI CB rnechanisms.
and base hydrolysesr Anatlon reactlons. orj_gin and signlfi: of trans effect in square planar ccmplexes. El-ectron transfer
:iectron exchan,,e reactlons. Fr_i-nclples of photcchemical rea_
'ences
i
substitutlon Rear:tions of Metar
complexes,
Basels R. G. pearson.
ndamental-s of photochemistry, K li Rohatgi-Mukherjee.
I 506 Vf Organoi"netalllc ccmpounds.
ompourds with meg(tal--carbon slngle bo,d: e1ksls and eryls of
:r Af, Sn and Fb.
ransition metal to carbon rnultiple bono: Metar car.bonyrs,
complexes and complexes of organo isocyznides. usefulness of
ien electron rule in predicting formai:i_on of such complexes.
-complexes : - Metar comprexes of eti-iylene, acetyrene, a1lyl
and
i-ene. cyclopentadtenyl conrplexes of ir-cn group metars and
complexes of chr.omj_usi group metals.
r.al-metal bondlns in carbon,,rl and haf ide clusters, Clusier
rg theories.
contd . . .28
1
i
i
I
I
?_6
_..29_r_
References
:_
ri. ,l;il_kinsor:.
4. O"grnom
e tal-I"i
chemis try'
E' G' Rochow'
5. organometar-ri,
compouncls,
c. E; coa ts,
K wade
6'
.
organoraetal-Lic trhemist.y
trme-l-eus A.
G.
I{. L.H. Grr en
- An rntroduction,
R.c. Mehro re
Unit I 5OZ Honogeneous
and Heterogeneous
O"ganometallj.cs
A singh.
CetaLysir
ttzitrnvolving
Oxidative
adrl r +i^r
. ins *i.
:::;,TriJ1eD
;f,::*: #i"1ii.;#:
n*""r"*l'i":i1,":t;""t""
a pollaerisa iron
or orerinJ.
Referenc€s:_
1.
2.
Advanced fnorganic
chem
cnemistry'
organomea"rlLic
r;" cornpotrnds,
:^-'
K
F.,i' cotton G- 'rfir-klnson.
G.E. coats, M.L.H.
Green
wade.
3. Princ_ip1gg and
J.F. corloan L.s. aPPficati
,"0"-*r"":o""
of organotransitio.
Iqelal chemis
p1 g2g2
try,
a
conti..29
I
I
/,1
\
\
27
Prrctical IV - Inor"gatlic Chemist''^y rI
Estimation, involving quantl,t r-uive s€1-r313tion, of suitabinary mixtures of ions (out, i{i'+ , F"1* , znz* , cuz* '
Mg2*, crror?-, in sol-ution by volume:ric, gravimetri-c,
olorimetric, ancl electroair,alytic-ri rne+-liccls. (14LS)
I.
r'e
I
i
Analysis of ores and. al]oys lilie clolomite, galena ilnieitite,
onazj-te, feldspar and Kaoline and two alloys' (12LS)
nit
II
n1t III. Ion-excrrange separation of binr:ry mixtures:
'g2*, and of co2+ and Ni2+. (4ts).
'nit IV inorganlc'preparations z
.ire complexes PrePared (10 LS).
1lt Nos ' ) '
I
I
I
i
)t
++z- Zn''qnC
Also to analy:se
:nit v soil and Fertil-izer analysis: Deterrninatlon of
s
i
I
I
I
PH,
timation (4 rS).
I
ieferences:-
. A text .bcok of Quantitative Inorganic Anlysls, A.I. Vogel'
'. Quantitative Chemical r"nalysls, I.i"I' Kolthoff
E.B. Sanderson.
i. Technical Methods of Ore anal-yslsr A.J. \leining and !{.F. Sciroder"
r. Analysis of Mlnerals and Ores ,,'f tire ilarer Elements, \{'R'
Schoeller and ;\. R. Powe11.
;\dvanced Practical- Incrganic Cher,lstry, D.14. Adans J'B' Raynor'
ll/'G' Falmer'
). Experimental Inorllankc Chemist:".',
t
).
f
Inorganic syntheses, Co1lective Volun.'es '
Freparative Inorganic React-i cns, i/.L' Joil-y (Ed' )'
Handbo,rk of I.reparative Inorganic che ;istry, vo1.I
9292
confi. , .
II
G. Bi'r
ucr.
{
I
I
,.J
\
papcr.
Unit
Vf _
2a
Or.g.:.r:ic Chcnistr.v
ll
-5O1 pl:ysical nctiiocls i:: c::;4r.pic
clicrrstr;.
Ir,ppllciiiions of U.V.,
t.il ., Itr.l{.tt., E.S.ii. }Ie.ss,
C.X.,
0'R.D., Sitcctroscopy arxi
cli:;o]-c nonc:ris in :i.i.r__uctur_ol_
cl-uciclations of orgenic
co._-itounci.s. irsc ol
t6c p1air.: i:l:ci
cctto' cfi'cct c*.n'cs fo.
clctcmini.r:g cor:fi6ur-atious
r.rcl
cor:fo-rrratiors' Octerrt
r-uIc eucl a;<ii,l ,erckcbor:c
..rlc.
Oo
11
(18
L)
O
Rcf cr.cr:ccs:
1. Dctcr-nir:ation of orgrrnic
str-uciur.cs
A scr.ics or
vo'ucs
cclitccl
pllili;;j.
2 . Applicatio,
of absori:rior:
--pcrdds
al:ci.
i'
.
;;;;.::JT;;:l
spcctr.osco;ty
by ,r.n. Dycr_. 1974.
spcct'oscopic iclcuiificetior:
R.M.
Silvcrstcir:,
G.
b,,r p].r,ni
of or6ar:ic
C. Bessl-,.x,
of
;:1,::]:;.
r:r.ger:ic cou_
conpcn,icls by
Mor:.i11.
1. or-sanic spcctora)_ pr:obrcns u, .er:cl T .C " -*'
,.i. ;;' ."
5. O.R.I. ancl C.D. by Crabbc.
Bclcvcnt clmptcxs ir: organic
chcnistry
v by
-u pir:c^-"v,
Ecndricksor: ct
o1.
7. Finar Vo1. f & f
8. pr-oblcns il a-61yi111....c1 or.grulic
' 9. IIobl'ms iD i4lyn1ls6ci
or_.,-.1--,.,i-"
Ciabe"f,f,sns.
chr=ristr.y lly Js:.y I,{archr
.,r;;;
, ,I";r,
L;r:it O - 5O2 Orgauic photoc5c__ristr.y
tr'urrckincr:tal. cor:ccpts,
nolccul_m
cxciiatior:, JabJ.o,ski c1ie.;:ri.rr Gu)
thc t.iplct statc, pirotoscr:sitizi-tio,,
,
phot,::.::ci.ctior:s cf or.g.:lr:ic
qorccul-cs, rcactio,s
lr:vo1vir3 Lilc
lcr'ctio's of cru'bo'yr con'routrrcls, ciciinic cr.oublc bords,
oxic'retio,
photo-Fr-ics rc[u-r.r-l\icncnt,
pitotol_ysil;
Icletcc1 ccnl:ounris. nl.ictn-!.-i
^+--_,
p r:ot os y, tlrcs
i s, r;..:"'-":;:,
of photoihenistry.
Tt;:"
;;
"
::rci
r-cc.,-uctionr
6; ^rrtr.rc cstcf.s
el)cl
il:":i :.il ":, ::;
Rcf cr-cuccs:
\rJ
r
li
I
I
contcl..
.
I
I
t'
I
I
227
1. Kan, R.0. GrSc'uic Photochcni-'try, McGrelr lIiL1 Pcok
co. (1!56)
Photocireristr;r, Vo1":-':cs I l'lrl rI
M;u'ccl Dcckcl tr:c. (t 967 lu:rcl 1970)
2
Lnr:olr-, A..!. e.ttc1 Tu.-ror il .J. , 1!r:cr';.4y tr.r.itsf c: "-tld Ol'a4rnic
Photochcnistry, (Tccirnirlutc of orgatlic chmistly :;c::1cs
Vol. (*ir), Irttclscict:cc Publishcr (t959;.
4, Chapnar.t, 0.L. er-tcI Dciruy, itolccu'.14r ::cactiot.:s ol:cr. lilctochcnistly (,nounclatictts of ::rorlcr:tr orgru:ic Chcnist::7 scl'ics),
2.
Chr.linatl
, 0.0.
C::or'11is
ITcr:ticc IIr.11 (1 972).
Cc.lvclt encl Pitts, Pirotoc)rcnir;try. Johtl 1'li1cy
tr
Intcr-scicrrcc (1966'i,
6, Cox at.:cl i(cp, Intlocluctory photochcnistl-y, Joiu: t'lilcy
Ir-rtc::scictrcc ( t "166).
(lr;
Unii 0 - ,O1 l,iofccuLct Or];itlr Tircory
';/ooclvru'c1 - IIof fn r.nt:, rrrl-c s ol Orbit r'1 S yructry .
b) Elcctroc;,7c]-ic rcr.ctior:s, Cyclo r.clditior: atlcl clinitrrrtiotl
signatropic rcactiol:s n'tld Copc crr:cl Cleiscon rc[Irf i:il$cncpts. Applicetior: of Wooclrriu'cl Eoffm-n rr:1cs to p'hotorciictiotrs.
Il
I
Rcf crct'l ccs :
I
1. Dntrnistlc, N., rCt'bitc1 synr:ictry colrch"tiot) itl cr'3'
Chcnistry - A 3uiclc to wooclvrgci - Hoffnetrtr r.r-'.Icsl.
2. pipc, Hcpcbickoop, cr.an opcl III:::qopc1, rOrgc-liic chmistlyl.
), J. I'Ilrch, Advatlcccl Orga'nic Circnist:ry 2rLc1 Ecl" i97i '
UnitO) -504 Molccuf cr rcesiat.:gcctci:ts
Rcr-r.repgcnct'tts itr.rolvirg Clcctlor: clcficicnt cexboll, urtrogcn
r.r:cl oxy6ct.t irtonsL,' 1'Ir€:ncr'-I'Iccr-wciil, Pit:aco1-pitracolouc,
Dicnor.rc-phcLrol, i,Iol-f i, Ilofnoprr, c.ur-tius , Lossctl , Bccicr:-t.lt.l ,
Sclpriclt
r"pc1
.f'I.i--ngcnclt!s
BncyCl'-liiIlir13cr'
:
bcrl
lrCr.rTs:lrSCIllClrts,
zil-bcrlzilic acicl
l
I
i
I
I
(,,,;
elllr;llir: r'c-
ctlcl Fr-vorski IiCCJI'i:l['C-
ncpts, aJona*ic tc:'jL'rr.t.t3cltcotc: Ortott, C1c-isol: rucl Frics
I
Ca:llll0-lla{CnC t-tt s
.
ccnt..1...
Y,
i'
tl
\
3C
Rcf cr-cr.tccs:
1.
a.
Sykcs, A GuirJ.c book ic Mcchauj-sns iu or.gnr:ic Chcr,istry,
Oricnt Lon3na.n (rr.a Acr. r95 ).
, Mcchauisn anrl
I{o1t-Dr-yclc n (t959) .
Gor1c1
). Piue,
Sil-uct-Llr.c
ir: Or-6.,ic
Chcr.ristr.y,
Hcr:c-u.icksor-l, Cr.i!:t r.ncl Hcru:ror:cl, Cr.gt.ri.c Chclristr.y
Mc-4::arv
Hill (1r:t Lkl. 19BC).
4. )c Mayo, 'r'rorccura' Rcl+'::i"r.r3'circnis r , rutcr-;cicr cc (",9c4),
5. J. Ivlalch, rArl.'ra.ncccr. o:-'gauic crrcr.ristr.yr , Iic c::c-w Hitr (1978).
Unit 0-505. Ilctcrocyclic
r_t
conpour:cls coDtl:ir:i.,3. i-,ro or- no::c irct cro
ons .
Ilcthcxls of syt:thcsis el:c1 tcactior.,s of i_uiciezolc, titir.z,olc,
pyrrnirlir:c (u.a"crI-, ih;rnirc, cl,,tosi,c), pyr-e.ziuc, pur.i,c,
pt c::iclinc ( zautirpt cr:i u Lr11or. z-i_u c errcl is o-r.l_
Io:<s,zir.: c
)
Stlucturc
crff cil:c.
R
cf crcr:ccs
ar:cl s;ur:tLcsis
of
aclcr,.ir:c, gua_itiuc,
qric acicl
(6t )
1ncl
:
1. Finar, ,rganic Chcnistry ELBS ( t)6), ltb Ek1.) Vot II,
Ch 12. Hctcr-ocyclic conpour:c1s cor:ta.ining two c.r norc
hctclo c.tons.
2. Gilnan (na.) aavancc<I Or.gcnic Chmistry, }/iIcy Col_.fV
(1951), Cir. B Ectcr.ocyclic Chcristry.
). Acltcso,, Au T,t::octuctio, to flrc Chmistly oi Ecicr.ocllclj-c
ccnl:ouncls , Int cr-scicncc ( 1 950) .
4. Beclgcr', Thc chcnist::y of lictc,ocycric conpour.r:cls, Acacr.cnic
tr
pr.css (19614.
Roclit (Ecl.) Chcnistry of thc C:ibon Colrpour.rcls, El_scvicr-,
Vol-. fV A, 3crr1 C (1958-1960) Hcicr.ocyclic conirouncr-s.
Elcl'clficl.d (nc',.'; 1iq1.::ocyciic conlro.lrcls r',/iIcy ( t ggt
).
7. wcissbc'gcr' (ec1 .) Thc circni st'y of Hctcrocyclic conlr:,rIs,
5.
fuicrscicncc (t gfO).
contd.
.
\
-11
v+
Unit)O-iO6Introilucti';t'D0iicr"'stryofnahrla-:il'-cr-"ucts
(21
L)
Gctlc::einctb'oc-lsofi-:lolitiotlclessiiicc;biolrpuu'ificetions
of plr-lri procluct:' lvith spccia
l,trti stlrrctu'e] clucid-:tion
C:cirJ, cxrit:inc, airopit:c
rcf cr.ct:cc to cr:rpl:or, ebi.ctic
LlyJ isofie:s;ltc^ classifichol-cstcrolr gcstcrotlc' f1;rt'ottc
r:lkr'Loicls' isc'i:rcn: ruic'
ce.tlotl oi icrpcn6s atrc"
B-cfcrctrcc":
5th c''i tiot:s) '
1. Fj'nrr vof il (5th r'rxI
?-. Ilighcl tcrpouoicls by Dc' I'Iayo'
'). Thc chr-ristry of thc tcrl:cir '::l A.R' ?itlcicr"
Bcnti y Prrt 'I erv-i II'
4. Thc c-Ik'aloicls b;'r K'lI'
Pcllcticr 1970'
5. JJk-aloicl's cc1' by E'I!t'
6,}Iatura}Prorluct:i!orsr.nicclicrristryby0.?.S;lrc*::a(1971)
e'urf Ficscl:'
'l , Stcroicls by f icscf'
I1i Klytlc'
B. t5c chcrristry of stctoids
to Eiopolyncrs
Uirit O 5A7 ir:troiluctioir
r-if protcit:e''
ancl tr:'tiery st'-*ctr':rc
Sccot:cll3:y
1l1.inrry,
Eckunrl
of pcptidcs 0-t:c1 protcit:s'
Scqacnec c1'ctc:::inr'tior:
-*d-th
pol ypcpticlc
at:ci syt:tbcsis of
Sturctulc
ir.gg'oclotlotl'
j-i:srlin'
r*i:i ottc' grer:iciclirn n'rx1
spcciai- r cf c:: c i'tc c to 31ut
t:uc--cosiclcs c'i:rl
of
synthi;:is
c.nrl
Stlr:ctr:tc
""'1'6ticlcs'
RN-t at:c1 IidA'
ci
Strrrctr:r'c
tlrcl-cic c'cicls'
ccl1uIosc a:lr1 s ;:rrclt'
Strrrcturc of pcl-yse'ccbericlcs'
(196r, u|ilr Ecl.) vol'
i:tT:::, 0i6anic crrcnisiry, Erss
licicis '
Ch. 1o. Pulincs r'l'rr1 l:Iuclcii
d
if
(15-L)
i'l
l
I
\1
\i
,l
rr
2.Gilnc'n(E-r)AcLvr'nccitO::'3aL.ricChcuistrY'Uilcy(lglg'IstEci')
Vol'1I,Ch'II'Tr'rcC:rcnistryofPyrini{iucs'Ru-iircsr'ltc'r
lfuclcic Acirls '
cotrt,i. . .
kfci,/
t
?
I
r22<-
-)
\
a
7
\
Chcnist.ry of cir-boir ccnlro'trLlc1s, (lscvici'
1io1. Iv: C (1950) Ch. XX. I'\:-r'it:cs :i:"1 Iiclitcc1 Riu6
Syrtcns . Ch. KXI. Ifuclcosiclc.r, Iiu-clcoticlcs arxl
nocf<l (f,lcl)
ltuclcic
Acicls.
Jo::rl:.n, Thc 0licnisiry lf thc :turclcic 'l'rci':[s, Buttcrwor:-Lir; (1960).
(
Pitrc, Ilcnclricksonr
G!-''rl atrl iler-n':llci rOt"l"t-ric Chcnistryr '
(r 9co) .
Ut:it O-5CB Tccirttig,rcs of Pu::ificaJiotr of Or--;::nic cca':i:outrcis
Tlrcoly er:d applicatictl of Cl:rona"o3-*cpl'-', nolcculee.
sicvcs , Zot'tc lcf initr6 alllcl cout)tcl ol'r'cttt crtlr'ctiotr'
(it;
Rcf c::cttccs:
1
. Physicr-I ncthels itr olget:ic clltr:istry by A' licissbcr'3cr"
vol. 1,(t950).
t
M, /18292
ir
L
I
--r4'
\i -,
?
_
Prac-ri 3i.1 !r
uuit - r
"6drza,ccd.
[I:5
_
- Orgai:ic
multi-sta.gc
pi
Ciromistr
j, If
(
++ls)
cpa,atiorrs i,c1urlr,g
1>rro-to_
ghcinicar mcthocls (six i'r cirar atious
of i',hich 'brvo sirar j, irc iisi.g
Pllotocircmiear tcchrtiquc) . 5-=r'bl o.ction of a f cr', niittrr ai pr orl._:cts.
-!-xc.rnpr e :- citr al r'rom Lemo, gr ass
oir., i,ipcr irc fr oin br-aci.r
'pappcr ctc. (Traiirin: irt iiarrci.ling scrni-miero q*rirltitios
is oxpcctccl.) (14 Ls)
t - II Qrrarrti tatirrc Orgarri c .,,.ltaI),si s z_
!stinratiorr of qui,al e.t weigh-u of arr aeid. ir}, tlic sir.vcr sart
methocls, uotrogcrl l-'l' Ilj elrialrl nrthods, ostirnetiou of iil,rlrox5,i
(Ecrcrrittio'off), car)io,yl a.d h,ietlrox5-)_ (zciscr) gror.lps, Dctcrrninatio:r of iodi:rc lrrrml;cr " ijn{i r,aponificatiop valuc of oirs.
rlStirnatiou of rodueiug .srlrgar s, amiucs, pircuors
and .-tors.
r"lorimctric
cstimation
of ascori:ic acid, nicotirric aci<l aurl
,
chorestdrol. ctreck tirc prrrity of alr trrc comirotinrls bl,GTLc
(Phl'sical eonstauts need not bn tlgi.rmincd) (a+ rc)
Unit - :*f ;III Papcr "'i,it: I n-,'er atrc col.timn clrromatographS- (Dcmonstlatiop)
r-rx. actiori of caf f cinc fl ont 1,ca ir:astc
anc.! chcc ji thc pur it1- by
tltitt 1a5'cr chrorriatogia.ilh5'. :xtr- acriorr of clsci,c fro:n mil,s
and .idoutir'y b5' coronLrcactioii r)f pr:otcrrrs. T:rtractiorr
of
raciose frorn mirk. rcrcniify-sr,-gais r-r5' pe,cr chromatograp,Saud TLC. Calculatiou of R, valucs. ( g LS)
Uni
R
cfcr cnoes
jlil
;
I
2-.
L. rl .I.1'oger, .ri tc-'<t booli of irrectical orgiinic circmistr5,.
2, Iri.cser , !-:.:pcr irncnt.; i n orgi.rr ic eircinistr5..
3, ]\f a'lr and S-:rrirrclc, sr practicrl Organie Chernistr5,.
,t. D , sitc] onliin, ancl Govintlacirari. rl La)lor trtor5- mauual
of orgatric clrenristll'.
5. j}.Ikatr, Nat'-rl i'11 Prodr:cts - a Iai:orator1. griido.
5. chcrouis aud r}tr"ilriu, Seni-micro organi e arral 5.sis.
7. L. I.irogcr, euirrrclitativc. organic anal1,sis.
8. I,. R. Si r1gh, D. SG,pia, arrd l(. S . Dai pai , Tx,er imc,tal
organic c.liemistri., Volrlacs i ancl 2, 1ggO.
9" I.Sr'irtivasatt, Td. Photocheuricel Syntircsis v.olumcs I ancl If
Cotrrd.
., .:)6.
+
3
r.6
t
+
!l
_
Papcr VII - pli5,sig41 Cltcmi str5, If
(oo
l)
ear antl Radiatiou Chemistrl,
(zr r,;
Nirelcar reaetions : T5'pos, co'lsc-r'rratioar
rcactioll cross_
s(rctio'rr compotr.cl cticlctrs t,cot5,, s.ccif
ic rurcle.r r eacti.o.s,
piroto.ueroar arrcl thcrmo.ticrcar r oaetio's.
Nrrclcar fissioa :
flssio. proccss, fissio. fragmcrtts, mass a'cl
c'argc.
cistri'btrtioir, flssio.l cllcrg),, trrcor5',f .trcrear
fissi,lrl.
.r
Nuci cal cae tor s .
rfireI
Radioerrcmicar tcerr.iQucs : )icutr-ou octivatio.
a,ar5,sis.
ilariiatio:r errenistrS': Tl.e i,teraetio, of ra<liatio,
rvitrr
mattor - PloecsGCS r esitonsiblc for cncrg): loss,
ratigc
e,c'l lar)gc crlar€:'rciatious, mctrroris of clctectiorr
arrd
ncasluemcut of radiatiou.
cl..cmir:a-':- :
rii-.iatio.
Elcmonts of ilh5,sical
anrt
ef f cets
i, solitls, rodiatio, crrcmistry
or' wltcr aritl aq*corrs ^'clr ous s.lphato solrrtion. Dosimotr5,.
Itcicrcnccs :1. S.Glasstono, Source Dboll ou Atomic Energ5,.
2. ,I.D.Rajam, ritomic physies.
g': Vauderncrf, R^clioactivc Isotopcs.
4-' )J.clce.r crrcrnistr5. aud rts appl_ieatio,s, i,t. Haissiuskl..
5. G.Fricdra.dor ..d J.trv.Kc.r:crl)', N.e1ca, iirrrt Rrrdio
Chcmistr5-.
5. li.i{rT,Spi.ks aurl R.J.',./oorls, A. I.troductio, to
R acli atio ir Chemi s tr.*
),.
Unit P - 50?. photo Clrernistr5,
(or)
Photochemicar r ea,:tiolls - r
arr<r lloir-r acriati'c.
tra..,sitious - Qtrantrrm 5'icrri^rllativc
llrrotosensitization _ FLaslr
PhqtoI5'sis errcmi1rrmi,csce.ce a,d ilrcrmorumi,cscclrcc.
Fl5'drog c,br omi l)c- cacti o, a,rr ii;-clr ogc'cirror
i .e
:eactio,. r,flucncos of tclnperattrre on photochcmic.l
\
r..,
Gontrl. . .32
Prk
.T
{
1
-*'
35
itr
cqttilibitttn - Photor eacti otrs
Pirotochcmic'rl
rractiot'ts.
i)r incilllc of tllc ttlillsntiotr
sol-irls sttch as silvor iri;litlcs'
(ttcmcl-''Ler 'i' itlcas onll ) '
ctle]'g] - cg' solar ccll' '
of solar
ilcfcn'clrces :-
| \iilc)"
I :t)'siccrl Chcmistr 5'
^
ii''ti'/ilircrt5''
i, F.DanicIs
(zr l)
rPir) sical Circmistr '''I Van Nost.r-atlc.
'
2. S. Classtotrc,
ljnit P -503: ClrcmicaI l(inetics'
: i: Lcs tillcl or dcr s of
of
Dctermitrrrtiotr
Latr
atc
Tl:c r
aucl f c-Isc otclct of rcactiotr r caetiolrs - Truc ordcr
ctrcl
I(irrct.icsoffirstottlcrr-cvcrsib}c,col.isectttivcatrtlprual}cI
r eitctiotrs.
qtatc
theory a"rtl ttnllsil!ol1
Coltisiott
t'lreoly,
.irrl:ctrius
vnriou; aetivatio:r peritmctcrs'
l-:^r:'. Significanee of the
of thc activ'ltiori etlergy'
ealculatiotl
Tltcoteti'caI
altC tr atrsitiou statc
collissiotl
tllc
of
studl
eomDor ative
.l1
tlteorics.
fr eCr
r cactivc iitoms arrd
itrvolv'itlg
cactiotrs
r
of
I(i nctics
L'-tctzfeld mecltatlism and steaC'y state
Eicc
of
Usc'
r etlicals.
at ratc latrs of sttch r eactious'
ivitlg
arr
itr
annrosimatiot-t
of chaitr
t cactiotrs' I(inctics
utrinolecttlal
of
ies
Tirr:ot
of cheiil alld cxpiosiorr Iirnits'
r eaetiolls. Ui atrolrittg
Tlrcoricsofgelreralatrrispecific.tCidill\dilasecittal5sisatrd llctrogetrcous catal5'sis'
Sim1lle etrz5Tnatic catal5'sis
of solveut - cffeci
rolc
soltttir)tl
ir'
Iiinetics of reactious
solvctlt - strclr as rlielectr ic
tlic
of
tics
ic
I)ropcr
of spccif
crllrstatrt.at.tcttlipolc.mometrtotrratcsofrcal-'tiotrSbctrYccll
imcu )'
cctiI os ' Sal i cf icc t 1rr
6oI
n1
:rcutr
atrd
es
i o tts , <lipoI
Conttl. . . 38
t,
^
kinctic sri.lt effccts. siurti- of trrc hiuetics
rtl sinnple f ast r caciions using rel a:;rrtion ti.mc.
arrd scconoar):
ii efor
eltecs
a--
rCiremi.cal I(ini-r-ics,
Ivic iir arv l]i I t .
1. I,l.J.Lai.lloi
:. ri.,I.i'rost
a.rrd
3. I.Dauiels
arrd
Johu, l''ri 1 e;-.
lYi
I c.J'.
Vo
t. I and fI,
R.J.pearsou Kinctic:,
tt
ancl hlcchanisrn
R.A.Albcrt5., rplt5,sieal
j
Chemistr5-r
.'lnit P - 5O4 Statistical Thelmori5 namics
a) Dhsic Principles ( ol)
Pormutations. Irrobabilit:' distr ibution of
i
(zr l)
f
I
ilar
ticl es in
i
onerg) s'tates. I!^cro statos and micr: o conf igur ations.
Statistical t'iolgltt. L{ost prolratri <listributiop. IJoItzmap
rlistribntiotr 1atv. Tho par titiou f r'.netion aurt its r clatios
tc tlie thcrmoill'namic firrietions.
b) Thc pcrlcct gas (ar l)
Factor i zatiot-i of thc niu tition f rir :tirlu inio ilre
tl anslational , rotritiol'rir-, vibrat:-crra.l ilrri'. :1cctronic
lraits. Tlre corr csporrrling c-o ror ii;u-ui ,ns to tlic tlrernocll rlami c f tlltc ti olts. T'lie ni:i'iri-:rrlous lrc L ,tai)ocit1'-tcmpcr attrl
r al otio il f or hildr r-:c eri : Or t,!ro i.-.llct l)c. a tt5-Crogcn.
( a l;
r) The :ltomic. Cr5's tal
nirtstcin
titcorj.of i:+.onric cr]'Stirls.
Thc
ri:odiflicatio:t of tirc Tinsteirr nroiiel.
c])
I
I
I
II
c.
Deb5'sta
Imper f ect Gases ( S L)
Thc virial (-rxprcrssiott ittrd tlro virial
eocfficionts.
Belation
tjc.trveorr the vir iar coc.fficicnts arrrl the clrrstcr irrtegrars.
i,
,
i
Contcl.
..39.
'a
37
-w'
Tirc idcalFcrrni Gas (gl')
Icrmi-Diractlistyi.btrtiotr}atr.fQilatiotrofstatcofall,
cxpr cssioll
idcal lermi gas. Limititrg forms oJ tirc
a'"
a) high r cmpcr atttr c alrd lotl densities
b) Lotl tcmlrer atttt c antl i:igh dcnsitics
.lpplicatiotr' to clecttotrs i tr'metals'
f) Thc rdeal ilbsc gas (SL)
r
tlistributiott lAw' rrpplicatiotr to
tr; liqrridi !telium'
Bose_Ti.steiu souc'lc.sation. /rpplicatiott
Tho Bhse-Tirlstein
:G'S'Rnsh broohe' OxforC'
t. Statistical Mecirauics,
Utliver sit5' Pr ess '
[.AultrtrotlttctioutostatisticalThcrmotlyuarnics'T'L'
uirr, iittttisou - Iicslc)''
Rcfer cr"lccs
3'-.Statisticallvlcrclratrics,Tlrcr:mot15:lamics.atrdKitrctics,
K. llttarY, Joir:r i?iIcY'
C' lilrdr ctr'
4. Tqui lil:r ium statistical lticchauics'F'
Jolitr i?iIcY.
Trrcrmo<lynamios
5. statistical lviecira.ics,
co'
atltl
6.i.ni"o, ll' H'Fr ccntalt
(9L)
unit P 505 Tlrc }iqrritl statc
and
studics of simplc Iiquitls'
f or liquitls'
gur atiortal Par titiotr ftttrctiou
statc
tatticc theolies of thc liguid
D-rir1- tliffractiotr
I(inctics,
Tlrc oorlfi-
z
thcot5"
a) Tltc eell of free volttmc
tj) rL s innl c ltoi- c thcor 5"
Lotrtlartl Jottes theor5' of
c.) Orderr-tlisorrler thcorl-'
irr liqtrids'
mel tirrg-. Communal cntrophl
Corrtd...40.
f
4+- '5S
:1
R
ef er crllces
3
i . Lat ti c.o thr
lorgnr,i,, ";;::;l:"
2
.
l,Iol cerrl
H"ri;i;a'
ar t
;.,;ii3i;1,,!t.il'tttio,s,
5'" statistical
c
rif tlio f iq,id state,
J. r,. Bcrrre.r,
Nrnnl,^,i+
-_
;ii:';i;I,,,,,T,1liililfii;
r. prizogi.o,
^.nr
Ill:,8::,,rrami cs and rii,,orl
,
trr
:",
'7. Ill::.r_""i,srremistr;., r.
ri.ilio
..'..,?'1ruy, IIig.es.,
u:tiv6nrsit)- prcss.
Cam,rirlgc,
Unit p _ 506
spcctrometr),
,l'JiJil:.]'il1;,i
5i.
v.
arr
I
r r.ft. ,
N.ii.E.
appl i cati ons.
,
artrl mass
(
Rcf,sr.cnccs :_
t. ftrstrumctrt I [,ra+r,^:^
i :i. M;,:; i ; 1,,11" 3f
i:;.H,
r,1,111,,
i,n
i ;,
X;,H:
eL)
i/i I I ar d,
j
I
i
I
i
(
I
Conttl. . . 41.
I
I
I
I
,j
I
'tk
I
ll
t:
.t
,ii
I
I
.jz q
++r'r--
ac't i
caI
'i
i
PltS'sica1- Jiremistr)- 1I
Clicrirical I(i ttet:- cs (/rn)
1
s
(
++Ls)
jx ori)cr imctrts shall l;c donc)
:.c I cac'ciott r atc of acitl ca'r,aIysct', ii5'cltoI1'sis of
il'letirl'I aeetatc.
1) Spccif
c coef f ici crtt otrii cntrEt of crcti'zatiorl of
ir1'cirolysis of mothl'l trcetate,. ictcrnii'natioii of iii' t irctrius
2)
Tenper atut
pilii"n.ctcr-s.
.
:
3) Satroitir'rcctiott of cthyl aictitc
lrictiroi.).
(
t: tr atiory'conclitctatrce
4) Kinc-iics of tle rcactiotl l:ctwoct'l acetouc atrri iod'itre itr
acidic nctliuin b)' !:alf lif e,method atrd ' ordcr of r eect:'otr
uitir respcet to iodiue at:d'agotouc'
5) Stuc3' +.ho cffcct of golvetrt (n'iSo iTatci ' Dffi i/:rier
sctl
acctono trtttet systcm) oti tllo r ato of acid catal5
hi,dr oIl'si s of acctal by tiiaLatomctJ y'
6) fuvctsiott of catlc stlgar irr prcscllcc of HCI'
,
'
1
7) It.atc c.onstarrt rrno ordcr of r cactiou bctitcctr potassium
per sttl;:liate aud potassium iotlitlo'
g) SaI t c.ffect otr tlre r eactiotr bcttt'ce, acctotrc" a:rr1 todille'
9) Iocliue cloci< r eactiotr'
Lrnit iI .rcjsorption ( 3
,
rx''rcr inents)
( 0.,,s)
I
1) VcrifiCatiol c,f 1cutrrllic5 atltl Latrg:avir at'lsc,rptj'tltr isot5errns'
acirl
2) lletcrr:i rratio. of co'ee.tt atiotr of aceti c acic.r/ilsalic
Usi.rrg Li:tlginttire ttdsotirtiotr isotherni'
Corrtcl
Pr Ir
...+2.
(
{t
fl
t
'Ljl
4o
4+-
IIi
Pirasc
ot,,rrrbria ( S e:<,crime,ts to be,cloncj
(tOl,s)
1) Slmple cutectic sl.stem.
:t ) Contir.liiorls series of solid so-t.lrtir_.;i.
i)) CornpoLrnd (ono) fol:natlon.
,i,) Ter,alf, Iiq.icl sl,stcm i,;itil
o,e lra.r of pru_tialI5,
SiscibIc liluids.
(iilSo_ ratcr_i,cnzor:c, wiitor_benzonc_
aeotic aeid, cth5.l alcoiio4Llcu:cltc_lla.tcr,
acctorrc_
, c'lrloroform_wator r ctc.)
S) Critieal sr.lItr-tiorr temltcr atLrre of phcirol_r.;atcrs5.stcm
ar:d eff ect of imptrrri5, op CST.
Lrui t IV 5,ect,,op'otonetl.1. (
S :x!-)cr_ imo.ts to l:c clouc)
(.0 f,S)
1. loterni;;atiou of pk
valuc
of
r.err
aci<i_bascinrlicator
(llcthyt rcd).
2., Dotcrminntiorr of tho conl:osi.r,iou
autl ir,rstcbillty
c'ousto,t of a comprcx b5' rnole ri; r,io metrrorr (nr
otiror
motho<l)
3. Simtrltaucous lstimatiou of lviu aud Cr
,
i, a solutiorr of
,o.
Kt[r:04 * nnd KrCrCZ.
ITuit i/ I{olestr}ar rvoight of a polymer b1, viscosil5,
mrttro<l. (orrO (Z f,::)
cxpcrimclrt to bc rlrrirc)
-f;itit Vf Cluornatogranh;,'( n,r5, two cxDct
imcrrts)
(+ ts;
1 . Iccr:tifj'
artrl scpar ato. tl:e comporrents of
a givou rtixtLrr c
of ani tro aci<1s (gl1'c i nc, aspal. tl c acicl. glutamic
acid
ar:c t1'rosi.o) by tr:'c, ciime.siorrrrr- papbr
clrromatogra,rrl,.
2. Scpcrate tirc notal crrtioirr (Cr,,
-,i,.;,r:rl\yiq) a*cl f i,C
tire Ilf rrel rrcs b3, paper ciu oi:ii _,,gr eif,i)J,.
:l'. seiraratc i.d irlcirtif 1' t1:c s*ger s p: cseirt
i, trre gi,c,
mixttir c of glucosc, f t trctosc iir:;J jlct
osc iJ,), :)apcr
cluonatography and finrl ilf va_r.ilcs.
Ilcfer eliccs:-
,l
1i
,l
'i
li
:I
:i
as that given uncier ptacti.ca} III lrli5,sieal
Citernisti'1=. l.
Srune
ti
:I
ll
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I
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i
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41
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I
Papcr-VIII - El-cctlrrc Anai.,.,r,ica.,l
Unit-f
\.
2.
a.,c1 prc sc
ntatio, of
A;ra. I
yt
.i
c ar'l
(et7
Coitsirlcra.tr-ons anr1 tccl,iiiqucs ior cbtiii :: i'rg rcltrc
scnt,atr.rc
sa-mplcs of .uirk:rovin l.ra.tcri e-l s f or ana ''i i
;-s s . .tc cLlr f.cy ,
prccisi on arti-l crror ojl anaJ-;l-ui_ca 1 i-loicl'r:ri r:a.-ui
ol.rs . Causc s
of crror. Stat, :_s-r, ica.l trce.trrcit-, of ozpcrr:rc utal_ r:1a i.a
:
I{ctliocl-of avcr a.gc a.ucr rrc'r,licrr of r cest r:qLi.!rc s
. srr,rirca,t
t'igtrrc s .
..
l.
nis+_r). (qO i)
,
sa''p'I-ing f o' A'aJ-ysis
Di.ta.
t
61161
I
. Rcfr..:rcnccs:
Anall,li ca1 Cl:.cnis-bry, Cliaptcr j, J.G.Diclc
A,a'l;rLica.l Chcr:rs--try- _ au -i-,,troclric.r,ic*, D.A.Skoog
D.ll.lics'r.
Unii- Ir- -
c,
Equiiit, r in
(tz t)
Ac i,-.1-bo. s i: c q u i1ibri a, c,omit1.,xa.tron
c q r-rrlibr ii,., Trj clox
cqurlibria,
prccipitetion oqtri librie. . coprccipitntion. o.nr.l
pos t pr c c ipii at i on. iionrogc*c otrs prc
cipi.r, n.t i ou . Tro...t nc nt
of irrccipita.tcs. Sclcc.t-j zity of o.no..l;,t-rca.l lca_gcnts.
connonly uscrl 0rEarlr-c sc. lcctivc rca.gcuts for
6ravinctric
r:1ctc rninat i on of r:n t a I ie.-ro
.
Ctic::r rs
a.1
Ecf c:rc llcc s :
.
2.
1
Analyti ca1 Clicnistry, J.G.Drck
Arlva'cccI Analy-,.ica1 cbcmistry, L.Ikrr-r,cs, H.c.Thoi:ra.s
R
)'
'
4.
&
.P.Ba.trnan.
Analytica. 1 Cllcnrstry - an i ntr:ocluc'r,iolr, D.A.Slcoog &Dill l{cst,
A Tcxt Book o.' Que.,-r,rto.t-iv-c Tnor3a.,.,rc .A.*a1),r:1s, Jr.l..i/ogc].
0r6alrrc Ana.Iytrcal Il,cc.gcnts, ,/o1.I, rI & tII F.J.qcl_clic,i,.
Unit-III - Elcctro-a.nat;;trcaJ. I,lct.liocls
(g t,)
Polo'rogra.phy, Anpcror-:ctry, cotrloncl-ur-;, ciironci:rotcntionctr.y,
Ercctro6'ravr r:rctry, e.*ri Higri f rcq*c.ci' trtratio,r.s
5.
Rcrf r;.;1'o''r"o".
.
2.
)'
A Tcxt Book of quantrta-i izcr .[la. I ysis, A. I. Vo gc1
EI-cc'uro n un lyt rcal Clicrrrstr;., J. J.Li nta.nc
Ari'ra.nccc'l Anaryti ca,r 0liomrstr;r, cfuaptc;. 61
L.l,fr:itcs,
4.
ncl R .p .Bnui.rarr
1 l,!ctriocls of A:raI).sis, H.il .Wi11a.rrr., L.L.irtorritt
and J.A.Dcan
1
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T,strtrr:rc'.rbi'.
i
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Unat_Jt,-
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'*:]'o
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ool_tn"tt",,'Jo"
r *,
i c r.; r cn c "'"
i.
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liorls of 4rralys-:s
ffJ;;:r'
-vr(r
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,.ll:::s
.:rssbor6cr.
Solycltl
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i
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--'rJr'r''
spc2f,, 16itc.1y.
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",'
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&
A'K'Dc
DifforcntiaJ +r.-.
(or.)
jr, ;T-._
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": Difr-crcrrtial
: :l:.rJ::]
t:-tro.hion"
;:::1,;".',::T" :',ji:,-.:"..i,*,;l;]TiJ::;,"
Unit_Vf _ th:
nk* (.rr ; *
ooto"t:tLnaiog--aphic r,ictr:,,cls
.A,.^ r""" of Anal-)'s-is
a)
*-oito'"
(gr)
i'rir.l
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ana.',".."-r,lr'iu.,, ('o)
"nrro. "t,o",
,
b) rr,i,,
rnlrouat;;;:;;'
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ol, .",1": I
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phy
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f rrorga.nic
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of qLr
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of ::.,;;'"titative
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rrrnn,' pri o t o :
rc t rv,
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43
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2.
1
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s
:
Corri:r'cl:cusi...rc A,raI]. i ci t_
crrisir)., C .L.Wil sor & D.ini'.'r,Ii.-t_si:;:r
?rc:at i sc i:r r!na y i;r c..-t_ Cl c:. ist-r",', .riir+--.t-T.. tlol-.Xff
I & :{IV,
f .il.lioltlioi-l ar;..'l I.J.i.t v:i:,,
Orgiinic Fr-rnctrc:'1 .:.ot.i,.i
Britisii pha.r na. c oi)c a
-.
I
rsr ii.D.Clrcrcnrs & T.S.l|,h
riI j-'L-v-1
.1 - Prit-:1i-, I s o.:_- .,1,.u1,c,t'ls ,,iSi; t rlt l,c .i:.ira-1.).s.is
ol AIIoI:r,
l{il:cr'i:'l s i..rtr] p,1 1tj -i-,;t.s
(,12 L)
.i,t:....t_;
AJ }c.';,.g
Ria.;
:
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lfiuc-r:iils
: Dotor:r-ii,c:: Cc ircr n;;rrLcs, IiACi-ra,r,i-,,cr
I,'c;ti1_rzcrs
l'{olazi Ic, I}l:ic.rni-t c
: IIPK c.1,c-'.c:i:ri natioirs., Soil'ir i:a 1ys
'.L
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rl
I
i
o-nd Wo.tci.
b
crcnccs:
1. d Tcxt tsook of Qtro.utit.jr-,_irrc Tuol .r.i:ic Aual',-s
is.. A:I.Vogc 1
Z. Siau'larc.l l,lctlio.r.s rlf 0h:l:tical All., i-;;sL,r: Yo'l .1fI
, F;J.liclclicr
) . Ai>i:l-icr1 f uorria.nrc ,[tralyl;,is , r/.:, . .ii.1'lcrbral.r1, ti.E.F.Ltrirrlr.t t,
ll.fr.Brigli.r" & J. I . .lot fr--o.n
lt. Chcr:i-str;. 3.r.., fotr, p. : .Bakc-,, G. I{.E ra,-l,bLlr;.-, J.I,I.E
ichi 11g1,1
& E ..ri .S in6c,r
Uuit-IX - Basic ii'li":trc,:ics
(,-tncic rollc(,. pts ::li,i aprl:,cLirotrs
oli,;,,)
R.cf
(
Elcc;t'onics, Piczoolc:trrc ity an.-l F ro.: tcc-ur1city.
F-cf crcnccs:
1.
ElcCironics f or sc j.c .itis-ts, lal lstnd.r, E1ii., & Torc:.r
2' Pririci-p]cs of E--1-cctrotf:-c Tnr:'.:. 1.!)c-Llia.'r.ioir, A.J.Dicfr,, nrlci.fcjr.
)' Elcctrouic Dcviccs, Circu.its r lr1 lii.::].icat,ioirsr Ii.il.Le.kshn-i
U:l . t
I
::
i
ri
i,t
LI
lr
1I
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o
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Clicnri:tr)'
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f utroclrret ron to jOurrfo. 1g, PCri .11 -'^^-,u alrrr. 1olrc,..rir*1s
111
tbc
i1
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Mcasurcmcuts of 'ro'ltagcr cl'ri'cint a.nr.l. rr:si steucc. Co-l-onr coclg,
,ii,n:.tsist,,rs, Anplif,ir-.:r=sr
Di.odi:s nt-rc1 Triorics,lc:ct:_iicr:s,
TIVM - Li.e ar i'.r,cgr.atcd c_:-rc.,ii i,sr -:, Ir_rr:)is-'c,rs, Dr6ite.1
i1.|.i.e.ya11
t1
subjc
ct.
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r
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0roit,'.. :'Udl i, Of ,ulio'irppo'f.-ii.,cl:rosp',rOrC , ,; .
.4, Brici' rnt orl'.rctioi-i to occl-,06 r.,ca1 pr,rue,i
'rlrivlio:nJiirta.:l- 'clt'a:r1;cs. ,einc1l
j
r.
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Clic:lica.t pci,s
1jc'ct iUc ;''rr
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1978, Cliiptcrs'd'& -..5'ti,, ..
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Il:rrib:Ila; pol_ltrtion
S onr ccs atE}:,:c{f c e!s of pcr
. I -, : r:;,1xI._,[Enc.l.;p.oIIg$f
9+:, g]gt1ic
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;
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c9.ri1iyo.1
a.pi i:1C,",cntion_ of
F.cfcrenccs:
,1.;.Etrrriro.nn-e'.nt,.'.tClicntis'ur},.A1Ki..)c,.,.:):-.:,: ,r,
2' ' c'1ca'ilin6;' 'or-','r .Envrrollnlcir^r, - A ..)rir-:i:rici.'r p6;19p+g-qivc
3
,
[]
irvi ronr:tcntal
Coutrol
a.ucl
pub'l'ic Hca.Ithr
Utri'r,-III - irtrros;:lrcr:-c Poi}-r-'iclt'
Co.llscs oi- r:rr polfli.r.ior-,
,
'i
'
W.l{c. I
L
r; a::g
rlcr:.i
ri,itrl I,l .I(cy:,r: s
(1 5L)
t
irrlus'ur:al ito11u+-ron: pot:.-LrtiJr, -r. itrdirst,riat cfilr-icnt, gi,iri)S,
S02, I'lO2r CO , iC^ r'-29,. iLc-.r', i.i:i;r, l,lcc,-; liousc i.;ifcc.u. Lc.-iial
p-ol-llrtr llr ti:.-cott.1'li :-itrlustnr,,'i i cc:.rlr:nt;: 'rllre tshopa1 ?ra.i;c,-r.;,'.
,ltLlior:rob i1c iloll tt'vrou: r,(:-a-r'i . -f.r-lc 1., c l.li ssi o,n sta.n4.er11s a it.l
o r:\ission cc:rt,rol_s .
Suspirttr:.clrl pnlr-i:'r''l air:: r:rat;ci't'r,r1 varlcLis soLrrccs: ?lrc..r.
ct'i'cctr a.sl>cGtcsrs, s rlicosrs c-r,c.
Hydrocarbons, ciilorrrf I uoz.oerpbg 1s, 1::cl o:cir-'1...: of nltr .,gcr-l:
Pliotocl:crrico. l rce.ct,rolls j-,, t'rlc.i,tnos|lbcrc, i>ho.r,ochcrrica.r
sr:roE, ozoirc rlci)I(,iion.
Arr rn.'l it; sta.r,trrrls.
/
+'{
Ilc f
1.
2.
crc ncc
s
:
Fundar:rcutols rli /i.ir Pol'l qlig'r, l:'.C.S'r,crr: &
Cl-cal1infi Our Er:.rironrlcI1!r, - .l: Chcr:rice. I L-c:rsitcc'u'ivc, ,l.trcrica.n
Chcuical Soc:-cty,
197a:
. Environr:rct-lta'l Chcnistry,
Unrt-IV - llatcr Pollutiou
3
A.K.Dc
(151)
Sourccs of waic r polhr',.ion: Scwa.gc, Wc.s f,us L'r'ort il,,'1us'urics,
To.r:ucrics r Dctcrgcnts ctc. cf f ccts ot' t)ol-l-Lr'uanis: 0xy6ctr
rlcficicncl,, iox:-ci'Uy arrrl r-:utroi:l:icctioii.
llornnl lcvcl- of C.issolvccr. o-r-) C:o11 iu r..ratcrioi' f ish 6rolv'r,h.
Expr:rrr:rcir.ta1 r'lctcrntj.ua.',.ioir of clissolvcrtl ox;17;c 1'I iu wa''t cr.
Chcr:rioa1 olygcn clcmanrL (C0D), anri biocircr.ii ca.l- oxir6cn c'lcur.rxr.
I
(nol).
c ?o].ltrt i on : i"lrira ma.t a clis s tcr
?rcatncnt oi' wa.tcr: Watcr c na.1i+-;, cri-icria ior inclus'r,ria1
a.ncl cloncrstic uscs. Scua.6c ',-rctr.tr:rcnt, rnclr-tstr.ia.1 wa.stc watcr
trca.tncnt, rlrinkiug w...tcr sr-rp;rIi-cs. ISI Sta.nclo.rcls f or
rlrrnking wntc r
I,,ic
ta]-l-r
a.
{
Rcfc rcnccs:
1. Hanrlbook oi Lra.tc:'Iicsourccs .p-ncl Poll.rtrou Coutrol,
ii.W.Gchr:i & J.f .Bcrgna.n (f:rfs).
2 . Pr iuciplcs oi wa-r,cr Cluo. 1ri,.',- Contrcl-, ! .ll .l. . Tc t:blttf
3. RAvirouncntol Chcni-stry, A.K.Dc
Unit-V - Polluiion of Soil l)n'vironr:tcii'u
Ag:'iculturnl Polllttioir: l'k:ta-] cyclcs n li.r. b 1o'l oci cAl
ncthylnti on. I;f f ccts otr cnviroirncnt of:
a)
Fcrti
1i- zc
rs
b)
Pc s t icS.clc
s
a.
nr1 hcrb
ici
clc s
:
C
1a s s iirc
rit io
ii,
i.r:
i. c
^u
(151)
avit;',
Dciccti on e.ncL l.tca.sitrcl-tcl". ?licrr:ra.l- al'rc1 plioi:-r'lccol:ll)osrti ou
of pcsticicl.<.ls a1cl licrbic:-r.l.r:s i1 soil . Pcs;lqi rr.c: ps5'i itcs
t-n soi1.
llcc,:l for control oi- cxcoss Llssrgc oi f c.t11lzcr s a. ll,-1 :icrsti ciclcs
IJtilisa.tiou of bi-oma.ss, o.3'ricuIt,-tra1 wa.st.:s c ic: Ba.ctcrio.l
rl,c6racl.o-'t it)rt, Lr'obar e:as .
Disposal of 4isca.rcl.c;1 p)-as'"ic wo.rcs a.:tr1. ct,):ir solicl ua.stucs:
Rc cyc lrng.
I
ii
tl
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uvi'
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of ra.li a t
t lic E,viro
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tur':
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Clic n:ice
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tastins .,"t;;::::
?oxicor
?oxicolo.
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lctttc
pr:'1on6'c6l
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r
n i.orosicjltj'i:.::n,""tt''
a1 cffccts
chriuic toxicitrcs.
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arsc
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nonoxirrrt ntttt
Ice:6i, nc
c;ra,i.ia"t
' car:lui
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' ca.r.erno6.or.".-'-'-ttt"
Rcfo :'nccs r
1. Esscntia
rircrus.,r"ti
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:.
;il;1"":lo.r,
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4.a1ysr" "'"t=ttmc:rta'1
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s in
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u:tvr-roill:lclltil,
(erir1 cipr-cs
of
r''cil:.o.l.s
-of +r,-.
thc t.i.
a) ,oua.o,l'lo"
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A,ocri .."'.I:.:."tr
v''l ter:rr)c i.J'
c) at,o ni""
chcr:icaI
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rr] x_".,r. .;;;::;;::
c ) Trrfrr,.rcd
s
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.,,""i....,J[:j;:jrctrv
Gas clironmt
ri) arr_*a*;:"t"tpliv,/r,rass s i)cjctronctry
.va c-r_cctrorlcs
contrl ....
l'i
r
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Av
lofcrcuccs:
1 . llnviror:r:rcrt-r,a1 Cl-r-rt:irstiy, ''! 'K 'Dc
G . l,'I .Ew i:i;;
Z. Tustrr-li:rcii'ua1 l'tcLircrle of CIrcnIc:'-1- 'a':lal-;,'s:-s '
oi L:-''-u raiLtr() Si-''vc" a:' Elvironnrcutal
U1 j-:--rX - i'Ic:^t lioc'[olo -1'
(?l)
Ciic urs-,"rY
otrs
Tnt:'od.uctior: to rcl-cvant er't' 'c:l-('s ct'4 olli<rz' i:irb lrcil'':'i
iu i]-,c sub j cct .
(soi
s
?,-,i:cr-VT If - E1c: c irvcr, : I'iat'-r ra'l- Prorr'uct
iiiri-r,-T - T(i.xoIlOlly oi
\
P1a'::i-"s'
u
)
!, i
''
irlt ivat:-on, C ol-l-c c'ui t)l.l', I-li oii-.
cation, T r'1r,li:-t, rf iciitiou
inl ,ortartcc
a.n,:!, ttscs oi 1.lIa;t',"s cf t:rr cr_i crnal
Rcf crctrccs:
of l'[acr'ras ' Vol-s '
1 .. Gar.rblrr J.S.Flora- of thc prcsic'lcncy
(195? Ecln) Bot .Surv'of Il'lia' I Cla'1cu'uta
1971+ En'
2. Lwo.rcncc GHli 1951 Txouotry of Vascula-r Plants
t.
Lo
llsy )c1hi.
t.i,cncl1c.A.B.1g8/+.Tlit-.cIa.ssi:]icationofflorqcrrirgp]s:t'r"s
1971 E;1n C8-r:rbricl6c llniv'Prcs''
L,HookcrJ.D.(^,872-1897)Tlicf.iora'ofBr:.t,,s1rf:rc1ia..VoIs.L,rl;|.:r'
p]a'n'"s (Vltti rcf cr 1::t:1
5. Barlr:y L.FI . 19/+,). I,le,nura.-1- of crr'ltivatccl
I
flr
t,
l,
I
t
Macni]-la-i1 compa-i)."', 1[sw Jork '
6.iotrcsrS.B.at1d.;\'E'Lucirsingcrl979i:ian"sys!r'cr:la'iics'
1,rg 61i',U Hll-l- Ir^c . I'icu York
( 3L)
oi iir,i, r.t::i. I t-f c,r' -tc'r, s
e,IktlIoicls, ":ig3oi-'5,
Carb ol'rYcLre.tcrs , ?c rPc::lci'1; , iar,:tcnoir.ls,
-i -.s-:l-i.'r,inlr of cacli cle'ss of
At"ttliocye-r:iiirsr c tc' itc-'I:orr's
L')il s t
r-lrli ll6 s'r, i'''r c ttlrc c l-r-rc r rlr' !
coltiloturr'L c'.r"1 Cc;l i lc'l s'i'11(il; , trcl
cl ass '
-'
syntlics is an':i s ic rc o cil::'t ' ry ltl;..LCr ce.cli
( i iL)
Uni"-I1I - Tcri:c:roi'rs
Cr'l:'rci(:
o'i -,,C'ai)CilCS - -ifcprcllc rul-cr - Ioiloncs
CI-ass if rcaii:rn
r.::'rc r car 2-c t:rc, C ar o rtc ,
l,!r,:n+.liol-, l{ctiior-ic, a-?lir-r jcl.ti-: ct r -)
ilisabol-c:la: I
Carorr.t-c aclrl . e.-Pi::i:l-ic'r Ct ;iior', F8-r:rr:s:rl ,
E:'cr:ri>lirlonc, Abi r:'uic
Ar rst oIc clicu:lc . 1-'rlivr:,rarit:: Tshrre.ronc,
-j-c,
lrc l- r't s o t::c::-u of Ln'rc: o1, .--5tn)'ri:', B-o't:tl'rilt'
qua.
L c i 11
Utrr-t-II - Cl8-ssificatron
I
I
"
r
:-.
1r
I
I
61
4g
Sir:iolion V'l-s
, .{'i el':c r Tc , irtr ttoi,, :
C)i.:r:iistr;,' gI' tl-rc Tc1'FcrlJs
: .. i.:r'ix!,noiris ir.l . b1.' I'trc.wtraa
.?6. Ir.B.1''i i:o (:i) (t9Zlr
.?.7.P /fi91 'uo 5005 (1971)
i.i 971) '. ' .
,
j,r;i!
I
l
)
5
o
:
t-
-
t I oIJ,,
Unri-TV - Stcrorl.s
of s:;<-:'orits. Dc ta r-l u il : L tlclY
Cl-a:: :-ircirio:r r,:rrr. rsola.tion.
:1.
.-.:. '
rn c o.rrr.r ilr; !: il,-r c. tir.c clpc alr:ll i,.qrr, s7n'ul1c s r s i l-:ri s.'cc roo CIcr;:r'i s.urj' oi t].c: lol lowing,
Ocs-uro'ic, Dros t:ct't'1--:
Cl,:fist,c:r'o'1 , ir6'r':;tcIol-';
).\i3,OccIcrfr,.:ro1
0cs'urar'i:r:r1 , cr:trr-o1 ?qti}lb4iqc r- An-r1t:os+-ci oilc, tosiostc;roi:'r
?:oi;c:rtro:-rcr tr -i 1c,, ac:-r1s r: ciio'1ic acirl . Cor'uisoitc: Atlrr'
....;.i .',. ,-r .. ._ ,- '
cor'urcostcroil(r.
I
'
Ilciorcuccs:
.,,
._.
.l
''.
1 . Ficscr a1r1 iicl-:ct', '.Siq{glfi,st
Z. | llic Cli.;r:rislury oi StOriorls I , K1i'irq...
) . rChcnis'ury oi ihc 'stcr'oirts' I I .Shoppc '
/ - r-r.l- filirarl,-,ciro I 'uo ilic. ' . nisi.'y, c'f tlir-) Tcl',rctioirls
+.
S'ucrl oai.sr , 1c:-tilIc'uiol:.r' :'
t7c:
5, I Op',:-cr.l rcia'ccr",' 4:-sicisaonr, Diirassi l{cAra"'r' ri-11-(
i,. rSii.r.ictrrra.l c: lucr,-iaiibn of jiatuf il i:ror1r'rcl,rr bJ l{acs s l() c 'u r' (l
:'
scoP:f r, Djc:rassi, ciia'I.
Ilcll ,cIi cl,: Ici': fr'ir:i I-L.Fino.r Vo--t-.II
(vr)
Uni^;-I/ - lfka1oirr.s
c
il o nc: n cl attir i: , c l-a-: s ri' i datiori .' I s bJ.ati on c !':r'-' r:in t o ;-:' ail i
j'
'
Dctii -l-i: 'r- iirtrl''' o
r::trl o'ui,cr'.c.'ct. li cnc-,s Of puriircation.
.
.
I l r'
i al l:\/n:..L.
rr.ri '
r,'
'lr
i'f
i
t
4e
Morphine, Reserpine, Tylopho: rn and Lysergi:
aciC '
References
1.
2.
3.
4.
5.
6.
t
VI
Alkal-oids bY BentIeY
The alka-Ioids by Manske Holmes' vols'
The Plant alkaloids, Henr:Y
Kodansha'
Natural Products Chemistry Vo1'I and Ii
rU.V. spectra of alkaloidst by Sangster and Stuar
Relevent chapters f r:om F inar Vo1' I i '
(eL)
Anthocyanins
General Nature and Structure of Anthrocyanidins'
Intreduction,
(Daidezein) and
Flavone, Flavonol- Quercetiir t Isoflavone
cha loon e .
eferen c es :
R
.
2.
3.
4.
I
Bentley, The Natural pigments ' Interscience'
comPoundsl(Pergamon)
Geissman (ed), the Chenristry of flbvenoid
(Pergamen) '
Bernfeld (ed) Biogenesis of Natural compounds
Academic
Harborne, Comparative Biochemist'ry of Fiavonoids
Press 1951.
5. Finar Vol' II Ch' 15'
rit VII Prostaglandins
j
t
(
51)
stry of Prostaglandins - Isolation classification '
PGEt PGF' PGA and
structural elucidation and synthesis of
PGB grouPs of Prostaglandins '
Chem-
References:
1. Pine, Hendrickson, et' Ql " ch'17'
Kodansha Vof' II '
2. tlaturaL products chemistry ediied by
Con
td
t
t_
;,
tt
{
t\
s$
5o
Jnit VIII
Biogenes_is of Natr-L::al_ p:r.oducts like
and a-Lka-l_oids
R
teiperr e ste::o:i-cs
(51.1
eferenc es :
' Bernferd ( ed) Biogenesis of Naturar products (r967)
2' Mulheirn and Ramm, Th= bi.os vnthesis of s tero.r-s
chem
Soc. Rev. j972, ZSg,
3. Relevant chapters cf i .L.Finer.
1
nit
Spectral application (I .H. , U.V. , lJ.Fi.R . Mass,
C.D.
,
and 0'R'D' ) in the structura-r- er-ucidation
cf Natura-r-
IX
pro ducts .
(tzt)
References:
1. Determination of oiganic structure by Physical
nrethods
Academic press Vo1. 1 to 4
?. Schwarz (ed) physical methods in orgdnic ch=mistry,
0l-iver and Bou d (1964)
J. Djersassi, 0ptical Rotatory
Dispersion Mc.Graw Hil_l_.
4. crabber '0pticar Rotatory Dispersron
and circuLar Dichroism
in organ ic ch em is tr3, H o Idern Duy ( 1 96 5
)
Wil-1iam and Flemingr Spectroscopic methoCs
in orgenic
chemistry, Mc.G.raw ljiIl (lgSS)
5 ' Bib1e, Interpretation
of NMR spectra, pr.enurn press ( 1g65)
7, Nature 196Br 217, g1g
Ha.emin and Ch-t-orophyl1
(GL)
E
rit
X
Structure and synthesis of porphyrins, Chemistry
of
Haemin
and ChforophyII.
References:
'l
. Finar Vol. II
2. B iochemis try by Leneinr_:he:
.
*)r
Ci:c::rrs-ur;r (t;O;':
""uo
(1 2L'')
S!t'r r-lct'-': r' oll soiids
ailr'l'
'l-tr-r'(:J':-;i''l?,oirclrirg
Tricva*c.cruLal-sicr.ccsr':,(:i-ii-ricbond-r'u'lrc6vnlc'iri'
1lii: i-r;;''L"otou boitcl''
L,olrlI +-1ic' i:)c'i-'r.il l-c oo'r" i:';111;
vari-cu: i<r;:lr'l s cn t classrr'lCor:ri:arls o11 oi 531'-1s oL"'-i':t'r
c
-ilL'(: -ic:-uLifc of bour-Lc - Ioii'i
i':esc:r'l
ii
ca-.fou oi scliria'-'ct:lic: Ii-u-uic")' l:c-;al-f':
'''ulcc'
Il-t3]-uc''':-l-er
Ia+.'r,rco,
lr,.tticcI 1-'tl;:-i:(: wi"il ii-Bc':c1 '
Papcr-VT-!I -
ljnr+-- j
i)
111
ala
Po I--r'r:lc r
/
l)li
.illcc'''j'rc:
3ol jr.l
'1
1 :r lli
-!licorrc
iinri-f I - ScLrC- Sta fc'
ii'l
l-1a,
s
,clLr]'s
rlcf
ccts, Linc c1c'fc:ts ' Planc
a.irc1 hc].c: s
1'1"t
u
n
I
r'"- IV
Ullr -r-
v
cc
ll
I
lr.
I:I
J
il
L:
sr;uicond.uctc'rs
a l-t.rr' ll n-
s'r' o
ic
r
o r.lc
i
d'cl'cc-r's
,
EIc 3'uolls
,l
o
1l
fl
t1
I'
liril
II
r1-
t r o lr s
l-") a 5;31 ii:-r:rircrf ' ;irrns
.ricolrr:itlucs of ir'trotltlc irle'
.)opini;, c o,:li)rcssi-cn, crLlsiiii-l :'nd' U'rai-1ia-r'rcn'
( 1 5I )
c1:cr i't ic:s of so 1lris
i
Irrpori cct rcns on''i Phl s cr: i t'r
ci)i' ca1 iii}r'l l:rz'-gllc'trc
r.f,iclianicel, tlic -i:ra1 ' cl-c cil'ical'
pi'opc: I'tics.
( 1 2L')
:'t !t'l- c s
]/'i
iicacirol;
S'ue'uc
Solrr't
- s of tlic -u;"prDc cor:r;.:os rtrou r<:o'c^ui
r.(s) -7;(s) +c(c)
Inpc r f
r1l
t;
Ir
(t ri,)
Uni-t-I I.I - Cr..,'staI Dcfccts
?oint
li
ir,
i/i
ancl rns'-rle,tors
i\
lr
(i8r,)
Frcc clcct:tou 't'l-c or;i oi s
gal|. tlicorl' urf :;olid's
into cort''ltlctors '
Cizir, sri:-ca Uic:l of sol-i'r1s
1)
li
I,
es
l'nal- d'c col)l)Lrs rtiorrs - i:
r sothc r:.1a.'l i''lrr'l t-tolt-l.so'-ic
l'rc'uiro4s' hiia]"''sis oi
g.79lLltr,l-oi.I aitrl tlrcflro'1;'11'ai11r--ri'Ilc
cqr-1f-ur:n' 'di"' I'roult'u-Tor:rpkll.eca r.rsi-u6 A--'ri't:lr-Er'lic1''cv
ia''t' 't'tir-: ooiltrectuai-Iij
oz'C'crr ri'!c
't ii'-: f rrst
t'r, l-atir-tiil
(''l--c i1i:rl-ratiou oi tli(: sc: rc:la'"rolrshri-ls
wo'1 unc iorr-l'.rli')
is '.ro t r cq ti i-re 11 '
c
rrl:td.. . .
tj
.:,
:
I
.;:
I
I
I
I
i
t
I
I
t:
1
iI
Ff>
- Tlic:1-lliorjravil:l'r'
ljnri-V-I
/\/Lr
cr \
-Pr:.1-rcj'll1clF,acLCId,]iCC!u]-iii|i-lIti:l..;1.e1r1,..t1.1CC111.vC3.
'c-v'r i"l(jrr'i"y''
Sor:rccS ri c:r ' )r ltl ilL";1'llo''
(121)
-. !icactiou kl-IIc-r'1cs
l:lart-Carril]-i l
}iotliso,r,]rc]'I141 l ilt}ic(.1s : A1lp1rcr.:r olr o,i Flcc
Do;'rg,Coe'tsalll1BCd-i,(-)],.1-I,n.nc,Liloroi,Jr';zaud.|i'c-vzcCT
Uni-t -I/IT
+,]rr: r.:qLta.'.ic]lls is 11oi
cqLl..tronsj ( utlc (.lcr I,r..laolf of
g:.-pcctcrL) . ltlc chcu:-s l:1 cll rriac-r'i ott i::on no:-1-iso'r'licrua1
kinctics.
ic :: cllcc s :
L.V.Azarof f : Trrtrocl't'' ')rr':-o11 !'.'' s <-r11r'1s ' Mc Grai^i Hrl-l.
Prcuticc HaIi
Itr.B .Hanna;r: So1.irr.-sta'uc ' ircnisir;-'
2,
I'{ir publishc:'s
G .I .Epif cl"r'cv: Solrci starc ?hysics '
7.
Iic
'1
/+.J.H.BroPli}rIi.i'l.Roscanr'LJ'Wir1f:Thcstructurcancli:ro':r-'r?vt 'Ltrl
tics o f l:{ntc r:-al-s, Vol 't r'nc1 rf ' Lilcy Ei''stcrn
D.A.Young: Dcconpositiou of solid'e ' Fcr6anon'
5.
(),.
lj.O.Buclnikov anrl A.M.Gi1s'u5n3:: Sol-rcl statc chcnistry'
Iia- cl.arcn
7.W.!l.WcndlancLtrthc"il"'l;:l:::ti-orisoiAiralirs!s'iolinUil-cry'
i 97 /+ Ch.I a.nr'i 2 .
'
tt
l],
It_-.
-\- A
5r.
Papc::
Unit
,l
(90
VIiI - x.i:ctj',,e: ?olJmer C]:enistr;
Basic coilccp'bs i"l.I !crn-,-
r)
(g L)
ol-c--1'
pol-yller Science - tlp lcience of largc
(oo"ro) I.Ic:l-ccu1cs. Iris'uo=y r,f tln clevdol:nerrt of rl:c nacronolecu.lar corcept. fi;.1:c-:tr-..ec i:: .,veryday 1iic. lt,atr-rral ancl
syr:thtic pol-]-ners. Di-ffe:r'cn.; types of pofy:lers antl ]:oJ'ynerjzation pr.-rac$L;s. Llolccular forocs an'-1 cl:cnical bondi-ng
in I:ol;trcrs, ;)='-nary bonti.li, seccnclary bo:xl forccs arrl i::tertr\rnclar:.eatal concei:tsof
noiecular iorcas.
?ext bcoks:
. F.I[. Bi]-f"rcyir:, rTex'J book of polyner sciencer,
'.V, 1c;r-1nts?s,.' -trtrl, ?gle)
.)
G. 0,1'; :!r'i' 'i-rincip*ec "i Polyr.Ierizatr-cnr, illc Gralv Iiill(1980)
1
5,
il.i.
ri.-.I-l
!r:e;rtice
,.:lck
c.,)('L
I.\,i. Lsnpe; rCoirtpnl;orary Polycrer Cl:cnictrlrr,
-Ih-.1-1 ( I go'i )
4. Elias, 'I{lc-r:o:olecules: , Plenua Press (f ggO)'
Unit fI
SteI- ileactic.r ?o,'-lnr-,rizaLior (Conclensatioar
Pol;:rerization) (tZ t')
Clenistrl, cf i;cli-..:nla'Lion l:oltrmrczization' $pes of
concien-
sationpclyners'$rycso.siepwisereactions.Intcrfacial
concle-:saticn - F.i-n3 v:rsur elp:::'fornation' Kjletics'
Reactiv:'.ty
ancl-
ncleculatr sizo'
Polyiunct:ona1 conitensaiion polynerizaticn. Gelation. C,eI
poirlt-CxI)CC]-ne..-]i.'.-].observab.icn.I,[oIecu.lar".vei8lltdistribution.
ilc i:r3-S:rssic'n rl'rilr:: izrr'.ion'
(rz r)
Unit IrT Ralj-cal Ji:a:r, (r.clcr'lior) ooli'ne-ization
vi:lyl pol-7:ter-izirtion' v-ry' nonorlors' Effcct of Cectronics
struc'turc oJ or,1-alic corli)o-inds' L{cclrrn:st't of uiny] railical
polymerizarr cLr, ij;-1;s1l:r2l-llal nethocr's i-n vinyl llolitrezization'
Rate ci 'tol1m-,cr1za"-i sn, llte '--- il'tiation'
Conil1.
5+
Stea.ly
state ki_rctics. De3ree of poly:rerization
ancl clrajl
tra.nsfer. Absclute reacticn i.atcs.
In.Iivitlue.L rate
constants. r',[o]-ecular lve:-glrt clistribution.
.ictivaticn energjr.
ibat anct iyce energy of pol;rnnrization.
Unit IV IIor_rcrilical ctrain (&lditj.on)
lolynerization.
(g
r)
Cationic poJ-;merj.zation _
necln:risn anci khetics. Anionic
polynerization - exani;l_es, kjnetics
ancl uec.l.:ani*r.
co-ordirration polJmerization
- khetics aniL .cclrnnisn.
?ol;rncrization rvith supitorteil
netal oxiclcs. D jiferent t14:es
of catalysts.
IIc catalyst polynerizations polSrncrization
via zwitter$on
i-n
Unit V
terr:rediates.
Copolynrerization
(lz t')
i..inc,ics. Il:e co-otrllJmeriza.t-ior
eq.uation. Lfo::oner
reactivity raiioe a:x1 co-1:olyncrisation
ilararxe ters.
Irrstantaneous coalosition of fcecl
ancl pofJmrer. Coni;osition
of cqrolylers. yariation oi ccnj)osition with
conversion.
Cl:enistry
of copol;merization. Reactivit;r ancl structr:re
of mononers axd. radicals, fonic anO step
reactions
poI;nerization. Block anci Craft Copolj,z-rcrs.
l
I
i!
I
I
I
Unit V-I polynerizaticn tecl:niqucs
1
I
G r')
polynerization ilhonogenous
Gas r;llrse
VG
irollnerization.
I
lr
l,
and
Bul_k
lnterogenous slstcns.
i>olylerizat ion ancl polyner
Contl.. ....
l\
t1
x\
?ta
+e_
precipitation'
sirspensi-on pollmrerization
and emulsi.on poryrnerization.
Dlene and divinyl polynrerization.
I'lono and heterodisperse po1.r'mers.
Unlt Vff Chemical Reactions of pdlyners
(12L)
Reactlvity of functional groups
otl pd11mers. Floryr5 concdpt.
chemical modiflcation of
r-inear and crosslinked polymers.
i:o,1mer
anal0gous reactiohs.
Effect of cross_linking on ti:e
reactivity or.
fwrctional groups.
I
ii
Functionalization of 'polystyrene.
preparation of
ion-exchange resins.
polymer-bound
reagents- applications.
References : _
1' p'l{' Billneyer, rTextbook polyrncr
of
ssfgnsgr.
Wiley
- fntersgience, l91t,.
,
2' H,R.
F.l{. l,ampe, ,contemporary
.A11cock,
Chenis
3
try' , prentice liatl,
1981
.
,
' G'Odian' 'principles of polyaerizatiohr,
Mc-Qrsw
ademic
5.
K. J. Sar,rnder-e
$
pollaer
Fr.,11
;,
1y70.
1
gB0.
, rOrganic Flymer Chemistry,,,
phapman and Hill;
London (1973).
6.
F.J. Flory, rprinciplex of
poJ_yzrer s ci.ence r
.
7, E. T. Severs, Rheology
anci poly_aers
New york, 1958.
,
Reinhold
r
Unit vrrr Rheol0glcal Behaviour,
fubber Elasticity and
viscoer_astic
prop,.rties (1ZL)
Types
cf Fluid
DiJ-atants,
Ff_ow:_ Newtonian,
Non_I,lewton'an, Visco_elastic,
Bingham plastics a:td pseudoplastics.
t,emperature
of viscosity. Efastic Effects
rn polyrrer Mer-t fr-ow:
Dj-e Swelf, Elastic
turbulence or IvleLt fracture,
Shark skin.
,
I
Dependance
1
ri'
t
)
I
{
,
C
56'
_59_
Kinetic theory of F..rbber Elasticlty,
Thermody,amj-cs of
Pubber Elasticity, statistrcal
Theory of Rubber ,r_asticity.
vis_
coelasticity: Experimentar- Methocrs (creep
anc stress relaxation),
viscoelastlc Models: The Maxvrell
Model, ?he voigt Mocrel, series
combinat6ons of Maxvrell
and Voi.gt l,lodels. Relaxation
and Retarclation
Dynamic Mechanical
unit rx
properties.
Morphol0gy and order 1n crystalJ.ine
polyiners (6L)
configuratlon of polymer chalns,
crystal structilre of polymers,
morphol0gy of polymer single
crystals, structure of polymers
crystallized froni the md1t, crystallization
kinetics.
References : _
1. F.i{.
,Text book of po1ym""
""1".r".,,
Wiley - fnterscience, 1971
B11J-meyer,
2. A. Tager, tphysical
poJ-1mer
Chemistry,xr.I{ir publishers.
3. Charles Transford, ,physical Chemistry
of l{acromolecu,es,,
John Wiley Sons fnc.,
1961.
4. J.A. Brydson, ,FI_ow properties
Books, London,
of polymer raeltsr, fleffe
19TO.
5' A'H'P' skelr'andr
I.Jew york, 1949.
'Non-Newtcnian F10w and Heat Transferr
, ,,i_1ey.,
6. Davld J. lvill_iains, rpolymei.
Science and Engineering,,
Frentice-Ha1l, Inc. New Jersey,
l9Tl.
7
.
E.
T.
Severs
,
r
Rheol-ogy
o f.
Polymers, i),einltrrid,
IVew york
,
.1958.
B. A. Rudin, ,?he Elements
of poly;rer science and Engineeringr,
mic press, New york , 19g2.
p20292
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