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Eirst Ycar Chcrnistry f IT

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Eirst Ycar Chcrnistry f IT
It
SyLLtJUS FgB
I{.Sc.
fi46
ADI.4TSS,fON
Dgraticn
I4arks
3 hrs.
3 rr
3 'r
3 rr
6
6 rr
6 rr
100
CI.11iIIIS,TRy g1111I,1]NATION (
0lill^tA1lDs)
SCiI]]I/E 0F nl'$14I1{AT IOiIS
Eirst Ycar
Thc'crctical Chcrnistry
Pa1:cr f
Papcr IT fncrganic Chcrni-<tr1' f
Papcr III Organic Chi:nistrY I
Papcr W PbysicalChcmistrYf
praebical TI'ncrganic Chcmistry I
P:ractical II Organic Cbcr:ristry I
Practical ffI Phlrsical Cbcrrristry I
Labc.ratcrlr Po"crds
v iva-vccc
rr
100
'100
'100
7o
7o
7o
3x10
30
3x2o
6o
Scecnd. vcar
3 hrs.
V Tncrganic Chcrnistry II
3 'r
Papcr VI Organic Chcml*'etr5' 11
3 rr
Papcr TII Physical Chcrnistry I1
Papcr VIlf. E1-cctivc Pa.1lc'r
Anal Yt ic al/inv i rcnrnc nt a1/
c"go n i" /i ilyr'w/ ]da t ura.l Pt cd'tct /
sciio s:tatc- chct'ris LrY/
Thccrc'uical Chc'ntstry.
3
Practica1. IV fncrganic Chcmistr5' 1f 6 tt
6 rr
Prac-u ie al \r Organic Cherlistr)' TI
6 tr
Practical Vf Physical Chcmistry fI
3 xl 0
Lab cra'u lry rcc crd-s
3x2o
v iva-vcco
Paper
rr
Tctal
T:ta1 ic.r First and [jcccnd Ycar 14.Sc. Dcgrcc.
ts/
1673"
100
100
100
100
7o
7a
7o
30
60
700
-,4il-
I
I
,
I
UN
SYLLAI.:US
Therc
s
bc lcnr:
f
,t l-,i.rr
IVEtis ITY
iIhIt
'
tiF
SLHEtVi-E
t'ALIE'UT
CF EXAIVI
Ccursc as Givcn
bc 1
Ma
tieal
I
Chemis
trY
II Incrgcnii hemistrY
III 0rganic Chemis
Pa F,er
ry
IV Phys ical- Chem
Pc lJL,r
Pe pcr
-,
I
I Incrgani Chemis trY
Frc cticel
I
Chemi6trY
Prac+'icc1 II 0 rgan
I
trY
Frcctical I I I Ph vCice I Ehemis
rCs
Labora torY
ks
3
Heurs
100
3
Hours
100
3
Hours
100
3
Hr urs
100
UIB
?0
C
6
Ho
6
Hours
3
x 10
J x ?o
70
70
60
vo-Voce
700
T
Et3!'
otal
ttrtStrtt-
vmi/zii.12'rJ6
I
-12.
P/rPEI
I.
I -
THE0RETIEIL cHEMIsTRy
Quantunr Chemistry (gC
Hours)
-
(. ) _lt""j" r*
( S Hcurs )
,t
Pi rticle charactcr' cf ra.iation.
'n/avc charictcr of
paxticlcs. Matter waves. Elcctron Ciffrcction.
The un_
certainly princi;:1e.
(b) FcsLul_atr,_s _qll qucntuUech.nfgg
(S H:urs)
Postulatc connecting obscrvales an.il
operatj.ens. ThD ccrresi'onl'ing orsrators of the common
observebles. The
Hamiltcnian ar-c'iratcr. Eigen velues
of cr)er.tors. Eigen
ft-:ncticn Eigen val_ue equaticns.
Expcetation ve lucs.
The schrorJinger eguetion. Time
CepenCi;nce.
(c) Apr:licrtion of the sch
s
tems
(C Hc,urs )
The free I-rerticle.
Thc p:article irt a one-ciememionalbox:
Eigen f unctions cncj eigen
val_ues.
The particle in a
th:rer.- - clinr enmonal
box I Deganeracy
The L-Du-dirnensianal harmcnic
oscil_Lator. The Hermite
pclyncnials. The three
cjimc.nsional harmonic oscil_latcr.
Thericla rotatcr. Transformaticn
to sphericalpclar
ccorCina tes. tinalogV
to thc particlc_in-a_ring
.1nd the
particre-upon a sphcre
p:roblems . Legcrn
dre porynomial_s .
AssociateC Legenclre
[)olynomials anC f unctions,
sphar-ica]
herrnorrics . hnguicr
momentum oljeretors
u'r.,,crors anc their
expectation va-iues.
(c) Hyctrcrgen-rihe
ctorE (s Hours)
Th' b'/'r/e eguaticn in
sr:herical p-'oler cocrc.linates.
so-r-u-
vnS/2C.12.A6
\
Contd....
t
-1
I
_i
tion cf the f , g, end .g_t
equations Leguerre polynomicJ_s.
Asso_
ciatec! Lar;urre y-orynomials
. Lis t of wave f unctions
. Eiscussion
of the wevc functicns.
0rbitaL cliagrams and thcir significance.
(e) Li-j..rr.ximF
The perturba ticn methods
.
Simpre ar:r,r-ici tirhs .
zceman
ef f cct
in hycreicn-rlke etems. 6rounci
stcte cf the helium atc,,.
The v:riatiln methr,C. Siml
le efrl licatiens. Start ef{ect
in
hycrogen-like atoms. 6rounc
statc cf the hcrium atom.
(f) EJ-ectrcn
_.-__... tsl_in (z hours)
Spin functions a:nC oljeretors.
Cnupling of orbital ancj spin
f uncticns. pcuLicjs excl_usicn
princig_1e. Spectros co1. ic term
s-r,mbols for atoms.
.
(g) c.mrr"r."t"rS : (z
Hcurs)
Slaterls treatment cf comp:Icx
atcms. The s c.l-f -con sis tin g
fieJ.C methccj. Hertree_Fock
methocl (briet Cis cu-*-sicn
)
f
"xt
; q. kS _IS-:"rlencecl:
1' Erenrunt;'ry Quantum chemistry,
F.L.Fi1ar, Mc6raw-Hi11
2. fnt:.-r-,,Lj ctiL.n to Quantum
Mechanics,
A.K.ChanCra
Ta
.
4.
3
ta
_t4
cGre
w_H
iLl
Quon tr_rm l"/techa nos
,
Quantum Mechani.cs
fnc
Straiss, prentice_HaII
in chemist"y, M.tdrHanna, tnr.A.Den jamin
IJ. Chemical
____ loncjipg
l
(tf Hcurs)
(")
The mcJccula r orl-.itr 1 theory
Excitcrl
s
te
tes of Hi
(Z
Uours
)
for the
grounC
stete.
Contd... ...
vn
i /zi'. .12 .
1
-o
.
a-
a
(b) The hvdro r;en molecule ( 3 Hours )
'
molecular orbital ana valence bonC treatments for
the grnunC str te onIY.
(.) M0 and VI treetments !f moes c-o[ .fex cliatcmic mole-
The
(S Hours)
cuius (Quel-ttjlrf")
as examPles
Lipt Pe2t D2, C2, N2, a2 anci F2to be cliscussed
anr.i HF tr:be clis
cf homonuler.s!f3f,r-mic mnlecuJoe' L0Hi CC' NC
ed cs examples of heteronuc'Iear rnolecules '
scopic tcrm symbols for cliatomic molecules'
5
cuss
( r! )
Comrlax mofecules :
(
3 Hours
pectro -
)
Hybrici orbita-ls ' DirccteC valence
treated
(Flcthrnc, wa t;r, ethylene and acctylene to be
bonC Ien gth
excml;1es . DonC prol'erties : bcnC energy '
Loca lizeci bci!=.
as
a ncl
boncl anEle-
:
(e)
Thr,:
Tl-re
(
2
Hours
)
s vs tems
par:ii-cIe-in-a-Lrox morlel for lineer conjugated
tems
s
sim;-'1e HM0 method ' Ap;rlication to s imPle Ys
]ike ethylene, butadienc and bcnzene'
(f) Forees on molecules (2 Hours)
encl its physical'
Thc. Eeneralisecl Hellman-Feynmen theorem
siEnificcnce.
Textbooks
reccmmenCed:
McGraw-Hil1
1. Elementr ry Quantum chemistryr F 'L'Pilarr
ancJ J 'Selbin '
2. i:heoretical Inorganic chemistry' M'C 'Day
[,cinhclci
a
.
VaLancc' C.Ii. Cculscn, EL0S
i,irl-L,cul-cr crbital Theory for er ganic chemistry'
L.Strutwrriser,
Jchn WileY
Contd. . . ..
vnj/2L.12.1rL6
I
III
S
.ectroscoi .v (2O Hcurs )
#
'
(5 Hcurs)
(o) G"J,e
Electromegneticrac]iationanclitsdifferentregions.
Interationofmetterwithrcc!iationcncjitseffccton
theenergyofthemolecule'0riginofmclcculrrsp'cctra'
Th"o"y of, ihe crigicn of clectrcnic ' viborationel ancl
rotatinnol spectra' Intensity of s[)uctrel ]ines'
Transition
Dependancc t-f intensity on population'
prcbabilities ancl selection rules '
(Z ncurs)
(b)
changEs r
Vibrctinna.I ancl vihra tionaf -rotational energy
s p'ectros co FY . Ylbrat lcnal
ed SPcctrosccpY' R9m1n
bctween
fi>c cira': - Be tat t cn
"
3 Hcurs )
crtia , bonC length
The rleterminition ef the moment cf in
the heat of divibrr: tion f requen cy r Force cons tan t ancl
mo
I ecula
r
(
ssocia tion of dietom j'c molccules '
(i)NMR anrl ESR Si-.rectroscopy (3 house)
of simple
Gencral thcory and epplicetion to the study
molecules.
(e) EIJ:ctronic sPectra (2 Hours)
and the
I ts re .la tion tc the e lectronic arrangements
of electronic
symmetry of molecules ' Differcnt types
systems '
tremlitions. Electronic spectra of conjugated
Contd. . .
I
b
s
re cerruEtn
Textba
ck
1.
Physical chcmistryr F.A. Dcnial-s cntl R.A. AlLcrty,
d-u-d :
WiIey.
2,
3.
Floleculcr silectroscopy, Di'rncw, McGraw-Hil-1
Funilamentals of Melecular spectroscoi'y, Darnwel1,
Ta
ta-t{ cGrr w-H il-1
tructure end cl_remical !rnrlinri inclurling
Molucular 6pectroscol y, Manas Chanda, Tcta - McGrew-Hi11
l,tornic
s
I
5.
thysicaJ. chemistry, P.W.frtkins,
a
ELUS'
t
IV.
(5
EJcncnts of-gEgg!-ThcogY
rrours
)
Difinition of a group. Mul-tiplica+"ion tablcs '
Examplcs of groups. Subgroupso Synmetry clcncnts
and synrirctry operations. thc syrmcntry poin+"
groups anC thcir systanatic idcntification'
Cha-
ractcr tablcs.
Tcxt! ooks rc comncndgd:.
l.Grouptlrcoryand.synnentryinChcnisLr!tLowcaI1
Ir{.HaI1.
2.
Chcnical applications of Group Thcory, F.A.Cotton,
Intcrs cicncc .
3.
Synnctry in Chcnistry - H'H'Jaffc and M'Orchin'
LIi1.ay Eastcrn.
/+.
Physical Mcthods in Chcr:ristry,
W.B .Saunclc
rs
.
R 'S
'Dragc,
-
-EpAEEr rJ_rNeRGANrc grn_r{J_srli;ar"
r
.
l,rl
t^ r.
urs
)
l"letallurgy: 0ccurrcncc , cxtra ction, ref ining,
-spccific uscs and important a11oys of thc following
nctals. Bc, Ti, Zr, V, l4o, lfi, Platinun nctais,
Cc, Th and. U. Principd,cs of powdc, rretallur6;r
.
tJ
llctallic corrosion and Passivity: E1-ectrochenica1thcory of nctallic corrosion, protcction against
Ilcto11ic corrosiun.
Pass
ivity of nctals.
Bcfqxa.ngcg:
.
2.
3.
l+.
5.
1
Rafc nctal
f
"btaIlurgy. of non-fcrrous n:cta1s r W.H.Dcnnis.
Principlcs of mctallic corrosion - Chilton.
Corrosion and oxidation of r.rqtals - Evans i
EIc ctrons , Atoms , I4ctals and A11oys Humc - Rothc ry.
(z t ours)
Lanlrranid.cs anci. A"ii.,iao,
I.
Hancl
book - C.A.Hanpcl
.
Scpasnlion by ion-cxchangc and solvcnt cxtraction
ncth64s. Elcctronic configuration, oxid.ation statc
:rtonic and ionic rad.i1, absorption spcCtra, comparison
of co orrlination Chcnistry with that of trflnsition
ncta.ls_.- _ Lanthanidc ehclslls r . Transactinidc clcnents.
tr.qf c::e ncc
g:
.
2.
).
/+.
Chcnrstry of Lanthaniclcs - T.yoc11cr
Thc ?ransuraniun clcncnts
G.T. Scaborg.
G.T'Seaborg'
Man nado Trans uraniun c]-cncnts
Inorganic chomistry J.E.Huhccy
.
Arj.vanccd Inorganic chcmistry - F.A. Cotton- anrl
1
5
f II.
Co 6l6ination
coEIPounc1s :
G.Wilkinsorlr
(t 5 trours
, Typcs of LiganrLs, noncncJ-aturc and isoncrisn'
----_
Formation an,:I stability of complcxcs. Naturc of
nctal - Ligand bond. Thc cffcctivc atomic numbcr
rulc, valcncc bond, crystal ftelil antl Ligand, ficld
thcorics. SpcctrochemicaL and ncphclauxetic scries.
Mo]-ccu]-ar orbital thcory - a bricf study.
bna
)
RcfcIc!ccs:
1
.
Advanccrl fnorgani.c
Chc
nistry
F
G
2.
.A.Cotton
and.
.Wilkons o n.
3.
/+.
5,
6.
Theorctical rnorganic chcnistry M.c.Day anrL
Sclbin.
Inorganic Chcmistry - J.E.Huhcey.
Coord.ino.tion Chenistry - Basalo and.
"Tohnson
Coord'inat ion conpounils - S .F .A.KcttIc .
Chcnistry of thc coordination conpounrfs
J.C.Baj.Icr (.rr) (oa)
IV.
tloblc gas can!.ggndqj
,Synt ho s is,
pro
pe
rt ic s anct s tr
(5 frours )
uc
t urc .
Rcfc rgnccg:
1.
2,
Noblc gas chcnistry - J.A.Ho11oway
Iloblc gascs and thcib conpoun.ls , G,Ivfoocl.y ancl
3.
fnorganic chcnistry - huhccy.
V,
fntcr halogcns aq4jqlyhalids
Synthosis, rcag!ions anrl structurc
JDR
Thonas.
(6 tours
)
o
Pscudo halogcns.
&cfcrcnces:
.
2.
3'
fncrganic Chcnistry - I. Moc11c:..
fnorganic Chcnistry _ J.E.Huhcey
j'fo4crn Aspects of rnorganic
chenistry
1
Vf
H.J.Enolcus
anrl A.G.Sharpc
Inrtrr{r'.nic Rinris an,i
(tO frours)
"ng;Lnlgrnorganic heterocyclcs: s-Nr p-N anrr. p-s ring conpouncls
Polyphosphazcncs ancl polyncbic sulphur nitriclc.
Borazincs
Coordination polyncrs
.
Siliconcs
a
1l
(
to
Silicatcs
Isopoly and heteropoly acid.s.
Refercnccs:
1.
of f nor8anic Chenistry _
lI.J. &:relcus ancl A.G. sharpc
Mod.eln Aspects
2. Stn:ctural Inorganic Chenistry _ A"F.
Ifc11s
1. Aclvancecl fnorganic Chcnistry _ F.A. Cotton
iy'ilkons
and T"
o
n
4, Inorganic Chenistry _ J.E. iiuhccy
5. Phcsplio::cus - llj.trogcn conrounds _
II.R. Allcocl<.
6. fnorgrnic sulphur Chcnistry _
S. Nickclcrs (E1.)
7. Organonetallic pclyners pp,
111_j21 _ c.E. carraher ("rr)
J.E. Sheats and
B. fnorganic rings
vrr.
EIe
C.U. pittnann (Uas)
andi
ctTon d.efi cfSE_S
chains - A:nitage
gppu ncls.
Boronhydrid.es
- Synthesis, reactions structurc ard.
bording. Equetion of, balance polyhedral
.
anions.
Carborancs c,nd netell_oboranes
_a
0
horrrs)
l:rief stud.y.
Ref crc n ces
1. ffodcrn Aspects of
2.
Aclv6nqsd fnorganic
Chenistry
1. fnorganic
Vf
f
.
JnorE:anic Chenistry _ H.J.
E:rcLcus
and A.G. Sharpe
Chcnistry
- F.A.
Cotton Bnd e.yilkinscn
- J.E. Huheey
nfreo=y_€lnaicatqrs,
Acicr.-baser recloxr ad.sorption,
netallochrcnlc
f luores ccnt a rrd. chenilunlnes
ccnt Incll ss1.=.
Relergn"ep-,
1.
A
Tcrt book of qrrantitative
fncxpanic A.natysis.
A.T . Vqg:e1
2. Lr:alytic.{
ukt/201285
,
Chcrisf,sy _ D.A. Skoog and D.M.
West.
t
.I
1.
identification of four netal ions,
tuo of which being less faniliar elenentst like
Separation and
T1., }f, Se, Tc I'Io, Ce, Th, Ti, Zt, Yr U
arrd'
ti.
(nUninating acid. rad.icals not to ba prcsent)
2. Yoh:netric estinations using DTA,
arrnonir:n vanadaiet
ceric sulphate, chlorartine-T and pota-ssiun iodate.
1.
Colorir:retric dete:minations
nangancse,
Duboscq
4.
of
chromiunl iron,
nickel, ard titanir:n usirg either
or photoelectric Coloriraetet.
Inorganio preparations (tO).
Ref crcnce:
1.
tA Text Sook
A.I.
of Qralitative fnorganic Analysis r,
Voge1.
2.
rAnalytical Chcnistryt D.A. Skoog and. D.M.
,.
tA [crt Book of fuantitoiivo fncrganic Analysis r,
A.I. Vcge1.
4.
r.{Cvarced.
ar:d.
J.n.
West.
Practical fnorg:anic Chcnistryr, D.M. Ad.ans
Raynor,
tr
rExperinental fnorganic Chcnistryrr
W.G. paLnei,
5.
rQtrntitativc
Chcr:ica1
I.l.l. ilmdcll et
Ana\sis r, f .M. Ko1thoof,
a1.
taa
l:.:t i?a1286
I
\
Y
/a
ONGA\IIC GIHVTISTRT
(l+
a)
-opt.+gllSsgc"igat
Mclacr:Iar d.isynnetry
hours)
axd
chirality - optical actrvity
cluc to nolcculax st:*cture
ancl c6npq-rl6dg containinS nore
than cnc J-synnetric carbon
aton. 'Ralative arrl absolutc configurations. Seeuencc
nrlc (n ancl s nctation). optical isonerisn of conpounds
atd containing asynnetric carbsnatons _ Biphcnyls
allcnes and. spirans, asynnctry cluc to folding or
helical stmcture - hexahelicenes and. tra.ns cyclooctAne.
.ptical isonerisn cf nitrogen and sulphur conpound.s
and.
of cyclic and. bicyclic conpounds (fuxitic acicls and.
substitutecl
b)
a.d.anantanes)
.
.
Geole-tllga-1-gsoneris6 with partiarlar
rcfcrcncc to
ring conpounds . E_Z notetion
with illustrations fron
acyclic systcns" Ilcthods of
cleternining configurations
of gconetricar' isoners cyclitol
ancr hexachl0ro cycl0hcxancs,
conpound.s ccntainirrg,
C=N clouble
c) Confornational anal.vsig::-
bonclso
:
Confozmatlons of
1'2dihal0cthanc - d'eternination.
by ncasr:rencnt of dipole
nonents - Confoznations
of cyclobutanc ard cyclopentane.
DetailcC stud.y cf eonfornation
of cyclohcxancs u-ith encr8y
consid'erations - clinethyl,
d.iha,0, cihyd.ro:cy cycl0hexanes,
41kry1 cyclohexanols,
cyelohexane cr.icarboxylic aeid.s.
Ccnf crnations of nccliurir
aircl large rings _ Fusecl rin6i
systc:::s - ciecaline,
nonosubstitutes c1ecal1ns 1 aru7 2_
I
"cr."'--'-rl-s
r'l:cl
.eelly1 :.'nincs, confo:nation
ard.
rcactivity -
llcaciions at- exocyclic and
at ring positlor:s - steric
ccntrcl ancl stereo.elect:ronip
fae,tors.
\:kt/2fl12a6
tl,
JLe€.p
rer.-q.!_!-o qlp :
l. ELict-, stcrecclomistry of carbcn ccmpouncls 1962
2. Eliel, et aI confcnnaticnal analysls'
3. Sterocchcmlstry bY I(,Mts1ovr
4. Sterio effccts in organlc chcmistr"y Ed' bv M'S'Newman
5. Confsrrnaticnat tt:oorlr by M'Ilannalc'
6. I+inar Vo1s. f and If .
If . Intr od oct i cn t c Ptrys lca 1 Orga nic Chcm istrl''
(") Mechartisr:n with steroochemistry cf nucleophiLic substituticn (U) substituont effu-cts (a somiquantitativa'
ccmparativo study cf thc incluctivo, nrcsclucric, olectror'rcrig,
incluctcmcric and sterlc effects cn roactiyity basocl mainly
c, carlrcr5rLic aclcls inonization) (.) Quantitative co*c!-at icns cf substitucn1 cffcct wltlr spbciaL rcfercnco tc
trIammett and Taft cquations, thoir applicatlcns and stcric
substitucnt cc:rstants (a) scLvnnt effccts ccmpriging
basic aspccts oifl soLvcnt structurc, epiricaL mcasurcs and
paramcters cf solvent polarit)' ( fitc y-valuc), lrydrogen
bcnding (o) Salt effects (r) carbcnium icns of spaclal
(lJhcura)
r.ntcrest.
Bochs Recommcndcd:'
1
2
.
C.A .Bunt cn,
carbcn ,Atcrn. (vc1. I cf tRcaction Mcchanisms in
crganic chemistryt A scrics cf Monographs cclltcd by
E.D. I-Iughcs), Elsevic:: IJublishing Ccml:any, Lcnclon/
Ncw Ycr'!.i (rq 63\.
. I{inc, !]rysjgt l
;.icGra'rr-I{i 11
Bc
olc
C
cnPany, Lcnd on ( t 962)
3. L.P.I-Iamnett, Plrvsical Oreanic Chemistnr '
McGraw I{itl company, Lonclcn: (rg4o)' usE 2ncl trdition
if ava i Lab Lc ,
I4
4'. E .i{.I(cs crror, An fntrccl
i cn t d pllrs icq_l Or,rranic
Chefq.i-qtnr., Jchn l,Itley ancl Scns fnc., f.,Tcw Ycrk (fg6g).
r-rct
5. R.A.Y. .fcnos, Plrysi-cal ancl Dlcchanistic Organlc Chcrnistr5r
( Zncl Ed it t cn) , Canrbrictgc Unlv . Press, Cdrbrtclgo,
( rgs4).
6. Jerry l.Iarcir, Advanccd Organlc Chcmistr"5r 2ncl Ecllticn,
III.Acicl itv/3asicrtv
cf Oreanic
1g77.
Coml:o
i cn cf ac icl ity anc'l baslc'lty ancl clctcnnlnaticn
of acidity ccnstants for strcng ancl woak acids (tr) Hammett
(3 rrours)
acid ity f unct i cn.
( o ) Eva Luat
tsoclls
1
Rqc cmmcndccl :
.
n-.-).
I,IcGrar,'-FIt11
2.
fv.
Bock. Ccmparqr, Lcnclcn ( t 962)
L.P,, I{ammett, Ph-rrsJcal Orranic Che'mjst:rr, McGraw Hi tl
Ccmparry, Lcn,'1cr:: ( tg4o) : USE 2nc1 Eclit icn if availabLe.
cr?s
?
Stability of Frcc raclicals, Scurces ancl dctcrminaticn cf
f ree racl ica Is, cl:a in rcact icns - rctardat i cn and aco lorat ion cf , anci incluctlcn pericd Df . Structura] ancl stcrccchcmical aspccts of raclical intcrtnu'diates, Frec-raclical
sul:stltuticr: reacticns (Halcgcnatlon; Oxiclaticn ancl slr]lstltuticns
invclving ary[ raclicals), Rcarra:13oments and
(: hours)
fra6pentat i on, carbcncs , nutrenis .
/r{r*
R.ofcrcr:ccs:
1. Arlv. Chemistry by Marcl: 2ncl Encl . 1977.
2. Rea.l,{ech. in Or,g. 'Chcmistry I:y S}I_},{akl:crji ancl
S.P.Sir4;h
1?TG.
3 . Pri.iicip les cf ilca.l{cdhanism by V.S.panrrar
ancl FI.M.
Chcwla Zncl trcln. 19TB.
(") l'fechanisrns cf e rlminaticn
- effect cf basc,, stcric
eff ect , stcro cchcrn istrlr r pyr c Lyt ic c 1im inat i cn,
c lassif icat icn cf c liminat i cn on thc ]:as
is cf ro rat ivc
pcsiticns cf th'c clirnlnating grcul)s, ccrupcti.ticn bctrycon
c Llminaticn ancl substituticn.
tr) I"Iecira.,risrns cf pclar adcliticn t c carbcn-carbcn
mult cplc bcrrds - ar-]diticn cf rralcgcns, cf strcng acids,
cf carl: cni um i cns ancl cf ructa I cat i ons .
cr\ i'{ccitanisrr cf trstcr hydrclysis: Acyl - Orlrgen, ancl
a Lr.ry I-C-:,,'gctr f is;s i cirs cf estcrif
icat i cn and of
l:;rclr:ll-y,si", rcactivity ancl catalysis.
(t5 hcurs)
Ref!-,!nj:c q:
1.
E.s.G-cLrlc'r
, Irfcdrranism ancr strr:cture in crganic
chcmistry 2ncl ccliticn.
2 . .jack llinc , Plrys ica L Organic Chc,mistry
, Zttrl trd it i cn
1962.
3. c.i{.rngcLcl, strtrdturc ancr Mcchanism in organic
Chomistry 2ncl Ecln. 1969.
4. D.V.Dantlrrcl>e, Eliminaticn Rcacticns, Elscvicr publisl:ing
Cc. . , i,cncl cn, 1963.
YT. :\r cqrat ig i ly .ggl,
t
"lre lr ics cf ar cmat i.c ciraractcr, I-iucicc f r s thc. crlr ancr
its o:>r-!'icat icn-s ancl cxpraining arcmatic stabirity.
'11-1- r.:!::.J':l:i'-; lirc.r ;'>senricarcntat ic cDmr)cuncls. An11urcncs.
,,
f4'
arcmatic su'bstituticn - Thccrry
Tyllical cxamplcs cf
ancl oricntaticn'
Elcctrcphilic
cf reactivity
clectrcphilic
arrynatic substitution
mcchanLsms
t{i--brartion,Fricclcl-Graftsrcacticn,sulplrcnaticn.
I4octranisni
)ir-tcic ci--i'i- l-ic ar:mat ic subst i-tut i cn cine
statcnent an<l cviclcnces' Benzync mcchanism
substitr-rticn.
-
(rO rrou"s)
I(cc"ranLsrn
Nuclc ophilic aromatic substitr-rtion cinc
statcmcnt ancl cviclcnccs ' Bcnzyne mecharrism s ubst it r-rt lcn.
( r O hcurs
)
vII.Sgge!igl-:I-gerE?3-:-}egglg-EglIiP}9-9919:.
NucLccptrilic ancl clcctrcllhiLic adciiticns tc
carbcn.Dx}'8cnc]cublcbcnc]snMcclranisticaP])roaclrcf ruatcr, alcohcLs, anincs, lryclrazinc clcrivativcs
lic.l iticn
St cbbe and bcnz cin
A lrl o 1, PcrL<in, c La iscrr, Dicctirnann'
Rcformatslry' 1{itti8l'
ccncicnsat j-cns. Darzcns, i(ncvcnagcl'
Cann3-;;i:ori'larrn:i;':ilnclP:l'''nsrcacticns'l'[eerwcinSt61i9Pncl crffvLarLcy Rcduction, Oppcn oxiclaticns'
chcmistrycfcarbcnyLaclc]iticnsCramtsrulc.Estcrifi.
cationanclhyclrclysisti-Iyclrclysis,atrcoLolyslsandro'da*
ct i cn cf nitri Lcs - Rlttcr rcact i on ancl ' lhcrpc
c cnjcnsat i on.
c.i
*
G
trours)
Dooke f cr chaptcr fV ancl V.
o
t
1) J. I'Iarch, I Aclvancc<l organic chcmistr]r r
2) Ivlorriscn ancl 3o:rd 'rOrganlc chcmistryrr
orsanl'c chemistr':rrt
3) p. Syiccs rrGuidc bcok to Mectranism ln
4) Plnc, I-IontJrlckscn' Cram ancl-Hammortd'
Organic chcmistrlrt'
uss/2ot?
,a2
t7
\lrrr
Irt:ggggllgl-tg-uglztg:-glsel:!s'
Prlnclplcs
of polymcrTzatlcn - cLasscs of poLymcrs
syntlrctic ancl biopolymcrs - chain rcac'tion polymerizatJ.on
Lincar, crosslinlccd
and stcp rcacticn i]olymcrtzatidn.
l
ancl nctrrcrk 1:olymers. Frcc-raclical,
crclination lrclymcerizaticn.
r ubbc
ionic and co-
Natural ancl synthctic
r: .
(4 hcr-rrs)
Dccks
1)
2)
riclcs cn, Cram ancl Hammcnd rr Organic chcnist=y'!
Saunc'!crs I'Organic PcLymcl Chernistry", Cl:a1:man and
I{onc1
Ha
11.
,
kas/z2tz
....9
t'
(",v at c,.t^:.
i,tl }ry ' *i3eS',J',
Labcrat crlr Tcchniqucs
I.
ctl'l!*"f*t'ry'' ,@'
I
3
ltothccls cf scparat i cn ancl 1;urif icat i cn cf organLc
stoam ancl f91v-prossurc distillaccmpcunds - fracticnal,
tions - fracti-cnai crystal-isaticn anrl srrblimatlon p airc r a'trc1 t b in- laye r chr cm at cgraphy .
rr.
separat i on ancJ iclent if icat i cn cf thc c cmp cncnts of
Drganic binarlr nLxtrucs 3 Analysis cf about a dczert
nlxturcs,Dfsotnccfwhlchcon-tainin8compcundswith
mcrc than cne f unct ional grculr.
rIIr
organic Preparat icn: Prel:araticn cf abcut f iftocn
organic ccmpouncls iLlustrating impcrtant synthctic mcttrccls
ancl rcacticns such as Fricclc I-Crafts rcacticn, Grin6Erarcl ,
Pcrkin, G Rcimcr-Tlcmann, Sanclmcyer, ancl carrrti-zzafo Itcactioni, claiscn, al-cJo1, and benzcin Ccnclcnsatlcns. sclect ivc rccl uct i cn in p o l.-'unitro ar cinat ic c cnp cunds diazc
ccultLing, 1:htlralcin fusiDIl ctcr
3glg=g*:s-:3:'i:i
crganic chcmistry
15,
A.I. Vogcl, a tcxt-bcok of practical
16.
17.
Shrincr, Fuscn anc] Curt in, Systcmat lvr-- fclcnt if icat i on
of crganlc c cmll cuncl s . 1964 .
Expcrlmcnts in organic chomistr"5r by Fi.escr.
18.
I4ann anrl S aunclcrs, Practlcal
19,
t sitaraman, and Govlnclachari, A Laborat crlr
j,(anua 1 cf crgani c chcm ist r'5r , 1957 . ( ttrtra ecl it I cn)
P'It.SinEhr D.C.Gupta, ancl I(.S. Bajpal, Ex1:orLmcntal
or'Sirnic ChcmlstxSr, Volurnos l and 2, 1980'
20,
Organic Chemistry, 1957.
De]y.
k
zs/z.ttz
.r...
4
I
:
lrri
IV F]I-IYSItAL
I. The SoIiC Stete:
FAI-Eh
CH EM
ISTRY-
I
( ZO hours )
( s hourw)
(. ) SemiconCuctols
Their preFieretion e propcrtics enci inc.!ustrial importence.
( b ) Im l,eTjcctiols e
hours
)
Imperf ections in s olicls: Foint r:lcfects, linc Cefects
o
anrl plane defects.
Nonstoichiomctry physiceJ. propcrties:
(i) ElectricaL propcrties Electrical conductinity, HaLI
effect, dielective proircrties, piezoelectricity, ferroe-i.ectlicity encl icnic concluctivity.
(li1 .01;ticaI ;,roperties .- Fhotoconcluctivity, Iumin scence,
colour centres, lasers, refraction, birefringence.
(iii)
Magnetic i'ropertics
Ciamagnetismr [-,oramegnetism,
fcrromagnetismr ontiferromcgnetism and ferrimagnetism.
(iv) "Thermal 1-rn1. erties
s pecific heet.
( c ) Solicl s tc te reactions
thermeL conciuctivity
anC
.
(e
hours
)
-if ferent ty-es of reactions invoLving solj.cls r Thc
mcvement of mcttcr in sliCs.
Diffus j.on anC Frrcccss.
Thermaf deccml,osition of inorganic soliCs.
cf LUCcmpcsition reactions.
Iincti6s
Isothermel ancl non-isothermal
r.luc:'rn;-scticn. Frhotclysis of soliCs enil photographic
proccsses.
Self-heating
anC explessions: DeccmL,ositions
cf aziclcs and pcrchlorctes.
Eeaction betwecn gascs
and
so1i.,=..,
Con$C......
\
.1
\<
I
{.c
To.xtb
ocks rec
omrncnded:
1. Chemistry cf scllcls, A.K.Galr'ray, Ohapman ar, I I{a1L'
2. Intrcrlucticn tc scllc]s, L.',tr.Azarscf , McGraw-HirI.
3. sclicl statc cleemistry, i{.3.I{ennay, Pronticc-I{a1L.
. 4. ScLicl Statc Ci:cmistry, J.Arucl l{cdwe11, ELccnicr'
I
McGraw-Hi11'
G.I'I.Berrcw,
Chcn:istry,
trlrysical
5,
6. Ptrysical Chemistrlrr II.J.l'[ccrc, Prcnticc-HaIL'
7. Dcccml:csition cf Solicl, D'Youngi Pergamon Pross'
(t: hcurs)
[email protected]
( 3 hours)
(o) Thircl Law of Thermgclynamic=
Statomcnt. Determinatlcn cf absclutc cntncpics usLng
the ttrird law. UnattaLnability cf abscllttc zctoo
Resldual entrcPY.
(l)
Det
(: hours)
Par-tiaL rlerivatives '5y-t:rc,nretfrca cf 'lacobl
Tbe c!isclrscicn tc bc confinccl tc closed thcrmcclynamic systcms'
(.) Tho thcnncdYnamics cf scluticns
Thc Sencral
Partial mcLar quantities.
(4 hcLrrs)
mcthccl
f or thc ir
lat i cns f r om Ra cu lt I s law ' Excc ss
thcrmcclynarnic f'unctions. Excess frcc cncr8)rt cxccss cntrcPY,
exccas cnthalpy and exccss volumc'
clotermiriat i cn.
Dev
G hcurs)
(.t)
Entropy prcduc*icn'
Slml:1o cxampLcs cf irrcvcrssibLe
prcccsscs.
Tlec plioncrncnclcgica I rclaticns.
Ousa8or rcci;:rocal
relatione'
Airplicati.on cf tho thcorlr to ctlffuslcn, ttu:rma1 diffusion'
i.rcr::rc-csmcsis ani-l tlecrmo-mclccular prcssure differencc'
-8.--
t
tt
Textb ccke. rcc
ommondod :
. Plrys lca I chernislry, Danio Is and A Lborty, Jchn wi 1cy.
2. Tho Mattrcmatics cf Ptryslcs and Chcrnistry, H.Margcman ancl
o
G,M.Murplry, Vol. I, Chap. I.
3. An Intrcriuetlcn tc Chcrnical Thcrmoclynamlcs, I[.P.Rastogt
1
and R.R.Misra, Vilcas.
t+. An Intrcducticn tc thc ThcrmcdynamLcs cf frrevGrsslblo
prcccsacs, I, Plgcgino, Intcrscicnce.
5. Stat istical Mcchantcs, Thcrrnoclynamiis and l(inctics, O.4.
Itlcc, rif .II .Frocman and Cc.
5. Chemlcal Thezmcclynamlcs, Ycrarnln, Mir PublishcrSi Moeec,$ri
(ZO tr'curs)
IV.Electrcchgmlstnr
Dcbyo-Hucko
l tlra or'5r cf strong c lactr clytcs"
.
The icnic atmcsphcrc, tlrnc of rclaxaticn cf tloe lonic atmcspherc, asyrrmetry cffoct, eLcctrophcretlc cff'oct, thc Debyc-
t- cnsager oquat i cn ( clcrivat l cn nct :rcqu lred ) , va lad ity
cf thc Jei-,,yc-I{r-iei',c1 cnsaS'cr equatlcn f Dr aquctll6 arrd ncnaqucous
scLuticns, dcvLatlons frcrn the Onsager oqt'atlOn, SlgnlflcalrB'G
of thc clcgrco cf .cllsscciation ancl lts cle6cr'rnLnatlofrr
Huckc
ccncluctanco ratlo and cnsager equation, cltspc'rsicn gf
ccnrl
uctance at h16h frcquoncies-Dcbyc-Faliconha8on cffcct,
canJuctance wlth hlgh pctential gradlcnts ,
AyPlicaticns
cf ccncluctance mcaouremcnts. Tl:,o Dobyc -nuokol Ltmiting lerrv
ancl Its varicus f crms (no dorivatiqn), Qualltativo and
quantltat ivc tcsts bf ttrc Dcbuc-Hiucket liinitirrg oquationt
acti'vlty ancl activity coefficicnts ln clcctrolylic sclutions.
r\;r'', 1ig31 icn cf E.IvI .Fr rlczlsurcmcnts: Sttr;ly of conrplex lcns,
instnl.:' f i.t:- e cnstont , rl i.ss ociat l on c onstant of ruoak acicls '
ac
\
ld
-basc and rcd cx -t l-trat
t one .
n
1
,4
0rler voltage I Thccrlesof overvoltage
i
llolcogaPlVt ?rinotP1e: md aPPlioations
Fere1
oclls:
I{ewer eleotrco herdcd method's
cf enerry lnoduotion'
Looto_i-
1. D.LL i,'cTnrcsr'jlhe
fr:-'aci-;:1cs
of ElectrootremistaTr
Dover Publications'
2. S. GLasstonel Tntroct'rrotion to
Electroohemlshilre
S. Van NostfAncl.
J. 3oo}rls
ard. Recldyt trb'tJcrn
Eloctroolcnristry Vo1'
l\calenlo Prosso
arraaaaa
ancl
flt
ri
(15 rp,s")
Optical behaviors of collold.a1 solutions. Deterniration
of bleoular rvciglrt by light scatterigrg, osnotic lressurel ultracentrlfuge srgl soily. Enmilsions. Cels. Igtclnstrial col1oicls.
Electro
ldnitio
Electrokinetlc' trntenti.al.
TI:o eLectrioal dcuble lqrer. Zeta gotentiaL, Deviation of tlre
equation
ptenorocn&o
for zeta lotential
Langr.uuarte d.sogption
isotlcTll - Kinotio
arrcl
clerivation" ?ln6icai absorpi i.pn and. chonrLsortrrilon:
statlstical
El:e
I.n.T.
oquation. Deternination of srrface eea of ecl,sor:bents. I&at of
ad.sorption ald
its d.etermiaaticn. itat of
ad,sorpti.on ancl, Lts
determination.
Xdsorptlon Jkom solution srEfaoes: [he Gibbs equation.
Exlulnental j.:rvestigation of uonoloyers. flp equation of state
of
monolryers.
llri.sorptiolr intLLoato:s.
Qlnornato
#adry,l.
thtl
la3rer and h"igh Jressua's J-iqutd [email protected]
Tert
llco
Colunne gase
l's Iteconnerld.e.d..
1. [he Plysios ard. chemLstry"of
.sr:rfaces, MK. dan,
Dover Publioations.
2.
Plnpslod. olramlsl4y
of surfaoos, A.[,/.
Arl.ansone
T[ile5r
Interscienco.
1, Co1lllld soianoel &8.
-&lercard.er qld.
Orfed. ILrlverslty kess
4.
\
\
fatrod.uotion to ColLci.cL
tr/iley - Interscienoe.
P. Jsluscnl
o
scj_encee
K.J. trffio1Js,
-
d/r
Erlctrc^lS
fr
$hernPchemistrY'
lbat of solution from
IIo
1b}eo ular
III. Lhleculq
welght
so
hDllitY
asrretrrlt'
- cleternilation u'siJl8
lveigirt C'eterurination
clegrcssion
rne
of salt
soIid. solvent'
fron [Eans:tjlition
!o
jxt
tS4lrateso
reaation jn vvater'
+
H
IG
of
strrly
\
W. cqroscoprc
V. Equilii:rlun stuly of IG + L = \
VI.
by partition
nretl:od'
and bi.:rdy rrixtr-res'
liquicls
prre
of
i:ritices
RefYactive
vII. I,rlscosity of binqr liquid
r,rfI1. Elccttac1rn:istry'
nrixttges'
arrl weak eleotrolSrtes
Conductanoc of' stony
scluble sa'lt' Dissospci:lsly
of
Soh'rbility
in sclution'
ciaticn constants of acids'
Conc'uotor'ctio
titration
(apicl vs
.ba,Sear(llreoipitdionreaotions).Sjx31ee]-ectroclelotentials
cf
oopper, zine ard
silver'
ftedox
concentration oeI1s ard'
lotentials.Potentioroetriotitreationcls.solwilityd'eterur-i.
weak acjds'
Dissociatjsn constants of
naticns'
aaaaaaaa
.sylla.b-us-Iglfi-n='l' Yci l
Paper
I
V -
J'l-:gq. Cl'o:' '!s*i!.*- -,,.r--:----.1'-L-Bg
IN0FG4N
iL
LJI5I',I-5-Ij!)---iJ
(t
The_ryl.eta1J-ic starte
Theories of metallic
bond
of metals.
Intermetailic
aIloys.
In'ters -L -. ..i
corn!-rrrunds
anci s il icir'es
.
Free elec-Lron -!heory
ThermaL a,nc elcctricel
band and zone theories.
ductivity
j-nc:
S Hours )
Interstitra-'l
e:nd
s ubs
r
con-
titutional
colTlf:aunds. llume - Rothery rules '
s Eorides, Carbides, nitrj-ces
ReferenLes:
1. Introducticn to sr--.J.ids L.V.A:'aroif
2. An introduction tc' sof ici stcte - G.i.Ipfinov
3. El-ectronic structure cf meta.ls N.B.Brandt
5 .['1.
Chindinov
4. Modern Aspects of Inorganic
5
5
II
ira
chemS.strrv', Emeleus and
rpe
. Structurai Inorganic
chem j-s
try,
A.F .\'/e1l-s .
." -i.ji:-Ig-e1,i Sot eciilt*g.I-c-'oqses.-: (7 Hours )
.:'Lin of Lewis ecios ond L-'ases. StabilizaCIass i f :
tion of uitl::t-la1 oxicii ticin stli;es ' Corlpounds cf meta'ls
Con-cept-
in tireir ?.e::o oxid;'tion
1
.
2.
s'r,E
te.
Thi:cret.-i t a.I Inr:rroi-:ltic che,-,ril; trr'
Se
III
and
Iirin
Ai',,incec Inoruinic
G.t,lil-kinson.
chemistl.v
l'l .C.Xa.'r,' anC
'F.A.fotton
and
(15 Hours)
0rqaJt-olnela+ic conrLo-t-rnds'1
The eighteen efectron rule
AIkyls
anc.i ary.Ls
of Be, Mg, Af , 5n
a-ncl
Pl-'
..
vmjl9.7.BT
. . . . .2
('
,2v
Me'La
Me
-1
Ea
rbonyls
i;aI-metal-
bond
Importance of
m
Me'La1 complexes
b uta dien c e
Cyclo;.
etaf etoni clus ters
of ethylene, ecetylene,
aJ--1-y1 and
.:dicnyJ- comPlexes cf iron group metals
e complexes of chromium gro up mr; ia -Is
Fluxionc-1 orgE nonie la1-1ic coml-ounCs
Aren
.3gfjr.g.l.=t,
1,
Advtnced Inorganic chcmis-L-.y F.A.Cc-Lton
and
G.ldi -tl<onson
2.
lnorganic chcmistrt,
3.
MoCern Aspects of lnoroenic chcrnistril
J.E.i-iuhecy
A.J.
and A.G.5hi,rpe
0rgancmetall j.c c hemis iry--E. G.Rochou
Eme-l-eus
4,
5.
IV
0rganometal-lic comi,ounds. G.E.Coats, lvl.L.H.Green
cnd Waci e.
: ( 10 Hours )
lligi!.Js ,-i:iiic-tg--e-f-
Elect;u - j r;r.'i'-nsistions xespcnsible fcr Colour
d-cl tr'; ,rsi-bion,
S.l
cct-i"on
rLI
-1.es.
, d4 ancl .19 complexes.
Cha::r'c t:ansfer t'''ans::- ticns :
0:r:EeJ. ci ie gram f or'
d1
/{naIV'tical r-pplicetion
of ch€;i.-,c'i,r-ans-ic:. spectra in -the vj.s-:1,1c r:;qion'
Ref e r.int cs:
m;'taf ci-remistrrr
L.t.[irSc].
1.
Transitition
2.
Physicrl- methods in inorclanic cl'remistrrr
3.
Modern ccordineticn
R.G.ll/ilkinson.
chem-istry, J.Lewis
R.5.Drego
and
...
c......3
.^7
tic
Maqn e
V
prgt;lrlt]es o-L'-!:+s':!t-o-l- gp-Le-l-flUal%{j
:
Paralne]rtnetism ternpera'anri orhit:-i corrtri'l''utionsr
ture depcndancc' spin
and its
Thc spin onl5r irom''jnt
pling
co
'
spin-orhit
tranchemrs try of the
coorclination
in
appIicaticn
properties of Lanthanide
Magnetic
metafs
'
sition
of magnetic susceptability
Determinition
complexes '
interec tion in
erromagnctic
Antif
Gcu5'r s rirt:thod '
trrrns rtion rnetal collr Plexeg '
Types of maqnc+-ic [:ehavior'
Refqr-ens-.'s:
Vo]'1y(Eds)
e niLc chemist:-;v
lnor:nf
f c''
't
1.
A'UJ"issberger'
H'B "'tnnt= =-un a':nd
i'Lei"lis i-nd
chr:rristrSr
2. Moi:'ern cocrojnr'tion
R. G '\liIl<ins
A Earnshaw'
3. i[agne'';oLiri:nris tr]l
(12 Hours)
--s.gi:(jeg
MechlirlFrn
- 5l' ' 5( anc
complexes
complexes
+-r-p'tr;-'l
octahcdri'l
5ul.;s'titr-.rt-ion of
VI
SlCBmechanj'sms'Acidandb;sehydrol'r'rsr'rs'Anction
comPlexcs
sQUi: rE planni'lr
in
ec'L
f
ef
re.ctions ' Tr?ns
Elcctrcn trans{er and
significanc-e'
its origin and
Frirrci;''le cf photcctinns
'
rei
electron exchanrjc
'
of coordine tion ccnr Irounds
!:lae-ctions
chernicai
Re!:''tli
ViI
'.' lnori-.'r:iil-(
I
Lotton ancl hlilkinson
o-';r'rr
e+J
Rerc'tiorr jn SoJution
'-'i
L:l'jrrrJJ
1.
,Ii''l vr ilt
2.
Mccl-'enj.siir
D .ll ens c;-i
3.
r'ci:c'ticris
*ti::t"1
MeLl-;anr sir o'i'
i:Gc-i-r '
Pot'
] Bt'saio anci
of Innrr-lanic
of
surlrs
ccrriP-l-e:<es
CIessj,lj-caiirrr-r
cf sn-l-i'-rr ts'
cJU
^'1
r
r'.-
-..-=i'
e-ia 1
(10 Hours)
'l
-z*'
';l-nT3
-'
Reacjj.rns*.ill-Jlg
m
.1
vent intcrerctioFt
.''''
vmil9.7.BT
" '4 '
\\
't
,{)5
sclf
i.nnizr tion of solvents.
Reactions in -Lhc following snlvents: Liquicl ammonia, Liquj.d hydror;cn
f l-uoride,
liquid sulphur dioxide anci sul; hu:ic acid.
nef
eqeqg__e5:
1. chemistry of no6-enqueous sor.vents H.H.sisfer.
2. Non-aqueous solvcnts T.C.bJa ddinqton
3. Tr '-,ctica.l Inornanic Chcnristry tvi.C.Day
and
",1.
VIII
-l_USSif_fc _ferti.]-: _PJ.ant nutrients. Function enC use
of
(6
F
Hcrurs
)
ertiLi zets .
Important N, F, K fertilizers.
RcferencLs:
1.
_Eherristry anci Tochnoleg.r, of. Fcrti-lizers.
5.la ck
IX
?.
Soil- chcmis try
3.
Corr,mercial ferti-lizers
A.V.
F. E.Ber:r
G.A,CoI1ings.
Ingrqanic__L+g.g.s15!9
(s Hcurs)
Titaniu,.r dioxide, Reci 1er d , Ultramarine .nd
alt,mini_
unl pigments. Lurninescent pignrcnts hrsed
on zinc
s
u1pl,
-89.f u,r=l:-r-*....i
1.
2,
Kirk--0thmol.l-r,c3cIcpedia r,f choi:.,ical
Technofogy
(SccoircJ eaiticir) ;;i;;"
i5.
Pilmr-n-ts Pa,rt I R.R.[iv::t,s;:ricl _r .5.1_ot-rg (Ea)
0-----
0
.......
vmjl9.1
5
.i7
---
\..
\
*.#
INORGANIC PRAITIIALS
II
'r of simple binar:y mixtures of me ta 1lic
ions in so-l-ution (involving quantitative s epa ra tion )
by vo.l.urneiri-c, oravimetric, cclorimetri-c and elcctroEs
t i-r'
anal-vtical methods.
2
Anal-vsis r,f same l,rpj.crJ ores
(Carbonitc 0rc, sulphide orie, i-l-menite, monazite,
feldspar and Kao.l-ine), a11oys ancj complexcs.
3.
Ion-exchanqe
s
epare
t-ion of binary mix'Lures such
as
those of zinc and magnesium and of coba.It and nickel.
References:
1.
tA Tt:xt bou:k
A. i.V.:qe1.
2"
I
J.
4.
Qurntita tirre
of Quantitativc
Irti-Lrginic Analysist;
Chem--lca-, iirr; J-'u's:i-s
r, i "i{.Kolthoff
E.il.SandLlrso;'i
rTechnica--l Methods af 0rc Analysist,
and l'J.[j.Schcr:ier.
,
/r.J"Wcining
y'sis of thc Fi irrrr:i-s anri !j--'e,. r,f fhc Rarer
El-ements t b/. R.5cl- oe: l-f er encl A. :l. Pi,t,;-11.
tAna-1
aaaaa
ua
T
PAPER
t h. I
Ph v_s_rca
I
rn
c.rlho
VI
0RGANIC Ct'ii:.1'IISTHY
ds [email protected]+_s-Lety
Applici-rtions of U.V., 1.R., ['J.[',i.R.,
(
3
E.S.R..l'.1
20 Hours
)
irss, C.D.,
0.R.D. sj:ebtro$cb;:y anci' dipo!-c nroments in'st;uctura.I
j
elubidations of or,-rani"c':cotnpouncls. U"c of the plain
:
-, I
and
c,otion.,,
.i .': , i'...'rl
,:;ct cu-rve.s for detc:rmining" c.pnfigurations
:a.\-t.
ancl cnn-for, . .---ns.
-lLr,
1
.
iii
0r,,it; i;: ;
a)
cl'
.i
0ctant ru.l-e and exia-1. haloketone ruIe.
cs bL'
Deternini.t-iL
Phvsic*l
- n {iof.
': clr$.nic
'.
. ;, s,tructu.r
,
--.1
, ::-i_,
".
._,.,
!'
Iiil,"*',".
,iu
i'. ='=,tr";ii,:,1;,."!lumPs. r:cr'!",0,
P/ Bri.cjs
and
2.
a
rJr
Spectroscbl-i'c iclcntificr tien'bf
4.
by R.:14.5il-vers tein , G. E.B: =[.].", , an d f ,. C. Pjor'::il-1.
0rqanic spectorc, f,ro"rlenrs by J.R.Dycr.
0.R.D. and C.D. by Crabbe
5.
orEani-t ."rpo'u,,ds
5.
Henci rrcksr-,
7.
n ct 41.
Fine l Vof . ji
B
"
....;
i
Proi-:lems j-n r dvr-nr il ..i r:;r1r'nic clisnii.s'cry-' ;,.. jerry
g
.
PrbbJems i.n acivi.ni cd o::ilinic
chcn,is;tr-v :', : Josepl-r
Ciatattone.
Orqqgic photechemis tr.rr:
r
jc,n
Fundanr ente, 1 conc epts mol,ccur l,; r .:xcite t
,, Jablons J:i
diagram, the triplc-L sta-te, phctoscnsr-'.:. i: t:ion, plroto-.
,
.
reactions of orSanic molccules r rccct-i.r :; j-i-vt.i-Iv:i-nq the
. , . . . . . . ..7
I
,,.rl,--
7t
.rr
olefinic
double bonds r
rGe
oxidi tion and 9teduc tion,
photcl-vsis cf nitric
appJ.ica
tion of
photochci,' ,ry
industria.l
chemis
Tex
photo*Fries rearrangement,
esters and r:eletcrl
h/oodtvc
r
ctions af ca-rbcn;u1 comf-rounds,
cori.f-ou,nds,
rd-Hofrrann ruiles to pl-rotaree:ctj-ans
f sornr: if e rDccS::sBS: Fhotosynthesis,
.1
F)
and tcchnclogical
a:pp-tiii tions of photo-
try.
t bc c lS_
(
Le_qo.
,
ryfqrlsla_q
B Hours
)
:
1.
Kan, R.O. 0-rr:a.r'ic ['irrrtochcmisLry,
Bcnk Co ' (i965i
2.
Chaprian. 0.L.Eigarric Fhotochem:r-str:y, Vo-'iumes I and II
MarceJ Deckcr irrc. (1967 and 19'lD)
3.
LamoIa, A.A. and Tul:ro,
fl
stry series Vo1. (xiv),
interscience
I'icG-raw
HiJl
.J., Ener.gy, transf cr and
0rganic photochernistr5r, (Techniqui: of orga-:nic chemiPublishers
(1 e6e)
4.
3.L. 6I''ld !eFuV, Mol-ecular recctions and
Chap:
pl-rotocir.
i,rjstry
ticns cf mociern organic
Prentice i-lal-l- (lgtZ)
(Founci;.
chemistr.; series)r
5.
Cc,lvcrt ;:ni Pj-t';s, ii-rotccl-,crnis'ury. John
In tc:r-'s t j i.iic e (1966
6.
Ccx an{i l(u1:,
I
II
i
t^Ji1ey
)
1n-t:r.ocl
uticrl'phct:'ci--,:;l--,ristrl', Johnldi.ley
ntc::s cicrrc e ( 1 9166 )
-U_r:g.,.,fj " _&L!r!i.]..J.t-._gfy
t
WooclweiC Hoffmann lufcs of Cr--ital 5y,i-rr:,ctry (b) Electrocyclic
reectj-ons, cvcJo addition anci e.liminr tion,
sigmatrop:c rE. ct j-c, ns end cotre enci claison reerrangements
........8
.
'/ 7'--B-zf.rc.lt.q-gs:
in
Entwistle, N., t0rbital- svl',rmetry coI'Iel-etion
'f mann
Hof
_
\rioodw;
rd
to
guicic
org. chemis t15 /.
rufes I .
2. Pine, Hendrick6on, frcrn ano H;-tnmond, t0rCanic
Chemis try I
3. J.Me'i'., I"dve'nted 0rganic chr:mistry 2nui Ed"1911
(8 Hours)
Mo-lqcglr.r-i:gq-rftqry-glcn'qq
1.
IV
Rcar:-anr-l
ements involving
ele c-tr:r-,n cief ic;ii:nt ci tbon,
!nor. l'i ,rorvlein, pinacolpinaccJorrc, rjicnc[]E]-phuno-I , \lic-if'f , Hn-Fmi'i-in, Lurtius'
Vifliger
Fossen, Bec[<mcr]n, Schmicl t r:ncj 'iaeyer
rearrcn gemcnts , e,nionic ree: rra g'Llr;i nnts : benzil-':enzi.Iic
nitrogen and oxygcn .'ccms:
tr/a
*z
acid ancl Favorski r.eaI-rc qoments , arcmr. Licl:r: anqements:
0rton, Claisen anci Fries rcerrcoenronts '
Tcxtbooks [(ecomr,cnded.
1.
Sykes, Ir Guide book to Mechc.nj.sms in orqattic chemis'Lry,
0ricnt
2.
Loncrman ( gf ct
ed. 196, )
_,ciianism and Structu.r-'r: in 0rganic chcmistry,
Cor..
Halt-ilrvden (1959)
3
.
P
j ne, Hirn,:lricl,son, C::i:m trnci ll ai' ilnnc, 0rganic
Cl'remistty fic.-Graw Hill
4.
De fi;irr..r ,
ir["'i
o-]-ccu-'l
(3rd Erl. 19S0)
;-I- [,ea,r a11clTr unti;ii " In-Lerscience
(1')54)
5.
V
, rrAcivant':cl 0rgtnir
Plc Graw Hill ( 1978 )
J.t'1 a:r'cl^,
Llren'istryt'
,
-elers.
)
of s-vnthesis and re'rctions of imidazol'e'
Pyti*j-ciine (uract-1 , ttr.5m:'nc" \/!uoslne)'
M,-,:tirods
thiezols,
L1
, r...
a a9
?T 3>
pyrazine, pUrine, pte;idine
isoa lloxas
-in
(xantii;:te:-'in) ci 7-oztrzine cnd
e.
Structure and synthesis of acenine, gucin'ine, uric
acid and caffeine.
1.
ch.
1 :.
hetere
2,
o
torns
Gii.mari (Ecl.
EtnS
.
,.lrliley
) iicivancGo (0::glenic Ch',nist::y,
953), Ch.ii Hetcrccyclic
Acheson e AD In'broour:tion to the
Vol.IV
3.
(1969,4th ed.) Vo1.II,
-rtsrocyclic comPounds conta ining two or more
Finar, 0rgenic Cherristr'Y'
(1
chemi-s-Lry.
Chirrnis
try cf Hetero'-
cJ'cfic cLrn);iounds, IntL:xscicncr: ( 1 950)
4. Badgcr, Thr Ehcmistry of Hetcroc5;cJ-j-c conPounds
Acaciemrc Press (t951)
pounds, Else5. Ro-tlcl ( Ecl.) Chemistrr, of t
1 95D) Heterocyclic
vier Vol. IV A, Band L
com prg un dg .
6. EIdcr
:
(
Ed.
) Heterocyclic compounds,
\'vi1=y
(1951i
1.
vJcissbe;.-g.rr
ccnrl'
VI
(
td. ) The cher,'istrSr cf i-lcterocycJ-ic
ounils, Irr Lerscit nt
(195C)
Il!:r-cL.:ttc-i-icj.t- -lr.:--9i:f-f,-9.-u-ifl..-qf..--1e.il;'S-]-.ij-.=i'*i:[c-]l
z (20 llours
)
ssif icrtici-r ,'urificitione
end structurai- elucir:e ticrr of pIt,ni p::crju':r:s r'litl'l special
ref erence to camphcr, e;ir]tic acid, tJlrininc ' atrepine
Genr;ra-.. lii1;icl',r,Lr5
of
;-sc-'r-.
tjt ir
cLrr
0estr'one f lavenuand isof .lavonJ, ciass if ication of tcrpenes ancl al-kaLoids, isolilren',.j IL! 1Er.
cholesterol,
...o...10
I
I
l,v
I
4.
Thc;E1kf 19ids Dy K1H.,B"i!i"Y
Part I
:11 ,'.,'
0.P.Sharma
itt
7.
8.
VI
(
I
:
tg
Hours
)
Hethr-i. for the.synthesis end degrcdation of peptides
polypeptici;s and proteins. . qarboxyl ond Amino protecting
g'rouF€. Plethpds 9f, cerbo;<yl, activetion in peptide
synt,hesj_s. SLepwi.si: clessicel synthesis pol.ymer-suPported cc.I,id phasc rcactj-ons and pepticJe synthesis Merrifield method. S"quen"e cletermin;ti-on tl,o,"ptides end
proteins. Edmann declra,dation. Prlrriry, scrconoa,ry and
terticry structure of pro'teins. structurc and synthesis
of glutathionc, gramicid:n and
-'i'nsu'l-in'
Structurr;flFlcisynthesisofnucl-t':osidcs'ntJc'leotides
r' ;itJ L"'lii '
and nucf eic ac icis. Structure of
strr . _ o{' p:olysaccharidr:s ce j-lulcs L3 and starch.
Fi11
(le
riirn e
1.
Finar,
0
r'ga
Vol.II ch.
r,
Hours
)
n
ic , chemis try ' EitS
t,l
1b . Puri-nes i,ncl
'
( 'i,r
.
I
4th
Ed.
),
:.
...11.
vn
j/9.1 .87
\,
2.
(1938,
u"g.ni. chcnris-ur.y,
Gir_mr (ea1 Ad anced
"Jilsy
Cht:mistry of i'yrimidines'
1st er''',) Vol'1I' Ct'r'tt' The
3.
Fuiines and N ucl-eic Acicis '
Elsevier'
RcCc (Ed) Ch"mistrSi of cari:on coinpourrcls '
Ring'
Voi-.IV C(1960) Ch'XX'Qurines ;ncj Re-litcc
systellS"ch.XXI.i\luic-.'}.er:si.c]os,t'luc]-eutidesand
Nucl-ci'c Acicis '
4.Jordan,TheCiicmistrS,ofthalJucleiclicids,Butterworihs (1950)
5.
VI I
I
tt0rganic
Pine, Henc'lrj'ckson ' Glan and Hcrrinonci
Chemistr5rrt, (1980)
r]-]lc-gii'Pg!9:
(
3 Hours
-L-hLr-gt,i,9-9-t-E-y-gi-ta'g:'tio,ff--S.f--.Q-g
Zone re-iirring and
Ehromat:' -hy mr:Iecul-ar sie ves '
'
courrter cu:.:-ent nxtri ction'
Ref tjrer'-c .; -bgglis
:
rrFhiisicelrnuthsLisinorginicchernistryby'{i'VJeissberg"rVo1'1 (196ii)
PR,,LTi'-r'L v 0RL"r"iL cHLt'iI5TFY II
P' f-. g i: gr:".1:l-:s3-f i le. i'
inc.rr.iding ;:hotocheniAdvanced multi-St;r,e p].epax.tions
I
Lx'tl'ic'ticn cf c few
caI cnci t'Icctroclrilrica' 'I mctheds'
netu,.alprociucts'(TraininginlrenC-'Lingsemimic::o
quant:'-tites is exPEctcci)
rI-Aren!Ejlu,-o:rq-i+-c-Jgjs-'ut
ilt r'rf 'n ac:d b5 the
Estirna,. - r:.i. eqr-j-vifr:nt t',tci,,,
l(jelclahl- mr:thocl' estiby
nitroEet
mc-thcci
Ji:-'r
silvt';'
'
inatic'nc'Fi'.r'cir;>r5'J-(Z':rt":wi+"tionofi)'ccrbonvland
ii-: -i-' ";' 4u' r 'r cf icrciine
methcrl ':- i Zc j-s ci) e r-' ur-'s ' Ilct'
-- i-'s'
Estimation
numLrelr lr ' r:)Ll*cirj"i l':t-'i"r Vcl''i':
,.....12
vmi
I
c1
'-1
'81
)
,d, 1,0
of
rer-l
ucing
rirnetric
s
urgr rs r amines , phenols ancl
cs;
te:'.s
e-.ttmation of ascorbic acid, nicotinic
'
Coloa.ciri
and choles'icroJ-.
Refeqsnce Books:
33.
Ii.I.Voge.J, li text-[:ook of prrctica:-]- 0rganic chemistr-y.
Fieser, Expcriments irr orccnic chcnistrir'
34.
Mann en'- Saunc! ers, Fractiral-
35.
Dey, Sitcrericn, ancl Govj-ncicchr.r':, r:i L;ri-li tn::r7 manual
32.
35
.
cf 0rg;:nic c.hemistrY.
Fi.Ikan, Nc tura I Proclucts
orglnic
chi:r'ristry'
a laDox'- tory
r-ruicie
Serni-micrc c'rgcnic analysis '
37,
Cheronis ancl Entrikin,
38.
A.I.Vogci,
39.
D.5.Gupta, f-Dcl K.S.Bajprai, LxI:erimental
ir;-t-r.y, Volunics 1 anc"i 2, 19[C'
oroanic ,
H.Sriniversirn, ia.phc':tochcmica-'l strnt'iresis vofumes 1 anci 2
4C.
Qual-it;tivc
0rganic Analysis'
P.R.5rngh.
...13
e)
PiiPER
VIi
PHYSILI,L LHEi"TISTFY
II
(15 Hours)
I!Tl,Y:i
ea'r Rerctions, Propr;-'ities of
nuc-Ieons r nuclear structure, nuclcr. i s-Le [-;i1ity anci
nuclee r mcci c1s. scurcLls of nuc.leaI 'DoI:lbaI.ding
Nucl-ear ch.mistry:
particlos.
Nucf
Nuclea-r sniirg!
bcsic PI.inciples urf, clrairn
reaction r rtji'ctors and acci-leYators '
R.iisttq*r,q:,1-!gtln,SA?o-,
activation
Ra
tL
Radro;:ct.,-r'e ci ti-t-i5 I nr;ut^on
atralYsis.
The in'beraction of rad.ii tinn with
diation chemis try:
Processes resi--'onsibl-e for entrgy loss, ranqe
ancj ranLrE ener-gy rclz,ticns' mr-.:thods o'i dcfection e: nd
Eie ments of nhSrsical and
measurerar:nt of racli;ticn.
matter
chernic:_. - .liition
effcci;s in solicsr
ricj i.r,tion
chcmistry i:'fl lvcter anci aqueDus forrns sulphitc sn'Iution,
carbon tetr.achl-oricj e r.Dd benzene. D,-,sirr utryr Hot atom
chenristr3r the cir;:micr.: I effects of nuci-ei,r transfolma-thc .5zilarc chalrrcrs e+''iect"
tion
Books:
1.
5.G-lasstone, Snurcc Boo[< cn i,tomic
2.
J.rJ.Fi6,j6p, Atcmic pi:;sics
Vande tutetf , Radicac-bive Isotcpcs '
Nucfeer c'lrcmisl;ry enQ ih l''-ipficctioirs,
3.
4.
6.
t\.|
.i,. r' .:iiinks ancl
H.J.V,l
Ptrlli i,, :'l n cherni-g'i".::','.
j lr.
,'. i
i\'l.Haissinsky.
G.Ftiuc.llancler anci J.bJ.Kenncci.l', i'lucler r anci Radio
Chr ' - Jr;r'!.
5.
vm
E11:"g-ry.
?
nous, Art lnt::oar:ction to
...14
\
,y{
II
(10 Hcrurs)
Pho-Lq--gbcmi-s-tJv
Fl.r -
transitions
diative
racli-ativc and non-re-
ulrchemicr_1 reections
Quantunr yield
Photosensitization
Ffash photJ.ysis cher,:il,uminescence anC thermofumine'scence Hydorrren bromine reLCtion anci Hycirogen
chl-orine reacticn.
Inf.j.uence of temper:eture
cn
Photaclrrr:'nical- equilibrj
phetochen',ical rer ctions.
um
Photoreaction in sofids such as silv,-r helides.
eg
Princ ip-1-cs of thc util-rzation af sola-r snelgy
5oIar ce-'1.i. (Glementary ideas only)
Refercnces:
1
.
F
.Daniel-s and R./..fi1bert5r, frPhysica-1 chemis
trSrtr
ldil-e'.,.
ill
2.5..-',i'onerrPhysical-chemistryrrVanNostrano'
Chen+qg-f-J,g.L.--: The rate iaw
Detclninaticn
Truc
first
orci
cr
of ratcs rnd
c,ncl
Arrhenius
trrs of rcactions
false ordcr of Iccction
o::clr-,r r .jvtjrsib.l-o.
re. c tions
o1'ci
(20 Hours)
clnsccutive
Ki:-,etics of
a:nci Freral-1c;1
.
theory, col-lision
theory cnd trirnsition
str'tcthrjory.Significanceoftni:variousactivation
param;ters " Theore.tic: I calcu-Ii tion of the activatiorl ener.gy. il compe:itive study of -Lhe col-lision
and t:ansition str-te thcories.
-. xea cl;ions invoJ vin g reactrve aioms
Kineti
a,nd
free raclr; -'1,s. Use cf Rice Hetzf el-.*r rnechani-snt nd
stuecly s i' -be epproxirnr '';j.on in . -'i i -:" -' i'L re'tc laws
'"-tll-ar Leactiorrs
6f auiit 1 )a ; j.rins. Tll:.:;:i it;s - i
a:l
--i
.....15
?e+li
37
Kinetics of chair rei cticns '
plos icn limits
BrancF,in
g
of' chai-n
an
ci ex-
.
Theories of general anrl sFccific
ar:j.c.l
and base catalysis
SimpteenzymaticcateiysisandheterooeneoUscatalysis
role of so-Lvent Kinciics of reactions in soluticn
.Uhe solvr.;nt
such aS
effcct of SPeCific Properties of
dielectrit'-:rstlntanrlcjil,o}emomEn.bonraltescflca*
ctj.ons bu'u'g uilit irns, dipoles anc'l neutral molcculcs '
Saltof.it-ctlri.rnalrle.nrjLicCond,I-\,kincticsa:ltr.lffucts.
Stud-v o{' thc k-i.nc-bics o-i simp'1e fi:s-t rLrrctions using
time.
relaxcticn
Ref ere ncLls:
1.
Mc Graw
2.
tChemical Kin"''sicsr Vol'I
K.J.l;idIer
and II'
Hill.
A.A.Frost and R.J.Pearson Kinetics and ['iechanisml
John WileY.
3.
F.Daniels ancl R-i',./i1'oertyr tPhysical
clrenri
stryr
WiIey.
Ptir,ITILi,L.5
Pr:,
lerimetrv
Dc'rcr'mint tj.on o-'
mixiUf'ti,-, lf
of
s
j:tic]'iic
c*ucosc ancl strcrt': lj'l'
1-':
tetion, anelYs;is of
(.inu-L:lrs c,'i inversion
s uc.lr-'cs iir .
Ehemicef Kinctics
II
tion of nr dcr 2 A rrhelt ius parcm etcrs of
c-ifect cf j-onic s-:'rsnoth on
o:.'r-i cr recction,
Detcrrn i nr
a first
rates cf
b:Lmc; Le
cul; r: reelc'Liln '
" "''15
-l
,
liI
A
ds o rELiq! :
A
IV
Lto
ds o -. l.
tion
is o th
exms
(Freuncll-ich anri Langmuir)
-[-hu=u_e-qS-l_EbS._e
Binary organic
mi><tL!
res
simplc cutuc tic a con-
finuous ser-ics of sofici soJution
Ternery
mis
V
cible
1i-qLri"c-i
system r"rith cn? ;,air' crf liquids
vmj lg.1
.gl
tion
Partia
.
Spectrophotometry
Law
and ccrit[- cunci fcrma
Vcrif ic; tion crf Ei;cr
Estimi tic-'n i:f simple substrnc es '
Lan,bertr
s
.
11Y
(!o
,
hor:rs)
hasentatton of analyticd data - dcfer:inatc errors
1.
anil ind,etcminate errors
- Eecision
deviation - Absolute error
Starde.:nil.
Itccision
and acct:acy corlparison
artd.
dcviation -
ancl acsu.rasy
-
- Signtficant
figurcs - Stetistical trcatncnt of axperincntal data Mcthod.
of
a.veragcs and nethod.
of least
sguatres.
(1o trolrs)
Rcf^cr.qng-es
-t.
1)J.G. Diek, tAnaJytior.l Cl.ic;:ristrytr
chaptcr
L,
IIiII,
],
2)D.A. Skoo[,
:.nc].
!.I.1. I,/cst, rAnalytical Chanistry
An introduction
2.
McGra"r+
t
,
I-Io1d.t
-
Iteinhart.
Application of Chcnica^I E+,tIibria - stepw'ise equilibria -
sta.bility constant - Eecipitation equillbria - Solubility
proi.uct. Curron ion cffcct - Honogeneous precipitation.
Copnceipit:Jion
-
- d.iffcrcntial prc-
Post pnocipitation
cipitation - Acid - basc cquil.ibria - conplexation aqri-
l-il:r' .P.
cf-e-r.,*.
.''iox cq,-rilibria.
(1! trorre)
r:ccs :
1.
,.,
.[1.
])ick,
I'{c(}rar,r
2.
r--iiIl
tAnculytical Chcnistry
-
Chaptcr
1,
- {.
L. Meitcs, H.C. Thcmras arrd i.P.
Analytical Chc::ristryl,
n.A.
Arr
Skoog rnd.
t
I'tcGrc"r.r
Ban:nan, rAd.vanced.
IIilI - Chapte -
2.
D.I{. \Iest, tAnalytieal Chenistry -
fntroductionr, Holdt Reintrart - Chapter - 2.
contd...
L\2III.
- Ar:pcronetry Elcctroana"lytical nethod's - Polarogra'phy
Clu:onopotentionctrly - Elactrogravinctry
Coulot-:,ctry
-
I'Iigh Fr c qrtc rrcy Titre"'tlons'
(10 hor:rs)
Rcfcrcnc csI'
1) A'I' Vo6c1,
of Qaantitativc Anatysist
tA Tcxt Book
EIBS.
Intcr2) Lingancr tElcctroanLlyticr'1 Chcnistryt sciencc.
and
1) I' i{'citcs H'C' Thonas
Adva'nced
Hill - Chapter - 6'
L'1" Mcrritt and J'A' Dcalt' InstruMc Grarv
Analytical Chenistryr -\"li11ard'
4) Il.I-i'
R'P' Baur:an'
ncntc.l Method-s of AnalYsisr'
4.Opticelncthod.sofAnalysis-i,icphelonetry-[u.rbi.
Aicraic
clinctry - !'luorinetry - Fla::rc photcrectry ltbs
orption Spectronetry Reflecta"nce spcctra'
(to trours)
!-gf
cr.cP-c_c
1) ir.I. Vogci,
A Tcxt Eook
.t\r:a"lYsist EIES
of Qrantitativc
"
A' l'lcissbcrgcr'
I
Inorga.nic ChcnistrY Vol' I'
2) II.3.
Jonasscn and
Thcrnc.l
,
Inorganic
rTcchniqacs of
Ana\sis - Thcrnogrrvinetric
AnaJrysis
-
Diffcrcntil"lThcrrralAnc'1ysis-DiffcrcntiaJ.
Scannin6 Calorinctry
-
Thernonctric
titrations ( 5 rror'rrs)
RcfgfPP.c.cF-:
1,1.'i. Vcndlr"rrd-t
)
2) RJ.
1
r
Sctrwc'.,:i:cr
tThcrr:'a1 Mcthods
('fr)
rThetrral- Analysist
and
of Analysis I '
P'D' Gesr:
YoI. Ir fI
a'nd
III'
conV'
,''u
\
1l
k)
6.
-
Organic Ano.lysis
nt" r.. .-, point
fats, oiis,
c'nd
standard-s
of purity -
boilinB; point
nixed'
- Andysis
so?'pst suger a-nd starch foocls'
of
nik'
buttcr, crlceholic bweragcs, tcat food prescrVativos, fEarolrring
and.
r"no
cclouring r€:cnts' crlultrents
crrrgs (Coaeinc, ncctyl
c"nd suI1-rhr-n
salicylic e'cid'
phenaectin
i lenidc )
(12 rrorrs)
Refcrcnccs:
1)
C
.L. lJilson
r'nd
D .'
I'
AneJYtiea'I ChenistrY
l"Ii1sonr tCcnprchcnsive
I
2) I.I{. Ko}thoff and P'J' Efvin8'
r'lrcatise in Anr'lytica1 circnistry r ?art II
-:--I
e'nd
Volunes
XIt;'
'r) II.Ir. C]rcrcnis
groull Analysis
and
I"s' l{a'' rga'ga'nic Funstional
t
4) Sritish Heanta'copcc"
5) At'oc (tl.s .l)
':'t<F+' 5) Gu';:stoncl tlntroducticnt tc Chcnistiy'of fa'ts
f:r,tty Acirls t Che'pnann ard HalL
7) I'J' trIelcher' rsta'nderrd
Mcthcds
o'nd
of chenicd Anelysis'
thc a'nalysis cf ailoys
?) Princlplcs of nettrcds uscd- in
nincral (Dolonlte'
(brass, lrronzc, type nctal); orcs and
ilnanitc)' fcrticoppcl p;:ritls, Ila'ena"titc' nonazitc'
Ii-
I .;X detcrr-rinr'ticn)' soil- ard na"terl'
(tz rrorrs)
Bcf c:.'cnei-'s:
1) ll.I. ','ogc-'.
r
J-.iri:';;' ''.-- j
2'l
t-4r
Booi<
cf furntitr'tivc
lncrganic
t !'i lli'i '
l.'i,1Icl-;l ' ::'r
-',"'ii.
ilcxt
rstLn'1arc1
i'icthcitscf chcnicn'I Analysist t
I1I.
con'td.
..
1
1) 1,I.I. Hild.chriirrl, G.D.F.
J.I.
4)
Ilcffi-rr-'.t't
,
l,T
ndaIf, II.A. Bright
rApplicd- Inorgenic -'-:ralysis
I
P.S. BC<cr, G.I''I. Bradbr:ry, J.Irtr. Eichingcr
and-
'
and
E.li. Singcr, rChcnistry ard Your.
B.
Basic Elcctrcnics - Sasic conccpts and n'pplications only,
l[casu:rcncnt r.f voltirg:c, orrxent
apd.
rcsistancc r colour
- }iod.cs and. Triqdcs, Rectifiars, Transistors,
fu.rplificro, W'WI - Lincar Integra-tcd circuits p
Thcniistcrs - Digitr.l elcotronics - piozoclcctricity
codc
and
pyroclcctrioity
(e irours)
Rcf c:cnc es :
1) l{:rb:star1t, Enkc rmd ?crcn, tElcctrcnics f or
Scicntists t Bcnianinr
2) A.J. Dicf
cnclerf
cr, tPrit:ciplcs :f Elcctronic
Instnincnta"ticnt
9.
Ion cxchargc
3--.-
"
phcnoncn.. - Resirnrcus and inorga::ic icn
_
_al.^h+n .ernfiltbfia _ S cpr.T ation
thrcu€h conplsr ione
-
onlon uxur'*"'-
conJ)Lcxes.
(5 tr';urs)
Rcfcrcnces:
1) L. Mcitesr iI.C.
Thonas ard
R'P'
Bauno'n'
tAdva.nccd.Analytica'lchcnistryrrl'{cGrarrHiI11
2) II.F ' \'ia1ton, rkinciplcs
and llcthod's
cf
Chenical
AnalYsis r.
10'
MethodolqgY
of litereture survey in Anr-lytier'I chcnistry.
(2 rrctus)
kt*/10487
//
irrl-.I,R VIII
-
TI-I3C-r.r!:'i'IClrL CijJ-I'IISTRT
Aclvanccd Q,uantum chcmtstry
I.
(go hcurs)
(nrectivo)
(n) I'"g J.-,,r,,c - Fcck_mgltl.tt_
QS ircurs)
(g hc'urs)
Tbe llartreo - F:ck cquat i lns ' Ti:c c lectr 3n c orre lat l cn
t]-lc Hartrce - Fcck
cncrg:/. R:,::ti:sanrs m:clifigati:n:f
nrctlr:r,.l.. Dxarni:las :f 'T'-Iart%e-Fcclc calculatl-:rrs f :r at:ms'
Apt>licati:rn :f thc nr:th:;I t: nrllcculcs'
A.l:?l-icati rl--rf Il'g valclce P'ltt-a3:l-rtrlocl11:
crb tta 1 mothccl _t 3 rl,o ly_at :mig E0lcguleg
irr)
(
4 trcurs
)
DetaiLe<] st'tr-Ilr of thc rasuLts :btalned| f cr
a%, IIIlrr iI2O anrl CZ'l+ (ethytene)
(") IiTo-'Je-lea,iclt-portuIblticE thc:ry
(4 h:urs)
i:n anil abs or;>t i:':l tf racl iart 1:n' Transit'i:n
i>r:bablLitlos. ?hc finstcrn c:efflci.cnts- sclecticn
ruLe6. T'.-' ':ca;ltir :f spcctral Ltnes.
(O) I:rccs_i:':l .leculcs
'
(4 rcurs)
Thc ScneraLizc:l IIall-rnann - Feynman tl:oDrcm. Thc clectrcstat ic trc :r'i:cn. 'Iha rc latl:n bctrrecn thc i{a LLmann-Feynman
thc crcm an,.l ths varta 1 tiic lrclllo
Emiss
.
'j':
t:":t:":
+.
:''-"lo-o':']]
$
h:urs)
(oi 'Itrorcvcmonts sf thc LIIIO met'lrccl
:
IIMC. .pa trtng thc crom. hirP llcat'l3tls r Thc pcnscr "h9
perr oni--l p:plc moth:rls. Ai:lrllcatlcn t c ctlrJrlono an'd
-L
bcnzg1e.,
Text
r:n:ncnd ccl
_b c cks _Re e
t. ELomcntarlr G-r-rantunr chcmlstry, F.L. P1lar, McGraw-Htlt
,.' Quantum chonristr5r, S.R.La Pag11a,
2. fntrccl,
-'Iarpcr a-:I i.crv
3. Q,uantlt'n }leclranics, \-,.I. Schlff, MsGrerw-I-Il1L
4. Qua-t um tL:c :r',r rf lviattorr J.C.SLater, I4cGrmv-Hi11
5, Aclvance.l ..u2.,':-tuur ci.remistr:., ii.Ii\. i-l:,lekc,
< lr-^-
Ai'l<)lSCb - i'treslcy'
\
6.
II.
Aprr3::1 ri''ic I"!)lecuLar Orbltal }4ethccl' J'A'
anc.t D.I-,. .iercnirlGe, I{cGraw-HiL1.
cup the cr-v_a1.l- i! s -ApP-licat icns
-.(a)
\ -., Basic ctcfiniti.ons 1"r.l tlgf,Iems-'[
Gr
BcpLe
(
zo trcurs )
grl'P tl.g31zz
Definiticncfar]r3up.MultIi:licaticntabLcs.Examplcs
cf gr3llps, sub-grl)lJpso class ';f grcuir clcments'
(u) Yrlo gu-La1 gYrSurctrlr.
Tlrc
cns '
Symmctrlr c Lcmcnts ancl symmetrY cllcrat l
symmotr-5rpcintGrsupsanrltlreirsystamatlcic]ont,lf'lcatl.cn.
(.) Rogreseutaticn-cf €r?ug:
Raducible and lrrecluctblc rcprcsentatlcns.'ctrar:ictars
cfreprcscntatlcns.Charactertablcs.Uscgfclraracteri
tabLcs. Vanlshing Lrrtegrals crbltals wlttr ncn-vanislrtng
cvcrtap.S..ilcti3nrulcS.Symmetrya<taptc<tcrbitats.
(a) lvgnotry-aspccts-c€ Eclc:"!a: vlbratlogg'
Synmctry cf. ncrntal' mccies'
Mcclcs cf mcrccuLar vibratl:n'
Gcneral
Nrrmal mcdc analysis taklna HaO as cxamplo'
pr:ccclurc in mrina 1 moclo analysls'
!o=t! :3kg $c g :'lngn!o!:
Lure1l
1. Grcup Tlre:r1r and sym:natrlr Ln chamistrlr;
11, McGra'"r-1: L 11 '
F.A ' C ott cn'
2. Ctrcmlcal litrt>Licat i::ns :rf Grcup Thc cr1r,
Int crs c lcnce .
Jaffe ancl M.Orchin,
3. SymmetrY ln chemistry' iI.H.
Wl lay Eastcrn.
.8. Saunrlors'
4. Physical 1'[cth:Cs in chemistrjr' 11.. S.Drag :r'vf
I.[.I-Ia
.
.t
Q)
III.
{nplicatlStP :f-statlst-lcal-Tl-rcy3cllnamics
(o) Itg
,, ,,(
lJ hcurs)
Jr-lng E'rgcl
Deflniticn. EquivaLancc tc (o) Latticc Gas
(fr) Blnary aLL:y, Thc Bra'g - Wl1llams a,l)rcximatLcn'
tsothc-Picr-1-s anc't ouasl-chcnlcal apprlxtmatlcns' Exact
scLutlrn - )r thc rno-clfunontlrnaL prcbLem'
(
r)
{,-l:::e!,.:r
Ir[cnrlaycr ;-rils:rrptl:n : The rlorivati:n ef Langmuirs
is:thcrm ('l:taiLccl trcertmcnt). Dcrivaticn :>f B'E'T'
multi-la;''cr c 1s r:.'1rti:n islthcrrn'
(\ .'! Thc
-,
cnr :f roact i:n rutos
clcrlvati:r: :rf thc abs:lutc ratc equatLcn'
statlsticat
Dcrlvat i rn :f e:il)rcss i:ns f :r tl:e frcc encr8Jr cf act lvat t on' cncrgJa cf act lvat i:tn an<l cntrclly cf act lvAt Lcn'
loft! c 3kg !c I clngn']"'l t
'
II/.
1. An Intrc<lt-tcticn tc statisticaL Tlecrmcdynamlcst
T. L. -Fii 1 " , lrrlrl ls i cn - i{as lcY
2r stzlt- ;'i .:-it}{edharrlcsr l(''HuonSr J:hn1flIcy'
Mcchanics, F'C' Andrcws'
3. Equilib:. iLrrlt statistical
J :hn ir i lc-r, .
h. Stiitist i ca1 Macirani.cs, Thctmodynamics and Kincticst
O.*L.F.j-1;g, 'i.,:I.Frecnan anl] C3.
(ZO Urr"r)
-Irrfralcl-an-.-l'r:uan-S'-rc-ctr:)sc:iY
Ir.; r:d r-rct i-:rJ
a)
( f)
Sc-rr:cti:,-i rules f ir absrrl:t1:n of racliaticn by
IR anrl Raman sclccti:n ruLcs'
rn:rLecu1i',r vib::ati:ns.
(Z) Intensity ancl llnc w1:lth:f s,cctraL 1ines. Pcpulatlcn
Dcpl>lcr broacliirrg anO
rf vari:ns statcs anrl intensity.
lifo tlmc br:arlcnl-n8. Chomica1 pr3ccsscs 'affect1n3 Linc
w lclt h.
.:/
e/
L($
t
D
cf
n:nnal cccrcliaatc analysis
(u) ( f) Intrrcluctlon
slmplcmclcculcsanc]tlreirbanclassignmc.nts.Ssrmmetry
cf pclyvlbratlons ' Vtbratl-cns
mrlccular
cf
aspects
3f number cf actlvc
DctoimlnatLcn
at cmic mclecul-es' ,
IR and Raman 1lnc'
bancl pcslticn and
abscrpticn'
affecting
(Z) Fact''s
rescnance'
U'*o-oo"":1:"^*"
coupllng'
as
suclr
nffiilber:
ccncliticns fcr
ltyr
S;rmne
snos'
combinaticrl at-r''1 overt
bantJs' 'Effect
rcs3nancc
Fcrml
ancl
c:'LlpLirr6, c:''lirinat ion
rluo t c chan4ie in syunetry'
cf cccrcllnat 'n "-oi'octra
Raman sircctriscopyt
(.) Appf icat i "'ns :f Res:narlco
and Lascr Raman spcctr:ssp-ectrf,sclPy
Ranian
Rctaticnal
ln IR ancl llaman
tcchnlqucs
:rrm
transf
ccpy. Frurier
tcchniqucs'
ls:Iati:n
spcctrcsc3Py' Mctrix
Rccommcnclcd'
EcttE r3kg
F. Danic Is ancl Il'A 'A lbcrtYt
chcmlstrTr
PhYslcal
L. ,
l'fllay Eastcrn'
2. Plryslcal chemlstr}rr
,
P
Univers itY
.W. Atklns , Oxf :rcl
t)fcElso
in chomistrlrt R'S'Drag::'
-'iathccls
Ptrysi'^9.
-"I'S'Sausrclcrs
ancl C: '
v.
t;;'sc-ro st':'e
si-rcc!r3s9 rPU
(
to trrrrs)
cffocts cf
rolcctr:ln
Ph:t
prlncipLcs
'
a) Basic
)(-ray flucresCcllccr
pr3coss''
.and il-rzlyso -r'!.3uf
Kccpr-ran'l s thc :re:n'
spoctra' IJV 6nd X-ra/
phct:o'octrcn
rf
(u) Fcaturcs
P.E.. spectrcrnctcrs
_^r^^+s^re spcc
sr-rcctfcsccpy arrd
phctcclcctrctl
betwcen
(") .teLatlcn
X"' N2 ' C)' H'S'
Ar'
cf
Stucll
MO thcory ccnccpts'
HrO and Ni{3. A1:PLicatlins'
t;)
To=tE.3kg Bc c :rmrncndcd
spcctrcsc3py: ChemicaL ancl Analytlcal
1. Ph:t:cicctr:n
Aspccts, -Ir.D.5akcr ancl D'Rettcrirlge' Internaticnal
Vel' 53'
serl-es of Mont>6raphs i'n Analytical Chcrnistry'
Perqarnon Frcss.
2.
iI'B'
.'hyslcal i'lcthcde Ln ;hcrnistry' R'S'Dragc'
Saundors and Cc.
3.
II
2
. tsock ancl ?.D.l'Icllaro,
506,
19'14
J' Ctrcm' E<lucatl:n'
'
l!. T.L.Jamcs, I'bicl, gL, 712, 1971
-:\Yt clrcmical Rcvicwsl 71t 295' 1971'
5. S.D"
'Jt'
\---L
.,
(_t
-.-.-o-
I
,D3?r3'
vlii
(;rrective;\
soLD sTliT;i cl:r:'it'lSTllr
(
9o '^''"ur" )
( 1o"'ltcurs)
:f ":'10"'
rntcrnal structr-rrc
thc
-ilaals f lrcos ' thc iinic bcncl'
1) Ttle va'':r 6161
c3valenti:onr'l'tirc$ctal-Licr:cnrlancltt'rchyrlrtrg:cn'bcncl'
:f bi:nc'l s - I:nic
ii)Co:nllafisclr:'fbcncls:rft'l-rcvariruskinrlsanilclassiflnatltrc
t1:e
:n
-::1 beiscr'l
cati-rn cf s:; s lzrbticc at :nric Iatticer l;rctalllc
lattico, m:l.t-'clitirr
i:r-b:;r:l
B:ac1i4g ancl
I.
lat I icc,
iij )
latt ir;c l'iii:ir
'
P:lynr ;:iirhis'n'
( zo t
.'ur.
-;r'i-rl 9
rlirl, statc ''':'6r
' '38:rc1 ?he:rrY :f
(iii
scLicls
jclcctron tLrccr)' :f
i) Frcc
cf scl-iCs intr ci;ncluctors'
cLassificr'ti:n
sciicls (iii)
ancl insILat :rs'
semic:nr]uct :rs
( t o rt:urs)
II.
S
9:z:!: l--?elgg!:
III.
ct s r
ects r Planc Dere
Eine
I:rcn-stcchi:,Def
? oir:t cref ccts,
rml:crfccticns ancl
l)
( ir)
i'npcrfccti:ns
Elcctr:ns "; h:les
:f lntr:clncing
Tecirniqucs
mctry ( if f)
ina5:'Li-'''-'r'1i:l['lrCs'nprcssi:r1'crusingancilrrar1iatl::ri
r:f c ct l:rrs '
cf var i :'"-rs i ''''
( f f 1::urs )
!ogs 99t
-Interagt
c ct f A-Eilibir io -ottl -Do-f
Daf
--:--'--1 cnt itY
n as a c"rcnica
It/ .
;'
il,,';:::Hphlso
cxtcr':rr'1
clcfocts'
v"
a
li:'
(
it) li-rcct
i::'l"::::::';il:J:::;"
and Inr-lircct interacti:ns
""'::::
iltl i
,]ifrgu i:;n !n -s -
(r
lnterst it ial'
Laws
icks
'ii'ttto"oaLr'
rcact i:n'
r
:f
hcurs)
clisscciativc
facc, Grain b:uncla4f
-\
)
cffcct
anci
I
ls
man anrl anima
cn
Effccts
Effc ct s of air PoLIutiints"
- Effects
vcgctat''on
on
s
ct
Effc
Effe ct s cn matcrlals
cn
wilcl eccsYstcms
(rz
rrcurs)
:'l'ncndcd :
|
ct ivc '
r
rr*omi
ca l- pcrsl>c
Clcmical
A
4'
o-rr Errvirorunent
Clcaning
"1978' Chaptcr
1.
Asrsrican "r'"titor ""io*y '
ancl 'datcr Pcllutiorrr
Air
Chc'nistry
S"ctt pu'oI' 1972 '
z.rEnvir:n::;cntal
L'Sc'\3er'
ii'S ' 5i 3p[cr arrcl
l LLili3is '
B o cks
IlI
r
c
lulatcr
PcLir-ttisrr:
tlatcr pclir-tticrr:
r,tr.f,cr o-uaLitY''rit"rrl
:::-:::""
Annostic and inclustrial
;
H :::,::r:::':;il"tJ';;-* :,:: ::L' :1:1::", "";
r
USCSO
.
Il;:;.:I'
"":1::' :I
l:::i':"u" cf: rsr
:::T$;"-x
"l "l "T.:;i
-:
-;
cbcmlca:
stanclarcls
:::::'"::;:::"r.':
watcr
::'.1.:::
(noo)
:*';.";:
:'l::. ;;;;;.
;:il:''
"".";;e
o"tilar aPPrl'toti"o"'
Biologi"o'
f cr clr 1d<ir]3'
?:l1uti:r'r
( B hours)
c:ntroL'
cc.:rtrc1r,
.,oLluticn ccr
?clluticn
^__1
ott]
il cf :+atcr Rcsorrrcc=
van Nostrancl
1-. iiani.i:o
inu" ' ) '
:i' 'i 'Gcirm and ' ' ' 'ot"";o"
ilc:u Ycrk' 1976'
Ilcin;rrLcl Ci"
Scorss rcclr':r.irc,rldcil:
2,royitrci-ll-cs;:f:'ratcrqr-raLi-tyccntrcltrT'r-I-Y'Tcbbuttr
ao"': t'1,'
Prcss ' Ne-'+
,t.ricaL Pcrsl:cctivctr
""t;;;';
chapt c'r 5'
3' ':::li"'I' :[*:;:'J::::::': l',;;;
IV.
anrl i{cnitcrinS:
P:lLr-rticn Anatysis
Analysis ancl air
llnaLyticalc:noeptsancll)rDccJures.Stanc]arcligaticn
air'
in
l'lcas'"oot"""
mcthcc'is '
qLlarl:li.].Crrcls..-..anclarcllzati,,,,rrnctlrcc]sfcraII.
gfo
et
l4cnltcrlng' air ccntaininants - particulatc :.:rattcr soz,
oxirlcs cf nitr rgcrr, i:hct cchcmica 1 cxidant, lry:lr ccarb cns,
co, i{2s. I'4casnremonts in rratcr. stan.lardizaticn cf
mcthccls. sainpLing tccr*riqucs. Mcnit cring rratcr
ccntaminants ' rncrganics in watcr. Aut cmaticx watcr
Autcmatic mcnitrrlng:. *lnarysis cf trace mctaLs llkc I-Igrpb, As.
cr ctc. ln rnratcr. rnstrumentar methccls - usc cf Atcmic
Abs crpt i on spcctrrmctrlr.
( t4 hcurs)
clis re c .rcnclcit r
1. rclcani: ; :nr rr'nvircnnont - A chcrnical parspcctivc,,
Ailcrica'r cl:ci;r.j-ca I s cciaty , 1978. Chapt er Z,
Bc
2. rStanrlar,:l l.Ictircrls fcr tlto E;661p1 inaticn cf rsater ancJ
',rastc ruator M.C. .IlanC ct al (Ects.), Amcrican
Publlc llcatttr Ass:ciatic, inui:t.), 1976 (f4 cd.).
v.]'I6sf,6 rvatcr Troatrnont: principlcs.
Bas;ic pri:nar1r and
scconrlary treatrncnt. sLudgc rra:rcrring and clispcsaL.
Advancocl troatrncnt.
ccaguraticn ancr procilrltaticn.
ri't ltrat i cn, arJs crpt t :n. Erem cva L cf crganics
anrr incrganics.
Bl ctcgica I trcatnont cf rsastc watcr
- thc orlr ancl
practice.
itiver 1>cllutlcn ancl sanltaticn.
ISI standarils
cf l-1'1'Lucnt ryatcr.
('lz hcurs)
tscclis r
.;.1,::! ccls
clcani'rr:f )rrr Dnvlrcnnent - A crromica pcrspcct
rivc r ,
rimcri_cai.r cl,.c:rical s:cict-,r, 19Tg,
chaptc r 5,
2' ll'Iir:l':'..''-'icr trcatrncntt, Mct calf
aucl jlclcly rnc.y
-f
ll0 C;:il,r -i 1 1 , l..Ic.,.r :1L: 1gTZ .
.ir6'ricr-rltura't cl:i:ni-caIs in thc Envir:mcnt.
l'
Vf
I
fntrccluct i:rn: pcst iciclcs ancl ,ncrbi.cielcs.
Tcxicity _
ha:<arcl. *estrorac anrl hcrbicr.clc
cl:eryicars. crassi-fr_
cat i cn tf post icicle anrl horbicirlo
chcrnica ls.
Rcact iv ity
or'-l pcrs lsteecc. phys ioc-c'ornica
1 j)r cpcrt ics ancl
3/kt:s
\fatcr.
Bo
1
.
.
2,
VII .
:ks re c Dnrlc::t'..l
c cl :
- A C1:cmical PcrsPcctivcr '
chaPt cr '7 '
I'morIcai1 c!.remicat socict1" 1978,
anc'l
rDc,3ra,-latisn cf l:crbicit.l cs t ' P'C' I(carncy
1959 '
D.D. Kcaufnan, I'larcc I Dek''icr '
t C teani-ii18
0nvirlla'nt
951"--nv ir cnlncnt
I
:'i- To::ictLttTfz
CLassif il- f llct :rs tllat i:rf lrrcncc t oxicity'
:f Chemicals incluc]ing
cat i.;;,r :f llit;::'rsf r-rl cff ccts
r tdsf,ins mctir:rls'
tcliclt:"i:'
r
ar1{l,,,iierbi',9i'-{cs
ilcet lelrtq+
Acutotcxicitirstudics-ProL':ngccltcxicLti'ytcsts'Chrcnic
Chcrniui:'
t:;ricit-r t':5ts '
{lz
hc'-rrs)
s rc c a:nilr;111.i c iI :
T'A' Lc:mis' Lcc ancl
T::xiccl:1ryr'
cf
Esscrrtiats
1.
1-1rhia 1978 '
I'cs i-1;cr r:uirlisircrs ' ?hiLa:'lc
A. I{anil'b:n ancl I-i'L'
r
t::ric:c:trsr/t
tTnrlr.rstrial
z.
Mass D74'
'
Flarclir, PS. Ptrilt' Co"
B c :1c
V]II
Ftacl
iat i:n in t'l-:c inv irrrrmcnt:
tl;rc ir
.rt i rrr :1c cay ancl
_ti:t:;'r, ,, ;::""r"]rl'''*o.
f u t ":t::::
":: I on
rransp crtat
Lo.
cvc
1
rr-re
roar
-*'ur
Managerncrlt o
'nqto Manasefficrlt.
cact ive wastc
llarrT
:;" ":;1';:";,;i';"-:'r"..=."
.
^6'iq.irrr:r ra(l iat i:n'
^ 3icr,t'LztT
cf
trffccts
n
oi.l'
soiL.
s
in
:il::::':; aIrd
,
llar'i'i
ilar'i'i cnuc li;l os in
;cxrs' Dctccti3n
I
;ii:]1:"'.l'l:.,::="::.i' "*r."i
nnr^
^t- c
b,
/tr.11=-
rn hL't:lia'lis
i
i:rr sls
'r<\
pApDR
I.
Intrcclnct.
VIII
I
EI.;VI;ICIMSNTAL CitDl'iIsTRl-
90 hcurs
: i,:rd sccpc t
Chc:nistrT' cf tho cnvircnmcnt.
its chcsnical constituticn
ba Lancc<I
ccnstitutlon.
(er,nmrvo)
The air cnvircnmcnt
and factors distcrting
tho
F1ov, clispersi-cn ancl transf cfrlro-
ticn.Chemicaltransfcrrnaticnsintlrcairanvircnment
suLf r-rr clicxicle: - thc sr:l.f ur cyclc. oxic'lcs of nitrcgen
ancl nitrcgcn cycLc. Hyclrccarbons. Plrct ccironicaL smoS'
A c r cs o1
Ph ct cchcmi ca L rea ct i cls in atnr osptrc ro '
f crmat I on l-n s'T! o$ r
The watcr envi.rcnment 3 -B-Lc't , d ispers icn ancl degradat icn'
Bi clog Lca 1 asr.)octs. Chcnrica 1 cxy'gon dcnancl ( COO) and
BlclogicaL oxy6en Dcmancl (loo). ParticuLatc matter,
trans:-lort ln s cil ar^cl grcuied water'
( lo ttcurs)
B g cks
L.
2.
If.
re c otn:;lg;;]
s cl :
rCLcani:-'3 cltr Envircnrlcnt - A CtrrcmLcaL pr:rspcctivcr '
Amc;:ica:n chcnica I Sccicty, 1978' Chaptcrs 4 and 5'
r.l:rvirll::nc:-rtaI clcinistfyl , J.i'I . i'Iccfe and E.A.
.'iccrc, liccr.ictnic 1:ress, 1976'
3. '"rrr.1 611irr-]rrtaLs :f liir Pcluticnl , A'C' stern ct o1'
Academic Press, 1973'
Scurccs cf air pcllution' fndustrlal
AiE-p!!q.!!qns
pcLLution. Prcccss wastcs ancl ncn-prcccss wastes'
PcILuticn by sttlft:r <licxlclo carbcn !ncncxldc ancl cxic'les cf
?hc alrtorncbilc pclluticn - ErnissLon stcnclarc'ls'
nitrcgcn.
Lca<l ln f tte 1- - EmissLcn ccntrcls'
Susircnilecl pn::ticuLato mattor, tncrganic ccnstituents'
crganiC,...i-al,tstalpartlculatcrnattcr-settlcd
particule,.i:. .ra'ttcr. Gasoctts and viiDcr;r air ccntanrinants
CO, SC2, SO3, I'lO, NOZ and tryclrccarbcns. Unlts fcr
c r-tant if i-cat j :n cf a ir il c i lut i cn'
animals
Tnan and
cn
uttott=
eccsYsteos
polrutrint:':.,
Effects ctl wLlcl
Effccts of alr
Effccts "" '";;^t'ot
Uffo"t" cn matorla]'s
Bocks 1., cr':'rcn'Jcd'
(rz
_-
A
rrcurs)
chcmicaL pcrspectivc
I
r
Erwl""::"r::r, 1r;;".-';;ptot 4 '
rur
1 . creanins
Pclltrtion
Arnerican chcmi'cat
n r n orrcl ,r{otcr
t'1"'';.:t"T-.;," ;.ctt pu'ol' 1972'
:n:::cnt^t
rsnvi,
z.
ancl
i'i'S' Str3q1'-cf
I LLin:i's '
t
'
Llscso
rrl
crcncstt:.::]=;:U::t""t
'ilatcr PDLiuriisrl: . -^ria ror
-oirrogi.or
q.ualitY
Ii{ater
""1"
y cf watcr
plrysi.or, ctrc"nical ";;
;;, Elcrncnta;":::, i::ri'i*
cf lsr
stot'd"rttt
t*cr'U:
crrcmlcal
'"ryscn
,oto"
1'SOO) '
on' [:;;:
.,,,.r *outo
1 apt>Iicat i
astria
i ol-ogica1(B nours)
f cr clrlrrliing'
? l1'!-rrt
i:r.i c:ntr cl'
lc:r.is rccl:'::'ire:rrJcil:
1','::fi
.
r
s :f
1t1i::rc ir lc
rvat
cr
qr-ra L
?cllution ca'rtrclr
s
'
;:Tl';'irancl
tty contrcr'r
T.'-I-Y' Tebbuttr
x** ; il ild l;*'' tt':;"'";":
chcnrical
/-i:nef ican
rv
ancl
; lJII,Tifl;X'l'"
cc"
*cini-rr,ro
2
s
"
1
iv
*
ccic':'
^:.;.:::;=;i
,-*J=.
=iffiqil1':L
::::,,:::"":.."1.;;;ati:n
cr mr
a,r
,{a.
^{--
J"
i'lcthcrls cf rail iart ion r;rctect i cn.
m:nit crlryi.
(
Bc
1
.
2.
IX.
lo hcurs)
cks rc c crn:nenclcd :
t
antn.3 3ur onv Lr ::nrncnt - A Cirenica 1 pcrspcct ivc '
tl circn ica L s :c icty , 1978, chal:tcr B '
hrir
C Lc
iati.:n pr:tccti:nr,
Prcss. , 1972.
rRaii
j'ic Li::;tl :;1-';31'
Cl:.r::ti s;
-'i' litcrerti-rrc sL!rvcy l-n Envircrrinental
i7 t
Intr-;ilucti:;l:
ln ti:e
J. sl:apiro, Hanuard univ'
sub
t c jcurnails, pcricdicails ancl mcn:graphs
ject.,
(z
h::'-rrs )
t'
a'
51
Pl:.],jil. VIfI
r.
?axcncm.y'
3f
P
lTliTJ-?AL pi-io._.r.ICTS ( ;;-r_'C-f filf )
lants: -
(Ur. cf lecurs !O)
Lccat i:>n, lclcnt if icat i cn, cu It ivat i cn,
c I 1 lc ct i :.,r:r st ,irage anr.'l usc s cf l> Lants cf . med ic lndimlt crtance o
RIFEITL'I.ICE:
-
1. Ga'lble J.So, III:ra of thc prcsic'icncy cf Mact ras
\,'trIs. {.'g5'7.i^.n-.) n:t. SLrrv. cf fnclia, Cul_cutta.
2. Lerrrc::.,cc G.r'i. 1i51 Ta;ronlril. rf vascLrrar 1>lants 1971+
I.:ln. Ncr,, .lc 1l:i.
3. Ilcn-llc +i.1. 1gCl.. .Thc classificati:i:
cf flc.wering
plants 197i Ejq. Carnl:ri,:J3c Unirr. press.
4. I'I::':or J..!). ('tzzz-1Dg7) Thc Frcra cf tsirl.tisir rnilia.
V c ts, Lcnr1 on.
5. 3ailey 1.,,]1. 1949. I,{anural cf cultivaterl i:Iants
(Vftn rofer 1961) i,Iacnillan cornpany. Itrew ycrlc.
6. Jcncs, S.B. anr.] A.E.Luci.:slngcr 1979 pLant systcmatics.
I.IC Grc.n i{ill
fnc. New ycrk.
If'
Classificati:n
lf I'iaturaL pr:c!ucts.
carb:lryr1r:,- r:.' - ?crponci,:Is, carctcncicls, aL1-.arricls,
srcrlicl s, lin';:r:rcr/rL-rmins ctc. I'Icthocls cf iscLaticn cf
cjitcl-t.cLq_ss :f c:m1-r ;Lrnil ancl clataitccl study incllrclirq3
strncture c r.Ltci,,laticns, synthcsis anil stcrcccitcrnistry
unrlcr caici-:. ciasg.
a) 'rerpc'ncii.'s. ci-assificati.:n of terpcnes - iscprcne
rule
r:ncnes carv3ncs, ncnthcL, mcth:nc, ,{-Thujane
car-J cnc, car 2-ene, Car;nc, Carcnic acld. 4-pinene,
Camphcr, Farnesclr Bisabclonc, Aristclcchcne. fshwarancr
Isirlnrarcne, Ircmcirhllcno, Abictic aci:lr LancstercL
Lit s :mcnt c1 Lupe c1, (-anyrin,
$-anyrln.
I
Refc rcnce
s
1. Tcrpencii-l s':y Srl-rncnscn Vcls.
'' r l--Iigiror terponclcls
2. P.De.lfe--
't/kss
cf the tcrPcncs
55 Erl .'cY NSldTrlan
. 15 tr 619 (rgzo)
*" 5ooe (rgzt)
1
b) StcrcLrls'
Dctailec'i
ls:lati:;n rf sterrit'ls
a'o''!
C1-e' ';-cati:n
ilnr synttlcsis and
Luci:',!at
c
structurc
i11i
st't:i',;' i '
thc f :1-lo:'ring'
stcro :ehc'r'r'.':ry :f
C
:rt ic cst cl 'i" :-rr!'c r
ftcfcrcnccs3
Stcrclcls
Elcscr an:l Fl-cser'
klync'
Thc ChcrristrY :f storiclcls shcPPc
sterclcls'
ChcnristrY :f the
ctrcmistry of thc fl-rpcncids
thc
tc
4. lrn i-ntro<lucticn
TcmP Lct cn'
an.'i sterl cLcls,
Dicrassl
cry cllspcrslcn''
rctat
J. Qrtlcal
bv Mass
cr Natura prorructs
1.
2.
3,
6.
l.
")
::""*
::l'"1:'"1?.,l;,,"
ct a1'
spoc.r-:.i:'ccpy' Djcrassl 1'L' Finar
frcm
Itctcvc:.'u .:iloitoi"
;1'[1<a;,.t.r=:;"tnr.ce
c-ras:sif,icati:nr
Vcr' rr'
rsolaticn
chrcmatc-
gri,-'hical'"';l;iicrtcclr'r:ict'tcscfpt-t-':ificati:i1'Dctailecl
f :;l'':t'";l't"r"lr
LyscrS:ic
st,-rcl-v cf t'''t
Ty1q:ircrln ancl
llcscrpirrc
'
l.'lcrphinc r Y ch nrbir'-o '
ac icl
.
ilafcreneo:
. /:I_ical:i,-]s by Bcntt-ey
2. 'ihc a Ll;a 1o irls by i{61s6c ,ro
lnes yo ls.
3. The 1>icnt alcirlci-..! s, I::cnry
4
' I'Iatrrra r rlciructs chemistry v o1. r anci rr .icrrans.r.:a
5. IJ.V. S:roctra :f a lka Lcicls by
San.ster and st uan
6, l-ile l-cvcnt chal:ters fr:m Finar
v:I. fI.
( lo hcLrrs)
'1
d
) Ant hccya:rins : Intr:;il uct i :;n, Gcncra I
ant irr :cyani,:l ins
i.tr61f,
u1,s an:l
structurc
cf
.
Fla'r:rrc, Flav:;n:1, eucrcctin,
fscflavinc ancl chalconc.
D o:ks:
,"r, ?l;c lrat r-rra I pisnrcnts
:.
l::a
i q ucissnlon (c:! ), Tirc cl:a,rstr,5r I rntcrscicncc
cf f lavoncicrs
compcun.^,,s,
(pcrgonr cn) .
Bcrnf,clcl (c..1) 3i:,3:enesis
rf Nainral
3,
(pcrgarncnr\.
4
.
Jrnc, C crnlorat ivc Bi cchomistry
cf
Aca,:lcmic press 1967.
Fina-.r V:I.. ff, Ch.
15.
1i6v:l
5.
IIr.
lDr
crm,o1rncls
cst
a1g
lancJ
ins
:
F 1a_tcn:icjs
(+
$ours )
Circmistrl' cf prcsta6LanrJlns
_ fsclatlsn c lass ificat
i cn,
struct u -a t c luciclat i rn an,-J
synthes is cf TG.T, PGF, PGA
anrl l)GB gr slrl)s of pr cstag
lanc.! tns ,
Rofol-ei-rccs:
1.
rrT.
Pinc, IIar ura I
;-cl.:s:n et aI cir. 17.
1;_-: . ;,rcts ehcnristz.y ecl
itcrl b1. rl:clansha Vc1. ff .
;..
tli c8cnesis ::f' I.latura I proclr.rcts
Icke tcrl:enc stcrciils
and alkalcir,.s
G ircr.rrs)
1. BcrnfcLcl(c..!) licgencsis
rf l.Iat r-rra 1 pr:rt uct s ( r
2. itf u lhc ir:1 a,-tri Ilarur. Thc
967) .
Bi csynthc s !.s :f stcr.cls
Clrem. S cc. Xev . 1972
, 25i._ ,
3/l--es
aF
lo'.'r-'nt s11i117te f s of t ' L'F inar '
c''Do
(r.ii., u.v., l{'I'{'F-'r }:i'-"i-:'
Spectra L antr ticat i rn
iclat i orr ':11 ii''- I ra L
o.R.D.) ln the st ruci lrra L c luc
3
IV.
.
P.e
ancl
Prcclucts.
( 7 troLrrs )
by i)lryslcal
!j-rn :f :rganic siructurc
1 tc 4'
..,ca.1 crtic i):lcss vcI'
mr-th:ils in :-:r'3a11ic circmistrlrr
2. Scl::."tnl':- ..c'l) Iii-rsi'cal
OIivc : a'.r'l'J:rrii( f95ll)
I{c Gravr IIiLI
R"rta t:trJ Dispcrsicn
Cirtioal
Djcrassi,
3.
Disl;crs i on 'inrl Circu Lar
:r'r
ilctrit
L
C''rt
ica
4. Crabi:o.
IIr;lclcrr DaY (lgGS) '
cltr:mi'str14
lri;ani'c
in
Diclr:ism
Sircctrcsccl-ric mctirccs in
Fl-c:ninil'
an:l!
-1IilLiams
5.
I{il1 {'tg65\ '
Cr3anic c-ircmi'stry t'Ic'Grarr
Prcss
:f NI'IR spectra' Plcnum
Intcrprctaticn
Bir:1c,
6,
(
7
rl5l).
, ITat,;r'e 1961't ,
217
'
91 B '
lb\
I
Pd,.oJ-f
ilrTT
p
ol;nvIER Ci-ii.Mrs?.?r
(erectivc)
r)
tsasLc c:ncc1>ts ancl ?oryninclcg,yr
Func.t ase_-r.i;_, e:n:,r1rts
cf pclymor Scienco the sciencc
cf large (r.,.,-..,,. "-:rir:cules.
Hist crT' cf thc clcvol-cpment
cf tha macrcmcr-ecii. .ri. ccncept.
rmpcrtanco
in evcry'ray lifc.
Natural .eued syntirctic pqlymersr Diffcrcnt tylras Df pclymcrs
ancr pcrymerizaticn
prscesscs' Mcrccular forccs
ancr chemical bcnciin6 in
pcl)zmars, ;:rlmarlr l:cnclsr
scccnclay bcncl fcrcos anct intcrmc1ocuLar fcrces.
(, hcurs)
?cxt bccks,
mcr
,,
s
wi tc.,-i.:rtcrsciance (lW6)
"t'Lorrao ,
.
2.
G. QJ lan, "princ lp las cf
F c lymertza,t i cn,r
,
Mc Grnr+ initt (rgeO)
I-I.Ii,-ri 1 [cock an,:l rr,,,I Laml:e, ,,ccntempcrar:r
3'
.
pcl;rme.r
ChomistrTzr!, prent f.ce_Iia1L
( f gSO)
4) ,'1ias, ,,i.Iacrf,rncI_oculcs,,, ple'um
prass
II)
(
tggo).
Ivlclccular ;rleightr I{clccu
lar ?Ie lglrt Dtstrllrutlcn anc]
l{ c 1e c.u lar s ize
Dlffcre4t ty1>es cf m:;rccurar
rreigtrts-Numbcr-avcragc,
wo lg.t -averogo ancr
a-ovcroge m clccu Lar rcc lghts.
I'4cLccuLar wei6trt ctistrlbuticn.
pclyclispcr b
lW
Mcth:ds f cr mclecular rrelght
,Cctannlnatisn cf
Ilcl-Jrmers' EncI-grcurr anarysis.
ccL Ligativa.p.rcporty
moas uromc,.+ , c 3ncontrlrt
i cn clcpanilcncc cf c c l ligat
ivc
prcpcrt: . , . ,ralr:lur prcssurc
lcwcrlng t cilcsc:py and
csmometr5r. , ig.:t_scattering
methc<I Ultraccntref ugati cn.
scluticn virc:sity
anci mcrecur-ar sizc, cxlrerimontal
metircclc, trcertmcnt cf r-Iata.
Strinilinger inclox. Empirical
ccrrclatirns bctwcon intrtnsic
visccsity and mclecular
sizc' Dctcrninatlcn cf
chain branchrn6 in pcr,rmersl
3
1/1i",
_v
:ra:l\f.
I'Tumcrical 1'rr:bl-cms t : illustratc
tho clctcrminati:n
:f mllccular r.roi61:tr rclccul-er r,rcight clistributicns ancl
1t rlyc!islrcrs ity basccl cn thc ab:ve tcchnio.uos.
Toxt Bocks:
1) F.Id. 3lllmcycrr rrToxt-bcck cf Pclyrner sciencetr,
wi Ie1'-Intcrscicncc ( tgZ5) .
2) Danic ls anr,! ;i lbcrty, I'P[ysica I Chenistrl'rr,
5th,Dsly1., Jchn I{ilcy (tggO)
3) Tagcr, 'tPirysical chomistry :f F:llrmcrsrr,
i41r ?ubListrcrs ( 19BO).
4) Stevcns, "P:Ilnlor Ohcnistry - An intrc,Cucti:ntr,
lrclr.lisDr.r - :IcsLoy (tgaO)
Sc'"-n:r-rr an:'l C.E.Carraircr, rlPcLympr Clrcn:istry?t,
5)
t Ma".ol
:.=.
- Dcirhcr (r9sr).
6),-r-l-ias, tri-Iacrlm:iccr.llcsfl , Plpnuil Prt-.ss ( 19BO).
1I)
Ccr:'c lcat i:r-: Dctr,icr:n struct nrc anil pr:1ru.rt ics:
Basic dctcr:rrinants rf 1>rlyrncr l)r:pcrties.
Sclurticn
i)ripcrtic,:i ci-.;r.rl chi:micaI naturc :f thc i>rlymcr cl-raln.
Ef f c ct '.;! s u-nst it r-rt i on in l) c lar i.ty anr-t lryr.ir ogcn b nncl lng
I'lclt prcpertics and tcnsilc
)r. 1):I-,'ruor silubility.
strcngth. Iff cct cf rn:lccular rrcig'bt, ffi]lcct-tlar :vcigirt
clistribr,rtL:n aarl c:r_ao|ymcrizati:n. GLass transiticn
tc.npcrat ure an,:l cr'5rsta 11lnc rnc 1t ing p cint , variat i cn wltl:
Molecul-ar interprctaticn
cf thc glassy stato
structure.
cf n3lyrnsyo. .llhoc'-t>Ey cf po1)rmcrs. Vi.sc:lte f1cw.
Frcperty requircments
liinet ic thc:rar :f runrl€ olast icity.
ancll pol-','rnur :rtilizatit.,
- clast3:rcrs, fibcrs ancl
plasti-cs. . :tr:nic ;)r'l.i)urtics, elcctrical pr3p3crties
an..l f Laine -rr .. i- ^:ila::t Dr fl)c rt ic s .
Text ll::-r;
:
1) ;I.R.A llcrcl< anrl F.',I.Laiu1tc, ttC:ntcm1:frarJr p:Ly:ncr
Circrni-st17rr, Prcnticc-I{all ( rgst ) .
2/k{:s
2'i F..Ir Biil_mcyerr ilText_bcth oi pcLymer Scicnce,,r
.Iilcy-fntcrsciencc (tgf O,
3) Stovc,s, "p3.1rmsv chcmistry'r, A,.r,:liscn ?Icsloy ( rgso)
4) Dliasr "I,,Iacrsrn:lcculcsr, pLenr:m prcss (rgAo).
rv'
Aclcliticn P:lyrnerizaticn
(itacticaL c',raln pcly.nc rLzaticn) l
Virryt P:lymcrizati:nVinyl m;,nDmor*so Effcct cf cLc_
ctrcnic structnrc cf crg.nic cf,mpcun:rs. I{acir.anism
cf
vlnyl polymerizatl:n.
chcmlstry- cf eincrcnsaticn pcry_
mcrizaticn.
?ypcs of conclensation p:I_ymcrs. Differcnt
step-rrlsc rcact i cns. rntcrf acra r c cnclensat
i cn. Ring
vor'sus ci-;ain f:rrnatirn.
Kinctrcs, rcactrvity and
mclocular sizo' Pr-'ly Functicnal c:udcnsatiDrr
psrymcrlzaticn.
Gcl-ati:;n. Gcj- I:,ci_nt _ experimcntal cbsarsraticn.
l{olccula:: rreight r.!istributiln.
Rlng_sclssiDn l)clyrnorLzat i on.
Technigucs :Lf pollrnorizat irn: pcrymcr1zat
icn in hctcrcgcnoo'_rs-{ ancl hcnc6icno:us
s.rstcrns. Gas i:hasc IJsLlmcriza_
t r. cn. -:-u rk ;::r-ymcrizat i:r-r. ancl pcrlnner precipltaticn.
sus;:ensi:n pcr;,5167izati ln anc,r cmulsicn pclymor
i-zat LtI^,
Diene ancr irivi.nyl pol)-rnerizati. cn. Ir{cnc
anc-.r rretcrc
dispersc p:lymcrs.
(
Text
b
ts
hcurs )
c:]rs:
1) G. Oiiianr rrprinciplos cf pclymerlzaticnl,,
l.tc. G.rary }ii t 1 i,tgZo) .
2) F",y''BiLLncycrr rrtcxt b;crs :f pclymcr
sclcnccn,
'tlii
1c:, -intersctr:ncc ( tgZ6)
.
r'Organic
K.J.S.3)
'a:r'ors,
pclyraer Chemistry,,,
Cb.:rpmo.; .rnc'l Ha11, Lcnilon (
t 973),
4) -r11as '-,ircr:;mcLccuLesr, plcnum prass. (
f)AO)
v.
C:1t:1y ,,,-.iizat i:n:
Different ty1:rcs cf cDptL_./mcrsr
I{inctics :'r-l c.jr)rl-y,::criza.h i:rr. Tilc
c:.:r_)lymcrizati:n
cguati 'n. . :rr':'r'or rDzrctivitv rati:::; arir
c?DolJnncrizatr:n
r)aralrDt'' is. T'!rc Q.-c scrre,-re.
rns; ta.i^tane :us c3:apcsitr
on
i
4r\
l\/
CeY
of fcccl anJ p:lymcr. C':ntpcsiti:rn cf cci)QLymors'
Variatirn cf cl';t!pcsiti:n with ccnfcrsi:n' Cl:cnristrTr
cf c fp :) lYr.crizat i cn.
( B trours)
Tcxt bcoksr
G.Oclian, rrPrlnclplcs cf Pcllrncrizati:nrr'
Ir{c. Graw I-il Lt ( f 97O) .
2) Ii'.I'I .Billmeycr, I'Tcxt-bc:k cf Pol'yncr scicnccrt l
-r,Il
1cy-Intcrs c it-.nce . ( l97 6,\,
rrOrgnnic Pclymcr ChemistrY",
3) K..i, ^nunilers,
( t g73)
Ci.rc:,; ,; -, anc'! ,'.Ia t 1, Lcnd Cn
'
( rg8o).
Pross
Plonlrn
4) li1las 'rllacromcloculcs'r,
Rcactivity Df fufictional
Chcmical- Reacttcns cf ?cly*ncrs:
Chcmical mcdlBr3ulls ln 1:lymcrs, FLcry's Pcstulatc'
clymers '
f lcat i cn :f Lincor and cr css- Linkccl 1r
Effcct :f crcss-Linking
PcLyincr anaLsgcus reacti:ns'
Functicnalizaticn
cn tire i'r)activi-ty ;f functi:;na1 Srcups'
roslns '
cf p cL;,rstyrcae ' Preparat 1:n cf 1:n-cxchangc
Pclymr-bcun:l catalyets'
P cLymcr-bc'-tnc'l rcagents'
Immcblllzod crrz)[email protected] AppLicatLcns'
(tz hcurs)
1
VI.
)
Taxt b:clcst
('pclymers as atds ln rrganLc
1) Matltr:::, UilLlarns,
19BO'
c1r, ' . .)rfr, AcademLc Prcsst
,organic P rlymer chemlstrlrrr'
2) li.rI. []a rl:rr1crs,
( r g73)'
Chapman ancl IIa1!r Lrn':lon
(' f 98O)
rrlr'1sT:rn:Ieculesrr Plcnun Prcss
D1-ras
3)
rf ?rl)'ncr izati:tttt'
ttl:rinciirl'es
Orliern
4)
i,ic llt^,'.- ri'i tL ( rqaO)
\
v>i
pApr[t vrrr cRGA]rtc
I.
\
cFm{[srRY(ELECTTvE) (so ]rrurs)
:
SYntlletl
Uses of rliborene, ena"nines, di.cyxclohexS'Icarbociiinitie,
dii:nicle, cli.:tct1l1,'tr suI':hoxltler tri.i:ilenr;L pllosplline, polypl:osnhoric acid, trietr 'yLplloslrtrite, eatbonyL. cllfi;aid,-'izole e:rc-r
singtr et oxygen. Phrse tr ensf'er catetlys$s, Poly",*aer ic
yeai_ents ir: organic s;.;n-b^lesis, olectrocile:iri.eatr synthdsis.
ivtoctern
Tcntirooits fleeoi.l:netlded.
1. I:Iousc, :i. 0.}{odein syntiretic Reaetions, r,iilcy-Intersci.c!1cc.
2. Ca^r'rut:lcr s, itr. l,'Ioclern i.{ctilo;ls .in 0rp il:.ic Syntilesi.s,
o.
ul-,. {l,g'tb) .
3. Tlryagara;arl, B.S. SeLective Orgarnic Irallsfor!a3r,tioi.ls,
Vol.I andt If , i'[iley Intcrsci.encc.
4. Tlmi.ions C...ri-. , i'{odcrn lleections in Ouganic Synt;:esis.
5. Forcst, lfewer mctrlocts in i'rci)erative Organic Cheuri.ctry,
. ViriLcy-Int cl sc j.cnec.
6. Fiescr anci FioGer, jtcegcn'Ls f,or Organic Syntiresis.
7.
Fi nax Or :,;:i c Cire,ri str y rt .
B. Pi.ne, i: lrlr --c-rsolt, Grarrn and Ijanurci
It
gy
,tCrg,::*rie C.:e.nistry ( fg,3+)
If ,
Str aincrl Rj np eor :ouncls:
(
tO ironr s)
ACnanta:rcr D:ai;e::antaiic, lrvistanc, prig::anc Dcs,,ar.
Beltzcne, cubr,ri: ilr,:rL ':Icrc:n, pr c:,,ctr 1-enc Lcrrgc r ing r(eton:s
ancl Catcn,i"l::s.,
.
Boolrs:
!-. cl:qrlstl5'of Aaia:'rcnta::es b5,R c Dingharo _illcl:.v.R.
ScliL cS,cr , Spz i. ngcr _ V rr L_,,g !j1 tr_,
2. Aiiey'c1i. c-.lcr:-istr;, i:i' F.".i,ic ].lrrion, cL .r:ririge
Un:ii, :rsi.ty I.T.lss, 1-9.!2.
con-ici. . . ./Z
/
]
e-e
f II.
L
t
Organof l-uorine jpnpoqrcis:
(
ro
irour s)
Metltctls of preporation - Rcaetioti s "r R:cli:c'tion, O=icla:tron,
eLectro:,hi1ia anc nucl.eo.rirlLic r c:rctioils ?r. acti.caL
applieations - Rc.,irigtralits, IrropoJ.Lents and frre
cxtinguisller s, PL:.stics ;:ur cLaston.Jx s - Fl_uc;r ine
eo::tai'niiig oil:t;aac outie:ils, ?rtric.ae traet j.es, aiiti-i;if,La:ii,-ltory
tzanq'r-ei-Ilscl an<l l;:t:_ ca::cer agents.
ii,cf, er ciie e b a9_;:p-l*
L. ari.i,:riees i l- -:ovinc cllcn:i.stry vclL s .r- Ir I:y ctaeey
ar:ci ?;t l;,
.. .
Z. FIuur inc in r-':: gani.c c,lto,,ris';r y iri, I'1. D. C-ra:;jrcl s
3. llLtir;r oc::r'bi>:-is ::.i:ci t:tr:il c,icr i.v;',tivo trry, It. f . Bdil.lS
,j. Or5. ;i::ic ;,_crr: -. iilc c--l,:jj.stIr: i:1: r,Iln o e,ncl -,;:.ci.::1.c1r5,
Plenru,:. 1)r ?s;c iicu Yi;l .l ( li?:i).
( tr iioru s)
IV. ter;;cnoj.cl::- S-ir..ct'-.r;.:l- ;t."'.cit,ls of, Isi,r.l-:li.riic gl;i::cr li
I
eni,'rins, il:;,eii-i, Li-is(;-:tcntoL, Satcnj-ns.
Rcf cl
ereo
L.c,r,:lc:
. Thc hi gi:cu t ci :cnoi s by D,:-Meyo Vol . I f I.
2. Thc Cllenistry of ti:c t:rccll.s l:y A.fL. pir:<.cr.
3. Tritcr':cncir'rs I:y Sinonson, VoI_s.
l-
c-l
V. Ai-lraLoi.cis;
Dctai. icci ot,utly i. nc )-irci ing synthcsi
Yohinbine, Itcscr pine ;xid!. Ly s er g i c ec i. el .
s of iltor,lhlne
(tg
rrours)
Rcf ':roi:cc Bor:..'
1 . Ai ha-ri oi r: c '.-; 3c'r-'. ,- c;'.
.
2. Aj-t.,loicis bi.' 'l:.r's-.^ ,rci;.
3. .j. Ohc'::. fl1 it. jI.':",. :'r;-33.
VI. -S.Eroiris: Clrc;i.f ic:til.n
:t:r ci: s. Synt,r,:sis enci
"f
s-(,r.lct;te r)-i ,cJ'Jr)3t,.-,Iiot:.f , Pr oi;csi,eroi'te, 3q'-liien:'.^1,
Cot+,.i-sone, 3iirt-ic:,JIcr ciic, 3i]Lc :cll-c(C-:.o1.c ;cit)
iti
i:o:tis)
Coi-i;r1....../S
t
Rcf,rr cncc br;o.Ls:
1. Sterioirls by lri.cscr artd Ficocro
2. Tirc Ns.t,-:raL nroclttets cllenis'0r5, Voi;I
I
tinCr'
II eciitccj by
Kodansira.
-'t
3. Finar Vo.trI
VtrJ. .Chc,uictry of -.r:"r3';ag]. :Inl-iinc : Iool:tiol:, Cl.zssj.fi.crtion,
Stf ,-tCtuf :,j. e: , ' ' ,.ti-'r;it --.it('l s5'ntheo:.S ot -)/l-qil lln-Er -*n,1
- u J,
PGD gr oLii')s
,,i.
uJ-
,
-i!,t !r
o,l'--- .r:t'i6-';al-:iins.
(
s
riorx s)
4!I! ti-c c_i:l-W_ g ; X. Pi-n c, Ijcnc,r:-c :s otr ct :l- e-.r-1'r
2. iJ,.tural- :'rocli.cts c ::.-listry ccl j.-icc by iiocja;rs::a 1.Ioi. II.
VIII. [email protected] : Fliiv oncs ii!'ld f, l-:ia'orioLs -(Ocf :12".j ltliC c..:aLCone,
qucr c otin.
l?.
c
:'.
(
Pooks
IX.
Intr
ic lrou s)
: Firla^l Voit. Li-
ocluieti on
.to _l.!1! :r atur c s urv:f
.
(
+
Irour s)
Books':_ JcYrS' lr:l-rcli.
I
\
-\
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